Adsorption of toxic crystal violet dye from aqueous solution by using waste sugarcane leaf-based activated carbon: isotherm, kinetic and thermodynamic study
The work demonstrated that waste sugarcane leaves were recycled by transforming them into activated carbon form and were employed for adsorption of crystal violet (CV) dyes from water bodies. Sugarcane leaves were ultrasonically treated with concentrated H 2 SO 4 as an impregnating reagent and furth...
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| Veröffentlicht in: | Journal of the Iranian Chemical Society 2022, Vol.19 (7), p.2891-2906 |
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| creator | Patil, Suryakant A. Kumbhar, Pramod D. Satvekar, Bhushan S. Harale, Namdev S. Bhise, Sagar C. Patil, Sandip K. Sartape, Ashish S. Kolekar, Sanjay S. Anuse, Mansing A. |
| description | The work demonstrated that waste sugarcane leaves were recycled by transforming them into activated carbon form and were employed for adsorption of crystal violet (CV) dyes from water bodies. Sugarcane leaves were ultrasonically treated with concentrated H
2
SO
4
as an impregnating reagent and further with microwave irradiation for 15 min. The lustrous porous SLAC adsorbent material was subjected to characterized through advanced techniques like FTIR, XRD, BET, Raman, SEM, XPS, and EDAX analysis, to support and confirm the successful preparation of adsorbent and adsorption process. SLAC adsorbent shows the glowing porous and amorphous nature with fascinating specific surface area 730.59 m
2
g
−1
. The porous and high surface SLAC adsorbent was utilized through batch adsorption technique for assessment and optimization of physico-chemical parameters viz. pH of working solution, SLAC amount, CV dye concentration, contact period, shaking speed, and surrounding temperature. At optimized conditions as pH 9.0 and 0.45 g SLAC significantly removed 99.81 ± 0.15% of toxic dye. Moreover, the equilibrium was attained within 60 min at a shaking speed of 170 rpm. The experimental data follows Langmuir adsorption isotherm with monolayer adsorption capacity 149.25 mg g
−1
. Kinetic study reveals that the adsorption process follows the pseudo-second-order kinetic model and thermodynamic study represents that the process is spontaneous and endothermic in nature. |
| doi_str_mv | 10.1007/s13738-022-02500-3 |
| format | Article |
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2
SO
4
as an impregnating reagent and further with microwave irradiation for 15 min. The lustrous porous SLAC adsorbent material was subjected to characterized through advanced techniques like FTIR, XRD, BET, Raman, SEM, XPS, and EDAX analysis, to support and confirm the successful preparation of adsorbent and adsorption process. SLAC adsorbent shows the glowing porous and amorphous nature with fascinating specific surface area 730.59 m
2
g
−1
. The porous and high surface SLAC adsorbent was utilized through batch adsorption technique for assessment and optimization of physico-chemical parameters viz. pH of working solution, SLAC amount, CV dye concentration, contact period, shaking speed, and surrounding temperature. At optimized conditions as pH 9.0 and 0.45 g SLAC significantly removed 99.81 ± 0.15% of toxic dye. Moreover, the equilibrium was attained within 60 min at a shaking speed of 170 rpm. The experimental data follows Langmuir adsorption isotherm with monolayer adsorption capacity 149.25 mg g
−1
. Kinetic study reveals that the adsorption process follows the pseudo-second-order kinetic model and thermodynamic study represents that the process is spontaneous and endothermic in nature.</description><identifier>ISSN: 1735-207X</identifier><identifier>EISSN: 1735-2428</identifier><identifier>DOI: 10.1007/s13738-022-02500-3</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Activated carbon ; Adsorbents ; Adsorption ; Analytical Chemistry ; Aqueous solutions ; Biochemistry ; Chemistry ; Chemistry and Materials Science ; Dyes ; Endothermic reactions ; Impregnation ; Inorganic Chemistry ; Isotherms ; Optimization ; Organic Chemistry ; Original Paper ; Physical Chemistry ; Porous materials ; Reagents ; Shaking ; Sugarcane ; Sulfuric acid ; Surface chemistry ; Thermodynamics ; X ray photoelectron spectroscopy</subject><ispartof>Journal of the Iranian Chemical Society, 2022, Vol.19 (7), p.2891-2906</ispartof><rights>Iranian Chemical Society 2022</rights><rights>Iranian Chemical Society 2022.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-f650bd19d054c621de3739ea29d9406c922398b10f8f9e0a6a10819720239bc23</citedby><cites>FETCH-LOGICAL-c319t-f650bd19d054c621de3739ea29d9406c922398b10f8f9e0a6a10819720239bc23</cites><orcidid>0000-0003-4237-6551</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s13738-022-02500-3$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s13738-022-02500-3$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,778,782,27911,27912,41475,42544,51306</link.rule.ids></links><search><creatorcontrib>Patil, Suryakant A.</creatorcontrib><creatorcontrib>Kumbhar, Pramod D.</creatorcontrib><creatorcontrib>Satvekar, Bhushan S.</creatorcontrib><creatorcontrib>Harale, Namdev S.</creatorcontrib><creatorcontrib>Bhise, Sagar C.</creatorcontrib><creatorcontrib>Patil, Sandip K.</creatorcontrib><creatorcontrib>Sartape, Ashish S.</creatorcontrib><creatorcontrib>Kolekar, Sanjay S.</creatorcontrib><creatorcontrib>Anuse, Mansing A.</creatorcontrib><title>Adsorption of toxic crystal violet dye from aqueous solution by using waste sugarcane leaf-based activated carbon: isotherm, kinetic and thermodynamic study</title><title>Journal of the Iranian Chemical Society</title><addtitle>J IRAN CHEM SOC</addtitle><description>The work demonstrated that waste sugarcane leaves were recycled by transforming them into activated carbon form and were employed for adsorption of crystal violet (CV) dyes from water bodies. Sugarcane leaves were ultrasonically treated with concentrated H
2
SO
4
as an impregnating reagent and further with microwave irradiation for 15 min. The lustrous porous SLAC adsorbent material was subjected to characterized through advanced techniques like FTIR, XRD, BET, Raman, SEM, XPS, and EDAX analysis, to support and confirm the successful preparation of adsorbent and adsorption process. SLAC adsorbent shows the glowing porous and amorphous nature with fascinating specific surface area 730.59 m
2
g
−1
. The porous and high surface SLAC adsorbent was utilized through batch adsorption technique for assessment and optimization of physico-chemical parameters viz. pH of working solution, SLAC amount, CV dye concentration, contact period, shaking speed, and surrounding temperature. At optimized conditions as pH 9.0 and 0.45 g SLAC significantly removed 99.81 ± 0.15% of toxic dye. Moreover, the equilibrium was attained within 60 min at a shaking speed of 170 rpm. The experimental data follows Langmuir adsorption isotherm with monolayer adsorption capacity 149.25 mg g
−1
. Kinetic study reveals that the adsorption process follows the pseudo-second-order kinetic model and thermodynamic study represents that the process is spontaneous and endothermic in nature.</description><subject>Activated carbon</subject><subject>Adsorbents</subject><subject>Adsorption</subject><subject>Analytical Chemistry</subject><subject>Aqueous solutions</subject><subject>Biochemistry</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Dyes</subject><subject>Endothermic reactions</subject><subject>Impregnation</subject><subject>Inorganic Chemistry</subject><subject>Isotherms</subject><subject>Optimization</subject><subject>Organic Chemistry</subject><subject>Original Paper</subject><subject>Physical Chemistry</subject><subject>Porous materials</subject><subject>Reagents</subject><subject>Shaking</subject><subject>Sugarcane</subject><subject>Sulfuric acid</subject><subject>Surface chemistry</subject><subject>Thermodynamics</subject><subject>X ray photoelectron spectroscopy</subject><issn>1735-207X</issn><issn>1735-2428</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp9UctOHDEQHEVEyrLJD-RkiSsT2vbOw7khBAQJiUsi5Wb12J7NLLP2xu0B5l_ysTG7IG4cWt0qVXWpu4riK4dvHKA5Iy4b2ZYgRK4KoJQfigVvZFWKlWiPXmdofn8qjok2AFUD1WpR_Du3FOIuDcGz0LMUngbDTJwp4cgehjC6xOzsWB_DluHfyYWJGIVx2iu6mU00-DV7REqO0bTGaNA7Njrsyw7JWYYmDQ-Y8mQwdsF_ZwOF9MfF7Sm7H7xL2RC9ZXso2NnjNiOUJjt_Lj72OJL78tKXxa-ry58XP8rbu-ubi_Pb0kiuUtnXFXSWK5svMrXg1uVnKIdCWbWC2ighpGo7Dn3bKwdYI4eWq0ZAxjsj5LI4OezdxZBPpKQ3YYo-W2pRN3XV8lXdZpY4sEwMRNH1eheHLcZZc9DPKehDCjqnoPcpaJlF8iCiTPZrF99Wv6P6D2HMjWs</recordid><startdate>2022</startdate><enddate>2022</enddate><creator>Patil, Suryakant A.</creator><creator>Kumbhar, Pramod D.</creator><creator>Satvekar, Bhushan S.</creator><creator>Harale, Namdev S.</creator><creator>Bhise, Sagar C.</creator><creator>Patil, Sandip K.</creator><creator>Sartape, Ashish S.</creator><creator>Kolekar, Sanjay S.</creator><creator>Anuse, Mansing A.</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0003-4237-6551</orcidid></search><sort><creationdate>2022</creationdate><title>Adsorption of toxic crystal violet dye from aqueous solution by using waste sugarcane leaf-based activated carbon: isotherm, kinetic and thermodynamic study</title><author>Patil, Suryakant A. ; Kumbhar, Pramod D. ; Satvekar, Bhushan S. ; Harale, Namdev S. ; Bhise, Sagar C. ; Patil, Sandip K. ; Sartape, Ashish S. ; Kolekar, Sanjay S. ; Anuse, Mansing A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-f650bd19d054c621de3739ea29d9406c922398b10f8f9e0a6a10819720239bc23</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Activated carbon</topic><topic>Adsorbents</topic><topic>Adsorption</topic><topic>Analytical Chemistry</topic><topic>Aqueous solutions</topic><topic>Biochemistry</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Dyes</topic><topic>Endothermic reactions</topic><topic>Impregnation</topic><topic>Inorganic Chemistry</topic><topic>Isotherms</topic><topic>Optimization</topic><topic>Organic Chemistry</topic><topic>Original Paper</topic><topic>Physical Chemistry</topic><topic>Porous materials</topic><topic>Reagents</topic><topic>Shaking</topic><topic>Sugarcane</topic><topic>Sulfuric acid</topic><topic>Surface chemistry</topic><topic>Thermodynamics</topic><topic>X ray photoelectron spectroscopy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Patil, Suryakant A.</creatorcontrib><creatorcontrib>Kumbhar, Pramod D.</creatorcontrib><creatorcontrib>Satvekar, Bhushan S.</creatorcontrib><creatorcontrib>Harale, Namdev S.</creatorcontrib><creatorcontrib>Bhise, Sagar C.</creatorcontrib><creatorcontrib>Patil, Sandip K.</creatorcontrib><creatorcontrib>Sartape, Ashish S.</creatorcontrib><creatorcontrib>Kolekar, Sanjay S.</creatorcontrib><creatorcontrib>Anuse, Mansing A.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of the Iranian Chemical Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Patil, Suryakant A.</au><au>Kumbhar, Pramod D.</au><au>Satvekar, Bhushan S.</au><au>Harale, Namdev S.</au><au>Bhise, Sagar C.</au><au>Patil, Sandip K.</au><au>Sartape, Ashish S.</au><au>Kolekar, Sanjay S.</au><au>Anuse, Mansing A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Adsorption of toxic crystal violet dye from aqueous solution by using waste sugarcane leaf-based activated carbon: isotherm, kinetic and thermodynamic study</atitle><jtitle>Journal of the Iranian Chemical Society</jtitle><stitle>J IRAN CHEM SOC</stitle><date>2022</date><risdate>2022</risdate><volume>19</volume><issue>7</issue><spage>2891</spage><epage>2906</epage><pages>2891-2906</pages><issn>1735-207X</issn><eissn>1735-2428</eissn><abstract>The work demonstrated that waste sugarcane leaves were recycled by transforming them into activated carbon form and were employed for adsorption of crystal violet (CV) dyes from water bodies. Sugarcane leaves were ultrasonically treated with concentrated H
2
SO
4
as an impregnating reagent and further with microwave irradiation for 15 min. The lustrous porous SLAC adsorbent material was subjected to characterized through advanced techniques like FTIR, XRD, BET, Raman, SEM, XPS, and EDAX analysis, to support and confirm the successful preparation of adsorbent and adsorption process. SLAC adsorbent shows the glowing porous and amorphous nature with fascinating specific surface area 730.59 m
2
g
−1
. The porous and high surface SLAC adsorbent was utilized through batch adsorption technique for assessment and optimization of physico-chemical parameters viz. pH of working solution, SLAC amount, CV dye concentration, contact period, shaking speed, and surrounding temperature. At optimized conditions as pH 9.0 and 0.45 g SLAC significantly removed 99.81 ± 0.15% of toxic dye. Moreover, the equilibrium was attained within 60 min at a shaking speed of 170 rpm. The experimental data follows Langmuir adsorption isotherm with monolayer adsorption capacity 149.25 mg g
−1
. Kinetic study reveals that the adsorption process follows the pseudo-second-order kinetic model and thermodynamic study represents that the process is spontaneous and endothermic in nature.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s13738-022-02500-3</doi><tpages>16</tpages><orcidid>https://orcid.org/0000-0003-4237-6551</orcidid></addata></record> |
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| source | Springer Nature - Complete Springer Journals |
| subjects | Activated carbon Adsorbents Adsorption Analytical Chemistry Aqueous solutions Biochemistry Chemistry Chemistry and Materials Science Dyes Endothermic reactions Impregnation Inorganic Chemistry Isotherms Optimization Organic Chemistry Original Paper Physical Chemistry Porous materials Reagents Shaking Sugarcane Sulfuric acid Surface chemistry Thermodynamics X ray photoelectron spectroscopy |
| title | Adsorption of toxic crystal violet dye from aqueous solution by using waste sugarcane leaf-based activated carbon: isotherm, kinetic and thermodynamic study |
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