ZnO nanowires and nanorods based ZnO/WO3/Pt heterojunction for efficient photocatalytic degradation of estriol (E3) hormone

•ZnO nanowires and nanorods were successfully synthesized by hydrothermal method.•ZnO based WO3/Pt heterojunctions were fabricated by spray method.•Efficient E3 degradation using continuous Drip Flow Biofilm Reactor (under UV light).•The photoactivity of heterostructures was quantified using facile...

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Veröffentlicht in:Materials letters 2022-07, Vol.319, p.132291, Article 132291
Hauptverfasser: Yasir, Muhammad, Masar, Milan, Sopik, Tomas, Ali, Hassan, Urbanek, Michal, Antos, Jan, Machovsky, Michal, Kuritka, Ivo
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container_start_page 132291
container_title Materials letters
container_volume 319
creator Yasir, Muhammad
Masar, Milan
Sopik, Tomas
Ali, Hassan
Urbanek, Michal
Antos, Jan
Machovsky, Michal
Kuritka, Ivo
description •ZnO nanowires and nanorods were successfully synthesized by hydrothermal method.•ZnO based WO3/Pt heterojunctions were fabricated by spray method.•Efficient E3 degradation using continuous Drip Flow Biofilm Reactor (under UV light).•The photoactivity of heterostructures was quantified using facile HPLC method.•Highest efficiency was for ZnOnw/WO3/Pt (86.2%) while least for ZnOnr (22.9%). In this report, ZnO nanowires and nanorods based ZnO/WO3/Pt heterojunction were successfully prepared on a glass substrates via a facile hydrothermal growth method followed by spraying. The photocatalytic performance was evaluated by the degradation of estriol (E3) hormone under UV light irradiation (∼365 nm) in a closed continuous flow reactor. The as-prepared samples achieved an excellent photodegradation rate in the range of 23–37% and 63–86% for the nanorods and nanowires morphology, respectively. This article provides a new insight into the construction of suitable geometrically optimized heterojunction for the remediation of persistent bio toxicants.
doi_str_mv 10.1016/j.matlet.2022.132291
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source ScienceDirect Journals (5 years ago - present)
subjects Continuous flow
Degradation
Estrogenic hormone
Glass substrates
Heterojunction
Heterojunctions
Light irradiation
Materials science
Nanorods
Nanowires
Photocatalysis
Photodegradation
Spraying
Ultraviolet radiation
Zinc oxide
ZnO
title ZnO nanowires and nanorods based ZnO/WO3/Pt heterojunction for efficient photocatalytic degradation of estriol (E3) hormone
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