Fluorescence and stimuli-responsive performance of polymer composites filled with tetraphenylethene derivatives
In this study, a series of tetraphenylethene (TPE) derivatives with 3-butenloxy moieties were synthesized. The developed TPE with different numbers of substituent groups showed controlled aggregation-induced emission performance and variable fluorescence properties, and theoretical calculations were...
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| Veröffentlicht in: | Polymer chemistry 2022-05, Vol.13 (21), p.3126-3135 |
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| container_title | Polymer chemistry |
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| creator | Yang, Fang-Hong Hao, Bin Yue, Xiu Ma, Peng-Cheng |
| description | In this study, a series of tetraphenylethene (TPE) derivatives with 3-butenloxy moieties were synthesized. The developed TPE with different numbers of substituent groups showed controlled aggregation-induced emission performance and variable fluorescence properties, and theoretical calculations were carried out to explain these phenomena. TPE and its derivatives were further employed to construct composites through physical blending or a hydrosilylation reaction between the TPE derivative and polydimethylsiloxane. It was found that chemical bonding could improve the solubility of TPE derivatives in the polymer matrix without obvious phase separation. The fluorescence intensity of composites filled with TPE derivatives decreased with increasing temperature or mechanical force, thus giving the material a stimuli-responsive fluorescence property.
In this study, the effect of interactions between tetraphenylethene derivatives and a polymer matrix on the stimuli-responsive property of polydimethylsiloxane-based composites was revealed. |
| doi_str_mv | 10.1039/d2py00396a |
| format | Article |
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In this study, the effect of interactions between tetraphenylethene derivatives and a polymer matrix on the stimuli-responsive property of polydimethylsiloxane-based composites was revealed.</description><identifier>ISSN: 1759-9954</identifier><identifier>EISSN: 1759-9962</identifier><identifier>DOI: 10.1039/d2py00396a</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Chemical bonds ; Emissions control ; Fluorescence ; Hydrosilylation ; Mathematical analysis ; Phase separation ; Polydimethylsiloxane ; Polymer chemistry ; Polymer matrix composites ; Polymers ; Stimuli</subject><ispartof>Polymer chemistry, 2022-05, Vol.13 (21), p.3126-3135</ispartof><rights>Copyright Royal Society of Chemistry 2022</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c281t-e18ba40fe9c4c034a6b859caec63acbb20c4313511c3842f4f86a9e5983774373</citedby><cites>FETCH-LOGICAL-c281t-e18ba40fe9c4c034a6b859caec63acbb20c4313511c3842f4f86a9e5983774373</cites><orcidid>0000-0002-4112-9535 ; 0000-0003-3176-7514</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Yang, Fang-Hong</creatorcontrib><creatorcontrib>Hao, Bin</creatorcontrib><creatorcontrib>Yue, Xiu</creatorcontrib><creatorcontrib>Ma, Peng-Cheng</creatorcontrib><title>Fluorescence and stimuli-responsive performance of polymer composites filled with tetraphenylethene derivatives</title><title>Polymer chemistry</title><description>In this study, a series of tetraphenylethene (TPE) derivatives with 3-butenloxy moieties were synthesized. The developed TPE with different numbers of substituent groups showed controlled aggregation-induced emission performance and variable fluorescence properties, and theoretical calculations were carried out to explain these phenomena. TPE and its derivatives were further employed to construct composites through physical blending or a hydrosilylation reaction between the TPE derivative and polydimethylsiloxane. It was found that chemical bonding could improve the solubility of TPE derivatives in the polymer matrix without obvious phase separation. The fluorescence intensity of composites filled with TPE derivatives decreased with increasing temperature or mechanical force, thus giving the material a stimuli-responsive fluorescence property.
In this study, the effect of interactions between tetraphenylethene derivatives and a polymer matrix on the stimuli-responsive property of polydimethylsiloxane-based composites was revealed.</description><subject>Chemical bonds</subject><subject>Emissions control</subject><subject>Fluorescence</subject><subject>Hydrosilylation</subject><subject>Mathematical analysis</subject><subject>Phase separation</subject><subject>Polydimethylsiloxane</subject><subject>Polymer chemistry</subject><subject>Polymer matrix composites</subject><subject>Polymers</subject><subject>Stimuli</subject><issn>1759-9954</issn><issn>1759-9962</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNpFkM1LxDAUxIMouKx78S4EvAnVfPUjx2V1VRD0oAdPJU1f2SxtU5N0pf-9WVfWd5lh-DEPBqFLSm4p4fKuZsNEosnUCZrRPJWJlBk7PfpUnKOF91sSj1PBeDZDdt2O1oHX0GvAqq-xD6YbW5PEcLC9NzvAA7jGuk7tEdvgwbZTBw5r2w3WmwAeN6ZtocbfJmxwgODUsIF-aiFEAVyDMzsVYpW_QGeNaj0s_nSOPtYP76un5OX18Xm1fEk0K2hIgBaVEqQBqYUmXKisKlKpFeiMK11VjGjBKU8p1bwQrBFNkSkJqSx4ngue8zm6PvQOzn6N4EO5taPr48uSZTlNJWdpEambA6Wd9d5BUw7OdMpNJSXlftPynr19_m66jPDVAXZeH7n_zfkPzm52Lg</recordid><startdate>20220531</startdate><enddate>20220531</enddate><creator>Yang, Fang-Hong</creator><creator>Hao, Bin</creator><creator>Yue, Xiu</creator><creator>Ma, Peng-Cheng</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0002-4112-9535</orcidid><orcidid>https://orcid.org/0000-0003-3176-7514</orcidid></search><sort><creationdate>20220531</creationdate><title>Fluorescence and stimuli-responsive performance of polymer composites filled with tetraphenylethene derivatives</title><author>Yang, Fang-Hong ; Hao, Bin ; Yue, Xiu ; Ma, Peng-Cheng</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c281t-e18ba40fe9c4c034a6b859caec63acbb20c4313511c3842f4f86a9e5983774373</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Chemical bonds</topic><topic>Emissions control</topic><topic>Fluorescence</topic><topic>Hydrosilylation</topic><topic>Mathematical analysis</topic><topic>Phase separation</topic><topic>Polydimethylsiloxane</topic><topic>Polymer chemistry</topic><topic>Polymer matrix composites</topic><topic>Polymers</topic><topic>Stimuli</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yang, Fang-Hong</creatorcontrib><creatorcontrib>Hao, Bin</creatorcontrib><creatorcontrib>Yue, Xiu</creatorcontrib><creatorcontrib>Ma, Peng-Cheng</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Polymer chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yang, Fang-Hong</au><au>Hao, Bin</au><au>Yue, Xiu</au><au>Ma, Peng-Cheng</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Fluorescence and stimuli-responsive performance of polymer composites filled with tetraphenylethene derivatives</atitle><jtitle>Polymer chemistry</jtitle><date>2022-05-31</date><risdate>2022</risdate><volume>13</volume><issue>21</issue><spage>3126</spage><epage>3135</epage><pages>3126-3135</pages><issn>1759-9954</issn><eissn>1759-9962</eissn><abstract>In this study, a series of tetraphenylethene (TPE) derivatives with 3-butenloxy moieties were synthesized. The developed TPE with different numbers of substituent groups showed controlled aggregation-induced emission performance and variable fluorescence properties, and theoretical calculations were carried out to explain these phenomena. TPE and its derivatives were further employed to construct composites through physical blending or a hydrosilylation reaction between the TPE derivative and polydimethylsiloxane. It was found that chemical bonding could improve the solubility of TPE derivatives in the polymer matrix without obvious phase separation. The fluorescence intensity of composites filled with TPE derivatives decreased with increasing temperature or mechanical force, thus giving the material a stimuli-responsive fluorescence property.
In this study, the effect of interactions between tetraphenylethene derivatives and a polymer matrix on the stimuli-responsive property of polydimethylsiloxane-based composites was revealed.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d2py00396a</doi><tpages>1</tpages><orcidid>https://orcid.org/0000-0002-4112-9535</orcidid><orcidid>https://orcid.org/0000-0003-3176-7514</orcidid></addata></record> |
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| source | Royal Society Of Chemistry Journals |
| subjects | Chemical bonds Emissions control Fluorescence Hydrosilylation Mathematical analysis Phase separation Polydimethylsiloxane Polymer chemistry Polymer matrix composites Polymers Stimuli |
| title | Fluorescence and stimuli-responsive performance of polymer composites filled with tetraphenylethene derivatives |
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