Selective Hydrogen Production from Glycerol over Ruthenium Catalyst

Glycerol – one of the prominent by‐products of biodiesel is also an important source of hydrogen gas. Herein, the efficient and selective production of hydrogen gas from glycerol in water at 90–120 °C over a ruthenium nanoparticle (∼2.7 nm) catalyst is demonstrated. Notably, high yield of hydrogen gas (n(H2)/n(glycerol); 0.96–1.61) was achieved from the glycerol‐water solution, where the reaction temperature and base concentration played crucial role in achieving high yield of H2. Advantageously, under the studied reaction conditions, the ruthenium catalyst also exhibited appreciably high long‐term stability for over 36 h while generating ca. 70 L H2 per gram of Ru with H2 yield of 350 L per L of glycerol. Moreover, high yield for lactic acid is also achieved during the production of hydrogen gas from glycerol. Hydrogen production: Efficient and selective production of hydrogen gas in high yield from glycerol was achieved over the ruthenium catalyst in water at 90–120 °C. The studied ruthenium catalysts advantageously exhibited high long‐term stability with H2 yield of 350 L per L of glycerol under bulk condition at 110 °C.