Simultaneous improvement of magnetic-field-induced working temperature and mechanical properties in Ni–Mn–In shape memory alloy

Ni–Mn–In magnetic shape memory alloys, which can be stimulated by an external magnetic field, exhibit a fast response and have aroused wide attention in the field of electro-mechanical actuators. However, the low working temperature and the inherent brittleness severely limit their application scena...

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Veröffentlicht in:AIP advances 2022-06, Vol.12 (6), p.065107-065107-8
Hauptverfasser: Ma, Tianyou, Zhang, Kun, Han, Binglun, Zhao, Lei, Zhao, Wenbin, Wang, Cheng, Liu, Rui, Tian, Xiaohua, Tan, Changlong
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container_issue 6
container_start_page 065107
container_title AIP advances
container_volume 12
creator Ma, Tianyou
Zhang, Kun
Han, Binglun
Zhao, Lei
Zhao, Wenbin
Wang, Cheng
Liu, Rui
Tian, Xiaohua
Tan, Changlong
description Ni–Mn–In magnetic shape memory alloys, which can be stimulated by an external magnetic field, exhibit a fast response and have aroused wide attention in the field of electro-mechanical actuators. However, the low working temperature and the inherent brittleness severely limit their application scenarios. Here, an effective strategy is proposed to improve the magnetic-field-induced working temperature and mechanical properties in Ni–Mn–In shape memory alloys. We predict that the Ni16Mn12In4 alloy with Pt doping can solve the problems simultaneously through a comprehensive first-principles study. The calculations show that Pt occupying Ni sites can increase the martensitic temperature (TM) and Curie temperature (TC) simultaneously. TM and TC of Ni14Mn12In4Pt2 are predicted to be as high as 440 and 476 K, respectively. This is mainly due to the increased phase stability of the martensite and Pt–Mn bonds having stronger ferromagnetic exchange effects than Ni–Mn bonds after Pt doping. Moreover, according to the increase of B/G and v after Pt doping, it can be concluded that the mechanical properties of the alloy have been improved.
doi_str_mv 10.1063/5.0092428
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However, the low working temperature and the inherent brittleness severely limit their application scenarios. Here, an effective strategy is proposed to improve the magnetic-field-induced working temperature and mechanical properties in Ni–Mn–In shape memory alloys. We predict that the Ni16Mn12In4 alloy with Pt doping can solve the problems simultaneously through a comprehensive first-principles study. The calculations show that Pt occupying Ni sites can increase the martensitic temperature (TM) and Curie temperature (TC) simultaneously. TM and TC of Ni14Mn12In4Pt2 are predicted to be as high as 440 and 476 K, respectively. This is mainly due to the increased phase stability of the martensite and Pt–Mn bonds having stronger ferromagnetic exchange effects than Ni–Mn bonds after Pt doping. Moreover, according to the increase of B/G and v after Pt doping, it can be concluded that the mechanical properties of the alloy have been improved.</description><identifier>ISSN: 2158-3226</identifier><identifier>EISSN: 2158-3226</identifier><identifier>DOI: 10.1063/5.0092428</identifier><identifier>CODEN: AAIDBI</identifier><language>eng</language><publisher>Melville: American Institute of Physics</publisher><subject>Actuators ; Alloys ; Bonding strength ; Curie temperature ; Doping ; Ferromagnetism ; First principles ; Magnetic properties ; Manganese ; Martensite ; Martensitic transformations ; Mechanical properties ; Nickel ; Phase stability ; Shape memory alloys</subject><ispartof>AIP advances, 2022-06, Vol.12 (6), p.065107-065107-8</ispartof><rights>Author(s)</rights><rights>2022 Author(s). 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subjects Actuators
Alloys
Bonding strength
Curie temperature
Doping
Ferromagnetism
First principles
Magnetic properties
Manganese
Martensite
Martensitic transformations
Mechanical properties
Nickel
Phase stability
Shape memory alloys
title Simultaneous improvement of magnetic-field-induced working temperature and mechanical properties in Ni–Mn–In shape memory alloy
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