Simultaneous improvement of magnetic-field-induced working temperature and mechanical properties in Ni–Mn–In shape memory alloy
Ni–Mn–In magnetic shape memory alloys, which can be stimulated by an external magnetic field, exhibit a fast response and have aroused wide attention in the field of electro-mechanical actuators. However, the low working temperature and the inherent brittleness severely limit their application scena...
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Veröffentlicht in: | AIP advances 2022-06, Vol.12 (6), p.065107-065107-8 |
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creator | Ma, Tianyou Zhang, Kun Han, Binglun Zhao, Lei Zhao, Wenbin Wang, Cheng Liu, Rui Tian, Xiaohua Tan, Changlong |
description | Ni–Mn–In magnetic shape memory alloys, which can be stimulated by an external magnetic field, exhibit a fast response and have aroused wide attention in the field of electro-mechanical actuators. However, the low working temperature and the inherent brittleness severely limit their application scenarios. Here, an effective strategy is proposed to improve the magnetic-field-induced working temperature and mechanical properties in Ni–Mn–In shape memory alloys. We predict that the Ni16Mn12In4 alloy with Pt doping can solve the problems simultaneously through a comprehensive first-principles study. The calculations show that Pt occupying Ni sites can increase the martensitic temperature (TM) and Curie temperature (TC) simultaneously. TM and TC of Ni14Mn12In4Pt2 are predicted to be as high as 440 and 476 K, respectively. This is mainly due to the increased phase stability of the martensite and Pt–Mn bonds having stronger ferromagnetic exchange effects than Ni–Mn bonds after Pt doping. Moreover, according to the increase of B/G and v after Pt doping, it can be concluded that the mechanical properties of the alloy have been improved. |
doi_str_mv | 10.1063/5.0092428 |
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However, the low working temperature and the inherent brittleness severely limit their application scenarios. Here, an effective strategy is proposed to improve the magnetic-field-induced working temperature and mechanical properties in Ni–Mn–In shape memory alloys. We predict that the Ni16Mn12In4 alloy with Pt doping can solve the problems simultaneously through a comprehensive first-principles study. The calculations show that Pt occupying Ni sites can increase the martensitic temperature (TM) and Curie temperature (TC) simultaneously. TM and TC of Ni14Mn12In4Pt2 are predicted to be as high as 440 and 476 K, respectively. This is mainly due to the increased phase stability of the martensite and Pt–Mn bonds having stronger ferromagnetic exchange effects than Ni–Mn bonds after Pt doping. Moreover, according to the increase of B/G and v after Pt doping, it can be concluded that the mechanical properties of the alloy have been improved.</description><identifier>ISSN: 2158-3226</identifier><identifier>EISSN: 2158-3226</identifier><identifier>DOI: 10.1063/5.0092428</identifier><identifier>CODEN: AAIDBI</identifier><language>eng</language><publisher>Melville: American Institute of Physics</publisher><subject>Actuators ; Alloys ; Bonding strength ; Curie temperature ; Doping ; Ferromagnetism ; First principles ; Magnetic properties ; Manganese ; Martensite ; Martensitic transformations ; Mechanical properties ; Nickel ; Phase stability ; Shape memory alloys</subject><ispartof>AIP advances, 2022-06, Vol.12 (6), p.065107-065107-8</ispartof><rights>Author(s)</rights><rights>2022 Author(s). All article content, except where otherwise noted, is licensed under a Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4098-7ea2830f3a044f9c2d477bc8087937ba62065508a65820cb1fe2f32fe759ef7c3</citedby><cites>FETCH-LOGICAL-c4098-7ea2830f3a044f9c2d477bc8087937ba62065508a65820cb1fe2f32fe759ef7c3</cites><orcidid>0000-0002-6290-2080</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,782,786,866,2104,27931,27932</link.rule.ids></links><search><creatorcontrib>Ma, Tianyou</creatorcontrib><creatorcontrib>Zhang, Kun</creatorcontrib><creatorcontrib>Han, Binglun</creatorcontrib><creatorcontrib>Zhao, Lei</creatorcontrib><creatorcontrib>Zhao, Wenbin</creatorcontrib><creatorcontrib>Wang, Cheng</creatorcontrib><creatorcontrib>Liu, Rui</creatorcontrib><creatorcontrib>Tian, Xiaohua</creatorcontrib><creatorcontrib>Tan, Changlong</creatorcontrib><title>Simultaneous improvement of magnetic-field-induced working temperature and mechanical properties in Ni–Mn–In shape memory alloy</title><title>AIP advances</title><description>Ni–Mn–In magnetic shape memory alloys, which can be stimulated by an external magnetic field, exhibit a fast response and have aroused wide attention in the field of electro-mechanical actuators. However, the low working temperature and the inherent brittleness severely limit their application scenarios. Here, an effective strategy is proposed to improve the magnetic-field-induced working temperature and mechanical properties in Ni–Mn–In shape memory alloys. We predict that the Ni16Mn12In4 alloy with Pt doping can solve the problems simultaneously through a comprehensive first-principles study. The calculations show that Pt occupying Ni sites can increase the martensitic temperature (TM) and Curie temperature (TC) simultaneously. TM and TC of Ni14Mn12In4Pt2 are predicted to be as high as 440 and 476 K, respectively. This is mainly due to the increased phase stability of the martensite and Pt–Mn bonds having stronger ferromagnetic exchange effects than Ni–Mn bonds after Pt doping. Moreover, according to the increase of B/G and v after Pt doping, it can be concluded that the mechanical properties of the alloy have been improved.</description><subject>Actuators</subject><subject>Alloys</subject><subject>Bonding strength</subject><subject>Curie temperature</subject><subject>Doping</subject><subject>Ferromagnetism</subject><subject>First principles</subject><subject>Magnetic properties</subject><subject>Manganese</subject><subject>Martensite</subject><subject>Martensitic transformations</subject><subject>Mechanical properties</subject><subject>Nickel</subject><subject>Phase stability</subject><subject>Shape memory alloys</subject><issn>2158-3226</issn><issn>2158-3226</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><sourceid>DOA</sourceid><recordid>eNp9kc1u1DAQgCMEElXpgTewxAmkFNuxY_uIKn5WKvRAe7YmznjrJbGDk7TaGxKPwBvyJBi2apGQ8MG2PN98ntFU1XNGTxltm9fylFLDBdePqiPOpK4bztvHf92fVifzvKNlCcOoFkfV989hXIcFIqZ1JmGccrrBEeNCkicjbCMuwdU-4NDXIfarw57cpvwlxC1ZcJwww7JmJBB7MqK7hhgcDKRoSmgJWJyRfAo_v_34GMu2iWS-hgkLO6a8JzAMaf-seuJhmPHk7jyurt69vTz7UJ9fvN-cvTmvnaBG1wqB64b6BqgQ3jjeC6U6p6lWplEdtJy2UlINrdScuo555L7hHpU06JVrjqvNwdsn2NkphxHy3iYI9s9DylsLpWY3oO00bTsqHRqpRccEaKUYA--196aTorheHFyl068rzovdpTXHUr7lrWpaw0tGoV4eKJfTPGf0978yan-PzEp7N7LCvjqwswsLLCHFe_gm5QfQTr3_H_yv-Rdwr6el</recordid><startdate>20220601</startdate><enddate>20220601</enddate><creator>Ma, Tianyou</creator><creator>Zhang, Kun</creator><creator>Han, Binglun</creator><creator>Zhao, Lei</creator><creator>Zhao, Wenbin</creator><creator>Wang, Cheng</creator><creator>Liu, Rui</creator><creator>Tian, Xiaohua</creator><creator>Tan, Changlong</creator><general>American Institute of Physics</general><general>AIP Publishing LLC</general><scope>AJDQP</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8FD</scope><scope>H8D</scope><scope>L7M</scope><scope>DOA</scope><orcidid>https://orcid.org/0000-0002-6290-2080</orcidid></search><sort><creationdate>20220601</creationdate><title>Simultaneous improvement of magnetic-field-induced working temperature and mechanical properties in Ni–Mn–In shape memory alloy</title><author>Ma, Tianyou ; Zhang, Kun ; Han, Binglun ; Zhao, Lei ; Zhao, Wenbin ; Wang, Cheng ; Liu, Rui ; Tian, Xiaohua ; Tan, Changlong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4098-7ea2830f3a044f9c2d477bc8087937ba62065508a65820cb1fe2f32fe759ef7c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Actuators</topic><topic>Alloys</topic><topic>Bonding strength</topic><topic>Curie temperature</topic><topic>Doping</topic><topic>Ferromagnetism</topic><topic>First principles</topic><topic>Magnetic properties</topic><topic>Manganese</topic><topic>Martensite</topic><topic>Martensitic transformations</topic><topic>Mechanical properties</topic><topic>Nickel</topic><topic>Phase stability</topic><topic>Shape memory alloys</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ma, Tianyou</creatorcontrib><creatorcontrib>Zhang, Kun</creatorcontrib><creatorcontrib>Han, Binglun</creatorcontrib><creatorcontrib>Zhao, Lei</creatorcontrib><creatorcontrib>Zhao, Wenbin</creatorcontrib><creatorcontrib>Wang, Cheng</creatorcontrib><creatorcontrib>Liu, Rui</creatorcontrib><creatorcontrib>Tian, Xiaohua</creatorcontrib><creatorcontrib>Tan, Changlong</creatorcontrib><collection>AIP Open Access Journals</collection><collection>CrossRef</collection><collection>Technology Research Database</collection><collection>Aerospace Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>DOAJ Directory of Open Access Journals</collection><jtitle>AIP advances</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ma, Tianyou</au><au>Zhang, Kun</au><au>Han, Binglun</au><au>Zhao, Lei</au><au>Zhao, Wenbin</au><au>Wang, Cheng</au><au>Liu, Rui</au><au>Tian, Xiaohua</au><au>Tan, Changlong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Simultaneous improvement of magnetic-field-induced working temperature and mechanical properties in Ni–Mn–In shape memory alloy</atitle><jtitle>AIP advances</jtitle><date>2022-06-01</date><risdate>2022</risdate><volume>12</volume><issue>6</issue><spage>065107</spage><epage>065107-8</epage><pages>065107-065107-8</pages><issn>2158-3226</issn><eissn>2158-3226</eissn><coden>AAIDBI</coden><abstract>Ni–Mn–In magnetic shape memory alloys, which can be stimulated by an external magnetic field, exhibit a fast response and have aroused wide attention in the field of electro-mechanical actuators. However, the low working temperature and the inherent brittleness severely limit their application scenarios. Here, an effective strategy is proposed to improve the magnetic-field-induced working temperature and mechanical properties in Ni–Mn–In shape memory alloys. We predict that the Ni16Mn12In4 alloy with Pt doping can solve the problems simultaneously through a comprehensive first-principles study. The calculations show that Pt occupying Ni sites can increase the martensitic temperature (TM) and Curie temperature (TC) simultaneously. TM and TC of Ni14Mn12In4Pt2 are predicted to be as high as 440 and 476 K, respectively. This is mainly due to the increased phase stability of the martensite and Pt–Mn bonds having stronger ferromagnetic exchange effects than Ni–Mn bonds after Pt doping. Moreover, according to the increase of B/G and v after Pt doping, it can be concluded that the mechanical properties of the alloy have been improved.</abstract><cop>Melville</cop><pub>American Institute of Physics</pub><doi>10.1063/5.0092428</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0002-6290-2080</orcidid><oa>free_for_read</oa></addata></record> |
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subjects | Actuators Alloys Bonding strength Curie temperature Doping Ferromagnetism First principles Magnetic properties Manganese Martensite Martensitic transformations Mechanical properties Nickel Phase stability Shape memory alloys |
title | Simultaneous improvement of magnetic-field-induced working temperature and mechanical properties in Ni–Mn–In shape memory alloy |
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