Carbon paste modified with Poly-Melamine and gold nanoparticles for selective determination of hydroquinone in presence of arbutin

Modification of carbon paste electrode (CPE) coated with poly-melamine (PM) and gold nanoparticles (AuNPs) was produced by electrochemical synthesis. The morphological characteristic of PM/AuNPs/CPE was characterized by field emission scanning electron microscope (FESEM), the effect of supporting el...

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Hauptverfasser: Paramita, Denok Risky Ayu, Widyaningrum, Bernadeta Ayu, Budiman, Ismail, Kusuma, Sukma Surya, Sakti, Satya Candra Wibawa, Harsini, Muji
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creator Paramita, Denok Risky Ayu
Widyaningrum, Bernadeta Ayu
Budiman, Ismail
Kusuma, Sukma Surya
Sakti, Satya Candra Wibawa
Harsini, Muji
description Modification of carbon paste electrode (CPE) coated with poly-melamine (PM) and gold nanoparticles (AuNPs) was produced by electrochemical synthesis. The morphological characteristic of PM/AuNPs/CPE was characterized by field emission scanning electron microscope (FESEM), the effect of supporting electrolyte and scan rate were assessed by cyclic voltammetry (CV) to get suitable conditions for hydroquinone (HQ) analysis, and the linear sweep voltammetry (LSV) was used to determine HQ into the optimum condition. The result shows the PM/AuNPs/CPE has been successfully determined the responses of HQ in a presence of Arbutin as interference. The modified electrode also enhances the electrocatalytic activities toward the oxidation peak of hydroquinone (HQ) 5 fold higher than the bare CPE. These modified electrodes displayed linear concentration ranging from 0.4 to 10 µM with detection limit of 0.27 µM. In addition, the PM/AuNPs/CPE shows high selectivity, sensitivity and excellent practice for HQ analysis in the real sample with satisfying recovery.
doi_str_mv 10.1063/5.0079004
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The morphological characteristic of PM/AuNPs/CPE was characterized by field emission scanning electron microscope (FESEM), the effect of supporting electrolyte and scan rate were assessed by cyclic voltammetry (CV) to get suitable conditions for hydroquinone (HQ) analysis, and the linear sweep voltammetry (LSV) was used to determine HQ into the optimum condition. The result shows the PM/AuNPs/CPE has been successfully determined the responses of HQ in a presence of Arbutin as interference. The modified electrode also enhances the electrocatalytic activities toward the oxidation peak of hydroquinone (HQ) 5 fold higher than the bare CPE. These modified electrodes displayed linear concentration ranging from 0.4 to 10 µM with detection limit of 0.27 µM. 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source AIP Journals Complete
subjects Carbon
Chemical synthesis
Coated electrodes
Electrodes
Field emission microscopy
Gold
Hydroquinone
Melamine
Nanoparticles
Oxidation
Selectivity
Voltammetry
title Carbon paste modified with Poly-Melamine and gold nanoparticles for selective determination of hydroquinone in presence of arbutin
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