Conversion of Glycine to Oxalate in Presence of CuSO4⋅5H2O and Isonicotinamide
The reaction of CuSO 4 ⋅5H 2 O with glycine and 4-cyanopyridine in aqueous alkaline medium resulted in polymeric complex [Cu(ox) 2 (isn) 2 ]·(CONH 2 ) 2 ] n ( 1 ) (where ox is oxalate, isn is isonicotinamide). Complex 1 has been studied by single crystal X-ray diffraction. Crystal structure reveals...
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| Veröffentlicht in: | Russian journal of inorganic chemistry 2022, Vol.67 (5), p.608-615 |
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| container_title | Russian journal of inorganic chemistry |
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| creator | Gogoi, Anshuman Bharali, Linkon |
| description | The reaction of CuSO
4
⋅5H
2
O with glycine and 4-cyanopyridine in aqueous alkaline medium resulted in polymeric complex [Cu(ox)
2
(isn)
2
]·(CONH
2
)
2
]
n
(
1
) (where ox is oxalate, isn is isonicotinamide). Complex
1
has been studied by single crystal X-ray diffraction. Crystal structure reveals that complex
1
is a polymeric structure bridged by oxalate ions. Glycine has been oxidized to oxalate during the course of the reaction along with the in-situ hydrolysis of 4-cyanopyridine to isonicotinamide resulting in complex
1
. Complex
1
was further characterized by molar conductance, UV-Vis and FT-IR spectroscopic techniques. The conversion of glycine to oxalate occurs spontaneously in aqueous solution under ambient conditions. |
| doi_str_mv | 10.1134/S0036023622050072 |
| format | Article |
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4
⋅5H
2
O with glycine and 4-cyanopyridine in aqueous alkaline medium resulted in polymeric complex [Cu(ox)
2
(isn)
2
]·(CONH
2
)
2
]
n
(
1
) (where ox is oxalate, isn is isonicotinamide). Complex
1
has been studied by single crystal X-ray diffraction. Crystal structure reveals that complex
1
is a polymeric structure bridged by oxalate ions. Glycine has been oxidized to oxalate during the course of the reaction along with the in-situ hydrolysis of 4-cyanopyridine to isonicotinamide resulting in complex
1
. Complex
1
was further characterized by molar conductance, UV-Vis and FT-IR spectroscopic techniques. The conversion of glycine to oxalate occurs spontaneously in aqueous solution under ambient conditions.</description><identifier>ISSN: 0036-0236</identifier><identifier>EISSN: 1531-8613</identifier><identifier>DOI: 10.1134/S0036023622050072</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Aqueous solutions ; Chemistry ; Chemistry and Materials Science ; Conversion ; Crystal structure ; Glycine ; Inorganic Chemistry ; Single crystals ; Synthesis and Properties of Inorganic Compounds</subject><ispartof>Russian journal of inorganic chemistry, 2022, Vol.67 (5), p.608-615</ispartof><rights>Pleiades Publishing, Ltd. 2022. ISSN 0036-0236, Russian Journal of Inorganic Chemistry, 2022, Vol. 67, No. 5, pp. 608–615. © Pleiades Publishing, Ltd., 2022. ISSN 0036-0236, Russian Journal of Inorganic Chemistry, 2022. © Pleiades Publishing, Ltd., 2022.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2312-4061fc0f789d0f6e8298da995108fc9b3bab6fc39bb80afbc67143ce0cb182293</citedby><cites>FETCH-LOGICAL-c2312-4061fc0f789d0f6e8298da995108fc9b3bab6fc39bb80afbc67143ce0cb182293</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0036023622050072$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0036023622050072$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Gogoi, Anshuman</creatorcontrib><creatorcontrib>Bharali, Linkon</creatorcontrib><title>Conversion of Glycine to Oxalate in Presence of CuSO4⋅5H2O and Isonicotinamide</title><title>Russian journal of inorganic chemistry</title><addtitle>Russ. J. Inorg. Chem</addtitle><description>The reaction of CuSO
4
⋅5H
2
O with glycine and 4-cyanopyridine in aqueous alkaline medium resulted in polymeric complex [Cu(ox)
2
(isn)
2
]·(CONH
2
)
2
]
n
(
1
) (where ox is oxalate, isn is isonicotinamide). Complex
1
has been studied by single crystal X-ray diffraction. Crystal structure reveals that complex
1
is a polymeric structure bridged by oxalate ions. Glycine has been oxidized to oxalate during the course of the reaction along with the in-situ hydrolysis of 4-cyanopyridine to isonicotinamide resulting in complex
1
. Complex
1
was further characterized by molar conductance, UV-Vis and FT-IR spectroscopic techniques. The conversion of glycine to oxalate occurs spontaneously in aqueous solution under ambient conditions.</description><subject>Aqueous solutions</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Conversion</subject><subject>Crystal structure</subject><subject>Glycine</subject><subject>Inorganic Chemistry</subject><subject>Single crystals</subject><subject>Synthesis and Properties of Inorganic Compounds</subject><issn>0036-0236</issn><issn>1531-8613</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp1kM1KAzEUhYMoWKsP4C7gevTmZzLJUgZtC4UWqushk0lkSpvUZCr2AVz5lj6JM1RwIa7u4nzfuXAQuiZwSwjjdysAJoAyQSnkAAU9QSOSM5JJQdgpGg1xNuTn6CKlNQDnUMgRWpbBv9mY2uBxcHiyOZjWW9wFvHjXG91Z3Hq8jDZZb-xAlPvVgn99fuRTusDaN3iWgm9N6Fqvt21jL9GZ05tkr37uGD0_PjyV02y-mMzK-3lmKCM04yCIM-AKqRpwwkqqZKOVyglIZ1TNal0LZ5iqawna1UYUhDNjwdREUqrYGN0ce3cxvO5t6qp12Effv6yoKDhTklPSU-RImRhSitZVu9hudTxUBKphuOrPcL1Dj07qWf9i42_z_9I32e5uWg</recordid><startdate>2022</startdate><enddate>2022</enddate><creator>Gogoi, Anshuman</creator><creator>Bharali, Linkon</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>2022</creationdate><title>Conversion of Glycine to Oxalate in Presence of CuSO4⋅5H2O and Isonicotinamide</title><author>Gogoi, Anshuman ; Bharali, Linkon</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2312-4061fc0f789d0f6e8298da995108fc9b3bab6fc39bb80afbc67143ce0cb182293</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Aqueous solutions</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Conversion</topic><topic>Crystal structure</topic><topic>Glycine</topic><topic>Inorganic Chemistry</topic><topic>Single crystals</topic><topic>Synthesis and Properties of Inorganic Compounds</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gogoi, Anshuman</creatorcontrib><creatorcontrib>Bharali, Linkon</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gogoi, Anshuman</au><au>Bharali, Linkon</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Conversion of Glycine to Oxalate in Presence of CuSO4⋅5H2O and Isonicotinamide</atitle><jtitle>Russian journal of inorganic chemistry</jtitle><stitle>Russ. J. Inorg. Chem</stitle><date>2022</date><risdate>2022</risdate><volume>67</volume><issue>5</issue><spage>608</spage><epage>615</epage><pages>608-615</pages><issn>0036-0236</issn><eissn>1531-8613</eissn><abstract>The reaction of CuSO
4
⋅5H
2
O with glycine and 4-cyanopyridine in aqueous alkaline medium resulted in polymeric complex [Cu(ox)
2
(isn)
2
]·(CONH
2
)
2
]
n
(
1
) (where ox is oxalate, isn is isonicotinamide). Complex
1
has been studied by single crystal X-ray diffraction. Crystal structure reveals that complex
1
is a polymeric structure bridged by oxalate ions. Glycine has been oxidized to oxalate during the course of the reaction along with the in-situ hydrolysis of 4-cyanopyridine to isonicotinamide resulting in complex
1
. Complex
1
was further characterized by molar conductance, UV-Vis and FT-IR spectroscopic techniques. The conversion of glycine to oxalate occurs spontaneously in aqueous solution under ambient conditions.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0036023622050072</doi><tpages>8</tpages></addata></record> |
| fulltext | fulltext |
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| ispartof | Russian journal of inorganic chemistry, 2022, Vol.67 (5), p.608-615 |
| issn | 0036-0236 1531-8613 |
| language | eng |
| recordid | cdi_proquest_journals_2674398421 |
| source | SpringerNature Journals |
| subjects | Aqueous solutions Chemistry Chemistry and Materials Science Conversion Crystal structure Glycine Inorganic Chemistry Single crystals Synthesis and Properties of Inorganic Compounds |
| title | Conversion of Glycine to Oxalate in Presence of CuSO4⋅5H2O and Isonicotinamide |
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