ACID SODIUM SALT OF 1H-PYRAZOLE-3,4,5- TRICARBOXYLIC ACID: SYNTHESIS, CRYSTAL STRUCTURE AND FEATURES OF INTRAMOLECULAR BONDS
The oxidation reaction of 3,3′,5,5′-tetramethyl-1H,1′H-4,4′-bipyrazole in the HNO 3 –Fe 3+ system unexpectedly resulted in the formation of 1Н-pyrazole-3,4,5-tricarboxylic acid (H 3 PTCA) isolated as the acid sodium salt Na(H 2 O) 2 H 2 PTCA. The compound has a polymeric structure stabilized by rare...
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| Veröffentlicht in: | Journal of structural chemistry 2022-04, Vol.63 (4), p.593-602 |
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| container_title | Journal of structural chemistry |
| container_volume | 63 |
| creator | Goncharenko, V. E. Gudovannyy, A. O. Lunev, A. M. Belousov, Yu. A. Lyssenko, K. A. |
| description | The oxidation reaction of 3,3′,5,5′-tetramethyl-1H,1′H-4,4′-bipyrazole in the HNO
3
–Fe
3+
system unexpectedly resulted in the formation of 1Н-pyrazole-3,4,5-tricarboxylic acid (H
3
PTCA) isolated as the acid sodium salt Na(H
2
O)
2
H
2
PTCA. The compound has a polymeric structure stabilized by rare seven-membered Н-bonded rings. |
| doi_str_mv | 10.1134/S0022476622040102 |
| format | Article |
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3
–Fe
3+
system unexpectedly resulted in the formation of 1Н-pyrazole-3,4,5-tricarboxylic acid (H
3
PTCA) isolated as the acid sodium salt Na(H
2
O)
2
H
2
PTCA. The compound has a polymeric structure stabilized by rare seven-membered Н-bonded rings.</description><identifier>ISSN: 0022-4766</identifier><identifier>EISSN: 1573-8779</identifier><identifier>DOI: 10.1134/S0022476622040102</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Atomic ; Atomic/Molecular Structure and Spectra ; Chemistry ; Chemistry and Materials Science ; Crystal structure ; Inorganic Chemistry ; Molecular ; Optical and Plasma Physics ; Oxidation ; Physical Chemistry ; Pyrazole ; Sodium ; Sodium salts ; Solid State Physics</subject><ispartof>Journal of structural chemistry, 2022-04, Vol.63 (4), p.593-602</ispartof><rights>Pleiades Publishing, Ltd. 2022</rights><rights>Pleiades Publishing, Ltd. 2022.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c268t-fe20bf86963eef22b4c2382586a284e2252f960e97bd3fa1943a9d4b312146083</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0022476622040102$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0022476622040102$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51297</link.rule.ids></links><search><creatorcontrib>Goncharenko, V. E.</creatorcontrib><creatorcontrib>Gudovannyy, A. O.</creatorcontrib><creatorcontrib>Lunev, A. M.</creatorcontrib><creatorcontrib>Belousov, Yu. A.</creatorcontrib><creatorcontrib>Lyssenko, K. A.</creatorcontrib><title>ACID SODIUM SALT OF 1H-PYRAZOLE-3,4,5- TRICARBOXYLIC ACID: SYNTHESIS, CRYSTAL STRUCTURE AND FEATURES OF INTRAMOLECULAR BONDS</title><title>Journal of structural chemistry</title><addtitle>J Struct Chem</addtitle><description>The oxidation reaction of 3,3′,5,5′-tetramethyl-1H,1′H-4,4′-bipyrazole in the HNO
3
–Fe
3+
system unexpectedly resulted in the formation of 1Н-pyrazole-3,4,5-tricarboxylic acid (H
3
PTCA) isolated as the acid sodium salt Na(H
2
O)
2
H
2
PTCA. The compound has a polymeric structure stabilized by rare seven-membered Н-bonded rings.</description><subject>Atomic</subject><subject>Atomic/Molecular Structure and Spectra</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Crystal structure</subject><subject>Inorganic Chemistry</subject><subject>Molecular</subject><subject>Optical and Plasma Physics</subject><subject>Oxidation</subject><subject>Physical Chemistry</subject><subject>Pyrazole</subject><subject>Sodium</subject><subject>Sodium salts</subject><subject>Solid State Physics</subject><issn>0022-4766</issn><issn>1573-8779</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp1kEFLw0AUhBdRsFZ_gLcFr43uvt1sEm_bJLWBNJHsBoyXkLQbsWhbk_Yg-ONNqOBBPL0HM98MDELXlNxSyvidIgSAO0IAEE4ogRM0orbDLNdxvFM0GmRr0M_RRdetCSGe64kR-pJ-FGCVBlG-wErGGqczTOfWY5HJ5zQOLTbhE9vCOot8mU3TpyKOfDxA91gViZ6HKlIT7GeF0jLGSme5r_MsxDIJ8CyUw6-GzCjRmVz0iX4eywxP0yRQl-isqd46c_VzxyifhdqfW3H60NfF1hKEu7caA6RuXOEJZkwDUPMlMBdsV1TgcgNgQ-MJYjynXrGmoh5nlbfiNaNAuSAuG6ObY-6u3X4cTLcv19tDu-krSxCOIxilwHoXPbqW7bbrWtOUu_b1vWo_S0rKYeTyz8g9A0em672bF9P-Jv8PfQP6knGp</recordid><startdate>20220401</startdate><enddate>20220401</enddate><creator>Goncharenko, V. E.</creator><creator>Gudovannyy, A. O.</creator><creator>Lunev, A. M.</creator><creator>Belousov, Yu. A.</creator><creator>Lyssenko, K. A.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20220401</creationdate><title>ACID SODIUM SALT OF 1H-PYRAZOLE-3,4,5- TRICARBOXYLIC ACID: SYNTHESIS, CRYSTAL STRUCTURE AND FEATURES OF INTRAMOLECULAR BONDS</title><author>Goncharenko, V. E. ; Gudovannyy, A. O. ; Lunev, A. M. ; Belousov, Yu. A. ; Lyssenko, K. A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c268t-fe20bf86963eef22b4c2382586a284e2252f960e97bd3fa1943a9d4b312146083</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Atomic</topic><topic>Atomic/Molecular Structure and Spectra</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Crystal structure</topic><topic>Inorganic Chemistry</topic><topic>Molecular</topic><topic>Optical and Plasma Physics</topic><topic>Oxidation</topic><topic>Physical Chemistry</topic><topic>Pyrazole</topic><topic>Sodium</topic><topic>Sodium salts</topic><topic>Solid State Physics</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Goncharenko, V. E.</creatorcontrib><creatorcontrib>Gudovannyy, A. O.</creatorcontrib><creatorcontrib>Lunev, A. M.</creatorcontrib><creatorcontrib>Belousov, Yu. A.</creatorcontrib><creatorcontrib>Lyssenko, K. A.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of structural chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Goncharenko, V. E.</au><au>Gudovannyy, A. O.</au><au>Lunev, A. M.</au><au>Belousov, Yu. A.</au><au>Lyssenko, K. A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>ACID SODIUM SALT OF 1H-PYRAZOLE-3,4,5- TRICARBOXYLIC ACID: SYNTHESIS, CRYSTAL STRUCTURE AND FEATURES OF INTRAMOLECULAR BONDS</atitle><jtitle>Journal of structural chemistry</jtitle><stitle>J Struct Chem</stitle><date>2022-04-01</date><risdate>2022</risdate><volume>63</volume><issue>4</issue><spage>593</spage><epage>602</epage><pages>593-602</pages><issn>0022-4766</issn><eissn>1573-8779</eissn><abstract>The oxidation reaction of 3,3′,5,5′-tetramethyl-1H,1′H-4,4′-bipyrazole in the HNO
3
–Fe
3+
system unexpectedly resulted in the formation of 1Н-pyrazole-3,4,5-tricarboxylic acid (H
3
PTCA) isolated as the acid sodium salt Na(H
2
O)
2
H
2
PTCA. The compound has a polymeric structure stabilized by rare seven-membered Н-bonded rings.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0022476622040102</doi><tpages>10</tpages></addata></record> |
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| subjects | Atomic Atomic/Molecular Structure and Spectra Chemistry Chemistry and Materials Science Crystal structure Inorganic Chemistry Molecular Optical and Plasma Physics Oxidation Physical Chemistry Pyrazole Sodium Sodium salts Solid State Physics |
| title | ACID SODIUM SALT OF 1H-PYRAZOLE-3,4,5- TRICARBOXYLIC ACID: SYNTHESIS, CRYSTAL STRUCTURE AND FEATURES OF INTRAMOLECULAR BONDS |
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