Programming of micro/nano‐scale information on low switching temperature shape memory film
Shape memory polymer films have been of great interests in storing functional information because of their optical and mechanical variability. High molecular weight polyvinyl acetate (PVAc) is an ideal shape memory material to program micro‐ and nano‐scale patterns on the surface of highly transpare...
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| Veröffentlicht in: | Journal of applied polymer science 2022-07, Vol.139 (28), p.n/a |
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| container_title | Journal of applied polymer science |
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| creator | Zhang, Ziyou Li, Zhenpeng Sun, Ruolin Olah, Andrew Baer, Eric |
| description | Shape memory polymer films have been of great interests in storing functional information because of their optical and mechanical variability. High molecular weight polyvinyl acetate (PVAc) is an ideal shape memory material to program micro‐ and nano‐scale patterns on the surface of highly transparent films. By blending PVAc with polyethylene glycol (PEG) plasticizer, lower switching temperatures could be achieved. We develop a shape memory PVAc/PEG blend film system featuring a unique design by taking advantage of multiple switching temperatures. The effect of the PEG composition was studied relative to different surface patterns, switching temperatures and efficiency of information retrieval by utilizing differential scanning calorimetry and UV/Vis analysis. The results indicate that higher contents of PEG enhanced the recovery efficiency of both the micro‐scale and nano‐scale patterns and the corresponding optical properties. Furthermore, a dual switching shape memory film was developed enabling multiple switching temperatures that can lead to versatile applications. |
| doi_str_mv | 10.1002/app.52516 |
| format | Article |
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High molecular weight polyvinyl acetate (PVAc) is an ideal shape memory material to program micro‐ and nano‐scale patterns on the surface of highly transparent films. By blending PVAc with polyethylene glycol (PEG) plasticizer, lower switching temperatures could be achieved. We develop a shape memory PVAc/PEG blend film system featuring a unique design by taking advantage of multiple switching temperatures. The effect of the PEG composition was studied relative to different surface patterns, switching temperatures and efficiency of information retrieval by utilizing differential scanning calorimetry and UV/Vis analysis. The results indicate that higher contents of PEG enhanced the recovery efficiency of both the micro‐scale and nano‐scale patterns and the corresponding optical properties. 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High molecular weight polyvinyl acetate (PVAc) is an ideal shape memory material to program micro‐ and nano‐scale patterns on the surface of highly transparent films. By blending PVAc with polyethylene glycol (PEG) plasticizer, lower switching temperatures could be achieved. We develop a shape memory PVAc/PEG blend film system featuring a unique design by taking advantage of multiple switching temperatures. The effect of the PEG composition was studied relative to different surface patterns, switching temperatures and efficiency of information retrieval by utilizing differential scanning calorimetry and UV/Vis analysis. The results indicate that higher contents of PEG enhanced the recovery efficiency of both the micro‐scale and nano‐scale patterns and the corresponding optical properties. Furthermore, a dual switching shape memory film was developed enabling multiple switching temperatures that can lead to versatile applications.</description><subject>Differential scanning calorimetry</subject><subject>Information retrieval</subject><subject>Materials science</subject><subject>Optical properties</subject><subject>packaging</subject><subject>Polyethylene glycol</subject><subject>Polymer films</subject><subject>Polymers</subject><subject>Polyvinyl acetates</subject><subject>sensors and actuators</subject><subject>Shape memory</subject><subject>Switching</subject><subject>thermal properties</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><sourceid>24P</sourceid><recordid>eNp1kMtKQzEQhoMoWKsL3yDgysVpc2luyyLeoGAXuhNCepq0KScnx-SU0p2P4DP6JKbWrTAwM8z3zzA_ANcYjTBCZGy6bsQIw_wEDDBSoppwIk_BoMxwJZVi5-Ai5w1CGDPEB-B9nuIqmRB8u4LRweDrFMetaeP351euTWOhb11MwfQ-trBEE3cw73xfrw-S3obOJtNvk4V5bToLgw0x7aHzTbgEZ8402V795SF4e7h_vXuqZi-Pz3fTWVWTieAVoUiKmhBniKvxUkhpSk-FdcrghbSs1IYvGbZW8AUl0nFFsFA1UhI5Q-kQ3Bz3dil-bG3u9SZuU1tOasIFVUxSygp1e6TKhzkn63SXfDBprzHSB_N0MU__mlfY8ZHd-cbu_wf1dD4_Kn4AaDZyhA</recordid><startdate>20220720</startdate><enddate>20220720</enddate><creator>Zhang, Ziyou</creator><creator>Li, Zhenpeng</creator><creator>Sun, Ruolin</creator><creator>Olah, Andrew</creator><creator>Baer, Eric</creator><general>John Wiley & Sons, Inc</general><general>Wiley Subscription Services, Inc</general><scope>24P</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0001-9026-9676</orcidid></search><sort><creationdate>20220720</creationdate><title>Programming of micro/nano‐scale information on low switching temperature shape memory film</title><author>Zhang, Ziyou ; Li, Zhenpeng ; Sun, Ruolin ; Olah, Andrew ; Baer, Eric</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2476-23087c22fa2fc1d788a87c37ef9a1b8e5c37a6d51ee76b328f692179c0980fa33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Differential scanning calorimetry</topic><topic>Information retrieval</topic><topic>Materials science</topic><topic>Optical properties</topic><topic>packaging</topic><topic>Polyethylene glycol</topic><topic>Polymer films</topic><topic>Polymers</topic><topic>Polyvinyl acetates</topic><topic>sensors and actuators</topic><topic>Shape memory</topic><topic>Switching</topic><topic>thermal properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhang, Ziyou</creatorcontrib><creatorcontrib>Li, Zhenpeng</creatorcontrib><creatorcontrib>Sun, Ruolin</creatorcontrib><creatorcontrib>Olah, Andrew</creatorcontrib><creatorcontrib>Baer, Eric</creatorcontrib><collection>Wiley Online Library Open Access</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, Ziyou</au><au>Li, Zhenpeng</au><au>Sun, Ruolin</au><au>Olah, Andrew</au><au>Baer, Eric</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Programming of micro/nano‐scale information on low switching temperature shape memory film</atitle><jtitle>Journal of applied polymer science</jtitle><date>2022-07-20</date><risdate>2022</risdate><volume>139</volume><issue>28</issue><epage>n/a</epage><issn>0021-8995</issn><eissn>1097-4628</eissn><abstract>Shape memory polymer films have been of great interests in storing functional information because of their optical and mechanical variability. High molecular weight polyvinyl acetate (PVAc) is an ideal shape memory material to program micro‐ and nano‐scale patterns on the surface of highly transparent films. By blending PVAc with polyethylene glycol (PEG) plasticizer, lower switching temperatures could be achieved. We develop a shape memory PVAc/PEG blend film system featuring a unique design by taking advantage of multiple switching temperatures. The effect of the PEG composition was studied relative to different surface patterns, switching temperatures and efficiency of information retrieval by utilizing differential scanning calorimetry and UV/Vis analysis. The results indicate that higher contents of PEG enhanced the recovery efficiency of both the micro‐scale and nano‐scale patterns and the corresponding optical properties. 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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Differential scanning calorimetry Information retrieval Materials science Optical properties packaging Polyethylene glycol Polymer films Polymers Polyvinyl acetates sensors and actuators Shape memory Switching thermal properties |
| title | Programming of micro/nano‐scale information on low switching temperature shape memory film |
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