Two New Borates Built by Different Types of {B9} Cluster Units
Two new belt-like borates Na 4 [B 9 O 14 (OH) 3 ]·0.5H 2 O( 1 ) and Na 5 [B 9 O 14 (OH) 4 ]( 2 ) have been synthesized under solvothermal conditions. Both compounds contain unprecedented B 9 O 16 (OH) n ( n +5)− [ n =3( 1 ), 4( 2 )] clusters, which are constructed from four B 3 O 3 rings via three B...
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| Veröffentlicht in: | Chemical research in Chinese universities 2022-06, Vol.38 (3), p.744-749 |
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| creator | Chen, Juan Wang, Jiajia Chen, Chongan Yang, Guoyu |
| description | Two new belt-like borates Na
4
[B
9
O
14
(OH)
3
]·0.5H
2
O(
1
) and Na
5
[B
9
O
14
(OH)
4
](
2
) have been synthesized under solvothermal conditions. Both compounds contain unprecedented B
9
O
16
(OH)
n
(
n
+5)−
[
n
=3(
1
), 4(
2
)] clusters, which are constructed from four B
3
O
3
rings
via
three BO
4
tetrahedra. Compound
1
exhibits a rare 1D belt with two types of 8-membered ring(MR) windows based on B
9
O
16
(OH)
3
8−
clusters. Compound
2
features two different 1D belts built by different B
9
O
16
(OH)
4
9−
units, which is first discovered in borate family. UV-Vis diffuse reflectance spectra reveal that compounds
1
and
2
have the cut-off edges below 190 nm, indicating that they may have potential application in deep UV(DUV) region. |
| doi_str_mv | 10.1007/s40242-022-1473-7 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2670626116</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2670626116</sourcerecordid><originalsourceid>FETCH-LOGICAL-c316t-cd8045bdcce2bb8250179369378febb17ec2f304c3acfe66b8b9c59bb66c0bdf3</originalsourceid><addsrcrecordid>eNp1kE1LAzEURYMoWKs_wF3AdfQlmUkmG8HWTyi6ma7DJE1kSp2pSYZSxP9uygiuXL3FPfc-OAhdUrimAPImFsAKRoAxQgvJiTxCE8YoEE4lPUaTDJVEQQGn6CzGNQBXQhQTdFvvevzqdnjWhya5iGdDu0nY7PF9670Lrku43m9z0Hv8NVPfeL4ZYnIBL7s2xXN04ptNdBe_d4qWjw_1_Jks3p5e5ncLYjkVidhVBUVpVtY6ZkzFSqBScaG4rLwzhkpnmedQWN5Y74QwlVG2VMYIYcGsPJ-iq3F3G_rPwcWk1_0QuvxSMyFBMEGpyBQdKRv6GIPzehvajybsNQV90KRHTTpr0gdNWuYOGzsxs927C3_L_5d-AARqaXU</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2670626116</pqid></control><display><type>article</type><title>Two New Borates Built by Different Types of {B9} Cluster Units</title><source>SpringerLink Journals (MCLS)</source><creator>Chen, Juan ; Wang, Jiajia ; Chen, Chongan ; Yang, Guoyu</creator><creatorcontrib>Chen, Juan ; Wang, Jiajia ; Chen, Chongan ; Yang, Guoyu</creatorcontrib><description>Two new belt-like borates Na
4
[B
9
O
14
(OH)
3
]·0.5H
2
O(
1
) and Na
5
[B
9
O
14
(OH)
4
](
2
) have been synthesized under solvothermal conditions. Both compounds contain unprecedented B
9
O
16
(OH)
n
(
n
+5)−
[
n
=3(
1
), 4(
2
)] clusters, which are constructed from four B
3
O
3
rings
via
three BO
4
tetrahedra. Compound
1
exhibits a rare 1D belt with two types of 8-membered ring(MR) windows based on B
9
O
16
(OH)
3
8−
clusters. Compound
2
features two different 1D belts built by different B
9
O
16
(OH)
4
9−
units, which is first discovered in borate family. UV-Vis diffuse reflectance spectra reveal that compounds
1
and
2
have the cut-off edges below 190 nm, indicating that they may have potential application in deep UV(DUV) region.</description><identifier>ISSN: 1005-9040</identifier><identifier>EISSN: 2210-3171</identifier><identifier>DOI: 10.1007/s40242-022-1473-7</identifier><language>eng</language><publisher>Changchun: Jilin University and The Editorial Department of Chemical Research in Chinese Universities</publisher><subject>Analytical Chemistry ; Belts ; Borates ; Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Clusters ; Inorganic Chemistry ; Organic Chemistry ; Physical Chemistry ; Tetrahedra ; Windows (computer programs)</subject><ispartof>Chemical research in Chinese universities, 2022-06, Vol.38 (3), p.744-749</ispartof><rights>Jilin University, The Editorial Department of Chemical Research in Chinese Universities and Springer-Verlag GmbH 2022</rights><rights>Jilin University, The Editorial Department of Chemical Research in Chinese Universities and Springer-Verlag GmbH 2022.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-cd8045bdcce2bb8250179369378febb17ec2f304c3acfe66b8b9c59bb66c0bdf3</citedby><cites>FETCH-LOGICAL-c316t-cd8045bdcce2bb8250179369378febb17ec2f304c3acfe66b8b9c59bb66c0bdf3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s40242-022-1473-7$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s40242-022-1473-7$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Chen, Juan</creatorcontrib><creatorcontrib>Wang, Jiajia</creatorcontrib><creatorcontrib>Chen, Chongan</creatorcontrib><creatorcontrib>Yang, Guoyu</creatorcontrib><title>Two New Borates Built by Different Types of {B9} Cluster Units</title><title>Chemical research in Chinese universities</title><addtitle>Chem. Res. Chin. Univ</addtitle><description>Two new belt-like borates Na
4
[B
9
O
14
(OH)
3
]·0.5H
2
O(
1
) and Na
5
[B
9
O
14
(OH)
4
](
2
) have been synthesized under solvothermal conditions. Both compounds contain unprecedented B
9
O
16
(OH)
n
(
n
+5)−
[
n
=3(
1
), 4(
2
)] clusters, which are constructed from four B
3
O
3
rings
via
three BO
4
tetrahedra. Compound
1
exhibits a rare 1D belt with two types of 8-membered ring(MR) windows based on B
9
O
16
(OH)
3
8−
clusters. Compound
2
features two different 1D belts built by different B
9
O
16
(OH)
4
9−
units, which is first discovered in borate family. UV-Vis diffuse reflectance spectra reveal that compounds
1
and
2
have the cut-off edges below 190 nm, indicating that they may have potential application in deep UV(DUV) region.</description><subject>Analytical Chemistry</subject><subject>Belts</subject><subject>Borates</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Clusters</subject><subject>Inorganic Chemistry</subject><subject>Organic Chemistry</subject><subject>Physical Chemistry</subject><subject>Tetrahedra</subject><subject>Windows (computer programs)</subject><issn>1005-9040</issn><issn>2210-3171</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp1kE1LAzEURYMoWKs_wF3AdfQlmUkmG8HWTyi6ma7DJE1kSp2pSYZSxP9uygiuXL3FPfc-OAhdUrimAPImFsAKRoAxQgvJiTxCE8YoEE4lPUaTDJVEQQGn6CzGNQBXQhQTdFvvevzqdnjWhya5iGdDu0nY7PF9670Lrku43m9z0Hv8NVPfeL4ZYnIBL7s2xXN04ptNdBe_d4qWjw_1_Jks3p5e5ncLYjkVidhVBUVpVtY6ZkzFSqBScaG4rLwzhkpnmedQWN5Y74QwlVG2VMYIYcGsPJ-iq3F3G_rPwcWk1_0QuvxSMyFBMEGpyBQdKRv6GIPzehvajybsNQV90KRHTTpr0gdNWuYOGzsxs927C3_L_5d-AARqaXU</recordid><startdate>20220601</startdate><enddate>20220601</enddate><creator>Chen, Juan</creator><creator>Wang, Jiajia</creator><creator>Chen, Chongan</creator><creator>Yang, Guoyu</creator><general>Jilin University and The Editorial Department of Chemical Research in Chinese Universities</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20220601</creationdate><title>Two New Borates Built by Different Types of {B9} Cluster Units</title><author>Chen, Juan ; Wang, Jiajia ; Chen, Chongan ; Yang, Guoyu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-cd8045bdcce2bb8250179369378febb17ec2f304c3acfe66b8b9c59bb66c0bdf3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Analytical Chemistry</topic><topic>Belts</topic><topic>Borates</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Clusters</topic><topic>Inorganic Chemistry</topic><topic>Organic Chemistry</topic><topic>Physical Chemistry</topic><topic>Tetrahedra</topic><topic>Windows (computer programs)</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Chen, Juan</creatorcontrib><creatorcontrib>Wang, Jiajia</creatorcontrib><creatorcontrib>Chen, Chongan</creatorcontrib><creatorcontrib>Yang, Guoyu</creatorcontrib><collection>CrossRef</collection><jtitle>Chemical research in Chinese universities</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chen, Juan</au><au>Wang, Jiajia</au><au>Chen, Chongan</au><au>Yang, Guoyu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Two New Borates Built by Different Types of {B9} Cluster Units</atitle><jtitle>Chemical research in Chinese universities</jtitle><stitle>Chem. Res. Chin. Univ</stitle><date>2022-06-01</date><risdate>2022</risdate><volume>38</volume><issue>3</issue><spage>744</spage><epage>749</epage><pages>744-749</pages><issn>1005-9040</issn><eissn>2210-3171</eissn><abstract>Two new belt-like borates Na
4
[B
9
O
14
(OH)
3
]·0.5H
2
O(
1
) and Na
5
[B
9
O
14
(OH)
4
](
2
) have been synthesized under solvothermal conditions. Both compounds contain unprecedented B
9
O
16
(OH)
n
(
n
+5)−
[
n
=3(
1
), 4(
2
)] clusters, which are constructed from four B
3
O
3
rings
via
three BO
4
tetrahedra. Compound
1
exhibits a rare 1D belt with two types of 8-membered ring(MR) windows based on B
9
O
16
(OH)
3
8−
clusters. Compound
2
features two different 1D belts built by different B
9
O
16
(OH)
4
9−
units, which is first discovered in borate family. UV-Vis diffuse reflectance spectra reveal that compounds
1
and
2
have the cut-off edges below 190 nm, indicating that they may have potential application in deep UV(DUV) region.</abstract><cop>Changchun</cop><pub>Jilin University and The Editorial Department of Chemical Research in Chinese Universities</pub><doi>10.1007/s40242-022-1473-7</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
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| ispartof | Chemical research in Chinese universities, 2022-06, Vol.38 (3), p.744-749 |
| issn | 1005-9040 2210-3171 |
| language | eng |
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| source | SpringerLink Journals (MCLS) |
| subjects | Analytical Chemistry Belts Borates Chemistry Chemistry and Materials Science Chemistry/Food Science Clusters Inorganic Chemistry Organic Chemistry Physical Chemistry Tetrahedra Windows (computer programs) |
| title | Two New Borates Built by Different Types of {B9} Cluster Units |
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