Integrating Terminal CoBrn Salts into a 2D Cobalt(II) Coordination Polymer to Promote the β‐(E)−Selective Hydroboration of Alkynes

In the present study, 2D Co(II) coordination polymers (CP‐1), which integrate terminal CoBrn (CoBr2 and CoBr3) sites immobilized on the framework, are synthesized at the gram level. As a special heterogeneous catalyst, CP‐1 shows regioselectivity (β:α>99:1) and stereoselectivity (only E configura...

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Veröffentlicht in:	Advanced synthesis & catalysis 2022-06, Vol.364 (11), p.1873-1878
Hauptverfasser:	Jia, Jun‐Song, Wu, Tai‐Xue, Fu, Yi‐Jia, Hu, Zhi‐Rong, Tang, Hai‐Tao, Pan, Ying‐Ming, Huang, Fu‐Ping
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkynes Catalysts Coordination polymer Coordination polymers Heterogeneous catalysis Hydroboration Regioselectivity Selectivity Stereoselectivity Substrates
Online-Zugang:	Volltext
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