Softening effect of trace Fe-substituted potassium-sodium niobate-based lead-free piezoceramics
For KNN-based lead-free piezoceramics, Fe usually enters the B site as the acceptor to harden the ceramics. Herein, Fe preferentially entered the A-site, and different softening effects were observed in trace Fe-substitution KNN-base ceramics. The effects of Fe doping on the phase structure, grain s...
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description | For KNN-based lead-free piezoceramics, Fe usually enters the B site as the acceptor to harden the ceramics. Herein, Fe preferentially entered the A-site, and different softening effects were observed in trace Fe-substitution KNN-base ceramics. The effects of Fe doping on the phase structure, grain size and electrical properties of 0.96K0.48Na0.52Nb0.96Sb0.04O3-0.04Bi0.5-xFexAg0.03Na0.47ZrO3 (KNNS-BFxANZ, x = 0.0~0.08) ceramics were investigated. The most excellent overall properties (kp=0.56, d33=464 pC/N and TC=240 °C) were obtained with x = 0.06. The enhanced electrical properties are attributed to the substantial improvement in density and polarization efficiency caused by trace Fe ions. Of particular interest is that the trace Fe ions doping could regulate the TR-O/TO-T without the change of TC. This work provided a refreshing thinking for the study of soft/hard doping of KNN based piezoelectric ceramics, and was of great significance to further improve the comprehensive properties of KNN based piezoelectric materials without sacrificing Curie temperature.
•Softening effect was observed in Fe doped KNN-based piezoelectric ceramics.•The trace Fe ions doping could regulate the TR-O/TO-T without changing the TC.•The most excellent electrical properties (kp=0.56, d33=464 pC/N) were obtained with x=0.06. |
doi_str_mv | 10.1016/j.jallcom.2022.164718 |
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•Softening effect was observed in Fe doped KNN-based piezoelectric ceramics.•The trace Fe ions doping could regulate the TR-O/TO-T without changing the TC.•The most excellent electrical properties (kp=0.56, d33=464 pC/N) were obtained with x=0.06.</description><identifier>ISSN: 0925-8388</identifier><identifier>EISSN: 1873-4669</identifier><identifier>DOI: 10.1016/j.jallcom.2022.164718</identifier><language>eng</language><publisher>Lausanne: Elsevier B.V</publisher><subject>Curie temperature ; Doping ; Electrical properties ; Fe-substitution ; Grain size ; KNN-based ; Lead free ; Materials substitution ; Piezoelectric ceramics ; Piezoelectricity ; Softening ; Softening effects ; Solid phases</subject><ispartof>Journal of alloys and compounds, 2022-07, Vol.909, p.164718, Article 164718</ispartof><rights>2022 Elsevier B.V.</rights><rights>Copyright Elsevier BV Jul 15, 2022</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c267t-8cb15bf846fc34f25169b55bc627fdb1726781576cc977ce54c67997ec51f4ec3</citedby><cites>FETCH-LOGICAL-c267t-8cb15bf846fc34f25169b55bc627fdb1726781576cc977ce54c67997ec51f4ec3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.jallcom.2022.164718$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids></links><search><creatorcontrib>He, Bo</creatorcontrib><creatorcontrib>Liu, Weipeng</creatorcontrib><creatorcontrib>Zhou, Benwei</creatorcontrib><creatorcontrib>Wang, Xijun</creatorcontrib><creatorcontrib>Cheng, Chuanbing</creatorcontrib><creatorcontrib>Du, Yi</creatorcontrib><creatorcontrib>Li, Zhongfu</creatorcontrib><title>Softening effect of trace Fe-substituted potassium-sodium niobate-based lead-free piezoceramics</title><title>Journal of alloys and compounds</title><description>For KNN-based lead-free piezoceramics, Fe usually enters the B site as the acceptor to harden the ceramics. Herein, Fe preferentially entered the A-site, and different softening effects were observed in trace Fe-substitution KNN-base ceramics. The effects of Fe doping on the phase structure, grain size and electrical properties of 0.96K0.48Na0.52Nb0.96Sb0.04O3-0.04Bi0.5-xFexAg0.03Na0.47ZrO3 (KNNS-BFxANZ, x = 0.0~0.08) ceramics were investigated. The most excellent overall properties (kp=0.56, d33=464 pC/N and TC=240 °C) were obtained with x = 0.06. The enhanced electrical properties are attributed to the substantial improvement in density and polarization efficiency caused by trace Fe ions. Of particular interest is that the trace Fe ions doping could regulate the TR-O/TO-T without the change of TC. This work provided a refreshing thinking for the study of soft/hard doping of KNN based piezoelectric ceramics, and was of great significance to further improve the comprehensive properties of KNN based piezoelectric materials without sacrificing Curie temperature.
•Softening effect was observed in Fe doped KNN-based piezoelectric ceramics.•The trace Fe ions doping could regulate the TR-O/TO-T without changing the TC.•The most excellent electrical properties (kp=0.56, d33=464 pC/N) were obtained with x=0.06.</description><subject>Curie temperature</subject><subject>Doping</subject><subject>Electrical properties</subject><subject>Fe-substitution</subject><subject>Grain size</subject><subject>KNN-based</subject><subject>Lead free</subject><subject>Materials substitution</subject><subject>Piezoelectric ceramics</subject><subject>Piezoelectricity</subject><subject>Softening</subject><subject>Softening effects</subject><subject>Solid phases</subject><issn>0925-8388</issn><issn>1873-4669</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNqFkMtKxDAUhoMoOI4-glBwndq0TdKuRAZvMOBCXYf09ERS2mZMUkGf3gwze1f_4r8czkfINStyVjBxO-SDHkdwU14WZZkzUUvWnJAVa2RFayHaU7Iq2pLTpmqac3IRwlAUBWsrtiLqzZmIs50_MzQGIWbOZNFrwOwRaVi6EG1cIvbZzkUdgl0mGlyfJJut63RE2umQ7BF1T41HzHYWfx2g15OFcEnOjB4DXh11TT4eH943z3T7-vSyud9SKIWMtIGO8c40tTBQ1abkTLQd5x2IUpq-YzKlGsalAGilBOQ1CNm2EoEzUyNUa3Jz2N1597VgiGpwi5_TSZWqdV0xKVhK8UMKvAvBo1E7byftfxQr1J6lGtSRpdqzVAeWqXd36GF64duiVwEszoC99YmZ6p39Z-EPECyA2Q</recordid><startdate>20220715</startdate><enddate>20220715</enddate><creator>He, Bo</creator><creator>Liu, Weipeng</creator><creator>Zhou, Benwei</creator><creator>Wang, Xijun</creator><creator>Cheng, Chuanbing</creator><creator>Du, Yi</creator><creator>Li, Zhongfu</creator><general>Elsevier B.V</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20220715</creationdate><title>Softening effect of trace Fe-substituted potassium-sodium niobate-based lead-free piezoceramics</title><author>He, Bo ; Liu, Weipeng ; Zhou, Benwei ; Wang, Xijun ; Cheng, Chuanbing ; Du, Yi ; Li, Zhongfu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c267t-8cb15bf846fc34f25169b55bc627fdb1726781576cc977ce54c67997ec51f4ec3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Curie temperature</topic><topic>Doping</topic><topic>Electrical properties</topic><topic>Fe-substitution</topic><topic>Grain size</topic><topic>KNN-based</topic><topic>Lead free</topic><topic>Materials substitution</topic><topic>Piezoelectric ceramics</topic><topic>Piezoelectricity</topic><topic>Softening</topic><topic>Softening effects</topic><topic>Solid phases</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>He, Bo</creatorcontrib><creatorcontrib>Liu, Weipeng</creatorcontrib><creatorcontrib>Zhou, Benwei</creatorcontrib><creatorcontrib>Wang, Xijun</creatorcontrib><creatorcontrib>Cheng, Chuanbing</creatorcontrib><creatorcontrib>Du, Yi</creatorcontrib><creatorcontrib>Li, Zhongfu</creatorcontrib><collection>CrossRef</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of alloys and compounds</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>He, Bo</au><au>Liu, Weipeng</au><au>Zhou, Benwei</au><au>Wang, Xijun</au><au>Cheng, Chuanbing</au><au>Du, Yi</au><au>Li, Zhongfu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Softening effect of trace Fe-substituted potassium-sodium niobate-based lead-free piezoceramics</atitle><jtitle>Journal of alloys and compounds</jtitle><date>2022-07-15</date><risdate>2022</risdate><volume>909</volume><spage>164718</spage><pages>164718-</pages><artnum>164718</artnum><issn>0925-8388</issn><eissn>1873-4669</eissn><abstract>For KNN-based lead-free piezoceramics, Fe usually enters the B site as the acceptor to harden the ceramics. Herein, Fe preferentially entered the A-site, and different softening effects were observed in trace Fe-substitution KNN-base ceramics. The effects of Fe doping on the phase structure, grain size and electrical properties of 0.96K0.48Na0.52Nb0.96Sb0.04O3-0.04Bi0.5-xFexAg0.03Na0.47ZrO3 (KNNS-BFxANZ, x = 0.0~0.08) ceramics were investigated. The most excellent overall properties (kp=0.56, d33=464 pC/N and TC=240 °C) were obtained with x = 0.06. The enhanced electrical properties are attributed to the substantial improvement in density and polarization efficiency caused by trace Fe ions. Of particular interest is that the trace Fe ions doping could regulate the TR-O/TO-T without the change of TC. This work provided a refreshing thinking for the study of soft/hard doping of KNN based piezoelectric ceramics, and was of great significance to further improve the comprehensive properties of KNN based piezoelectric materials without sacrificing Curie temperature.
•Softening effect was observed in Fe doped KNN-based piezoelectric ceramics.•The trace Fe ions doping could regulate the TR-O/TO-T without changing the TC.•The most excellent electrical properties (kp=0.56, d33=464 pC/N) were obtained with x=0.06.</abstract><cop>Lausanne</cop><pub>Elsevier B.V</pub><doi>10.1016/j.jallcom.2022.164718</doi></addata></record> |
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subjects | Curie temperature Doping Electrical properties Fe-substitution Grain size KNN-based Lead free Materials substitution Piezoelectric ceramics Piezoelectricity Softening Softening effects Solid phases |
title | Softening effect of trace Fe-substituted potassium-sodium niobate-based lead-free piezoceramics |
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