Ni–Fe Cathode Catalyst in Zero-Gap Alkaline Water Electrolysis

Ni–Fe cathode catalyst for zero-gap alkaline water electrolysis was studied. Ni–Fe coatings on nickel foam were prepared by direct current (DC) and pulse current (PC) electrodeposition. The influence of different plating conditions and composition of the electrolyte on the morphology of the samples...

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Veröffentlicht in:Electrocatalysis 2022-07, Vol.13 (4), p.447-456
Hauptverfasser: Záchenská, Jana, Jorík, Vladimír, Vančo, Ľubomír, Mičušík, Matej, Zemanová, Matilda
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container_end_page 456
container_issue 4
container_start_page 447
container_title Electrocatalysis
container_volume 13
creator Záchenská, Jana
Jorík, Vladimír
Vančo, Ľubomír
Mičušík, Matej
Zemanová, Matilda
description Ni–Fe cathode catalyst for zero-gap alkaline water electrolysis was studied. Ni–Fe coatings on nickel foam were prepared by direct current (DC) and pulse current (PC) electrodeposition. The influence of different plating conditions and composition of the electrolyte on the morphology of the samples was studied. It was found that under DC electrodeposition, iron is dominant in the coating. Under PC plating conditions, Ni is the dominant element in Ni–Fe coatings. Ni–Fe coatings prepared under DC electrodeposition provide an effective catalyst in zero-gap electrolysis. Increasing Fe content in the coatings improves the catalytic activity of Ni–Fe catalyst. The study of convenient parameters of PC electrodeposition seems to be complex to reach a highly active surface area. Graphical abstract
doi_str_mv 10.1007/s12678-022-00734-6
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subjects Catalysis
Catalysts
Catalytic activity
Cathodes
Chemistry
Chemistry and Materials Science
Coated electrodes
Coatings
Direct current
Electrochemistry
Electrodeposition
Electrolysis
Energy Systems
Iron
Metal foams
Nickel
Original Research
Physical Chemistry
Plating
title Ni–Fe Cathode Catalyst in Zero-Gap Alkaline Water Electrolysis
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