Tellurium-chlorine secondary interactions in palladium(II) complex of MeOC6H4TeCH2CH2NHCH(CH3)C6H4-2-OH resulting in self-assembled bimolecular aggregates with short palladium-palladium distances
A non-Schiff base (Te, N, O) ligand MeOC6 H4TeCH2CH2NHCH(CH3)C6H4–2–OH (LH) having a chiral center and its palladium(II) complex [PdClL]·CH2Cl2 (1) have been synthesized. Both have characteristic 1H and 13C NMR spectra. The single crystal structure of the complex 1 has been determined by X-ray diffr...
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| Veröffentlicht in: | Structural chemistry 2007-04, Vol.18 (2), p.203-207 |
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| creator | P., Raghavendra Kumar Singh, Ajai K. Drake, J. E. Hursthouse, M. B. Little, M. E. |
| description | A non-Schiff base (Te, N, O) ligand MeOC6 H4TeCH2CH2NHCH(CH3)C6H4–2–OH (LH) having a chiral center and its palladium(II) complex [PdClL]·CH2Cl2 (1) have been synthesized. Both have characteristic 1H and 13C NMR spectra. The single crystal structure of the complex 1 has been determined by X-ray diffraction methods. The monoclinic crystals of 1 (space group P21/n) have a=14.581(5) Å, b=13.160(5) Å and c=20.249(5) Å, β=99.398(5)°. The TeCl secondary interactions [3.303(2)–3.352(2) Å] between two nearly square planar palladium complex molecules results in a bimolecular aggregate having a PdPd distance 3.203(1) Å. The Pd–Te, Pd–N and Pd–O bond lengths are 2.5005(7)/2.4914(7), 2.060(4)/2.061(4) and 2.054(3)/2.044(3) Å, respectively. |
| doi_str_mv | 10.1007/s11224-006-9077-2 |
| format | Article |
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The Pd–Te, Pd–N and Pd–O bond lengths are 2.5005(7)/2.4914(7), 2.060(4)/2.061(4) and 2.054(3)/2.044(3) Å, respectively.</description><identifier>ISSN: 1040-0400</identifier><identifier>EISSN: 1572-9001</identifier><identifier>DOI: 10.1007/s11224-006-9077-2</identifier><language>eng</language><publisher>New York: Springer Nature B.V</publisher><subject>Chlorine ; Crystal structure ; Crystals ; Dichloromethane ; Imines ; NMR ; Nuclear magnetic resonance ; Palladium ; Self-assembly ; Single crystals ; Tellurium</subject><ispartof>Structural chemistry, 2007-04, Vol.18 (2), p.203-207</ispartof><rights>Springer Science+Business Media, Inc. 2006.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c273t-f8fa42b5963f5bee6f9681a5b2000b58ac2e5649a8b05d87abf73e2d2b2709543</citedby><cites>FETCH-LOGICAL-c273t-f8fa42b5963f5bee6f9681a5b2000b58ac2e5649a8b05d87abf73e2d2b2709543</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>P., Raghavendra Kumar</creatorcontrib><creatorcontrib>Singh, Ajai K.</creatorcontrib><creatorcontrib>Drake, J. E.</creatorcontrib><creatorcontrib>Hursthouse, M. B.</creatorcontrib><creatorcontrib>Little, M. E.</creatorcontrib><title>Tellurium-chlorine secondary interactions in palladium(II) complex of MeOC6H4TeCH2CH2NHCH(CH3)C6H4-2-OH resulting in self-assembled bimolecular aggregates with short palladium-palladium distances</title><title>Structural chemistry</title><description>A non-Schiff base (Te, N, O) ligand MeOC6 H4TeCH2CH2NHCH(CH3)C6H4–2–OH (LH) having a chiral center and its palladium(II) complex [PdClL]·CH2Cl2 (1) have been synthesized. Both have characteristic 1H and 13C NMR spectra. The single crystal structure of the complex 1 has been determined by X-ray diffraction methods. The monoclinic crystals of 1 (space group P21/n) have a=14.581(5) Å, b=13.160(5) Å and c=20.249(5) Å, β=99.398(5)°. The TeCl secondary interactions [3.303(2)–3.352(2) Å] between two nearly square planar palladium complex molecules results in a bimolecular aggregate having a PdPd distance 3.203(1) Å. The Pd–Te, Pd–N and Pd–O bond lengths are 2.5005(7)/2.4914(7), 2.060(4)/2.061(4) and 2.054(3)/2.044(3) Å, respectively.</description><subject>Chlorine</subject><subject>Crystal structure</subject><subject>Crystals</subject><subject>Dichloromethane</subject><subject>Imines</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Palladium</subject><subject>Self-assembly</subject><subject>Single crystals</subject><subject>Tellurium</subject><issn>1040-0400</issn><issn>1572-9001</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2007</creationdate><recordtype>article</recordtype><recordid>eNpFUcFq3DAQNaWBpmk_oDdBL8lBqSRbsn0spokX0uxlcxaSPNpVkK2tJNPm-_pj0bKhhRlm5vF4D-ZV1RdKbikh7bdEKWMNJkTgnrQtZu-qS8pbVi5C35edNASXJh-qjyk9F5CKml9Wf3fg_RrdOmNz8CG6BVACE5ZJxRfklgxRmezCksqBjsp7NRXy9WZzg0yYjx7-oGDRT9gOYmx2MIys1OM4jNfDWN-cQMzwdkQR0uqzW_YnnQTeYpUSzNrDhLSbgwezehWR2u8j7FWGhH67fEDpEGL-b4z_bWhyKavFQPpUXVjlE3x-m1fV092P3TDih-39Zvj-gA1r64xtZ1XDNO9FbbkGELYXHVVcM0KI5p0yDLhoetVpwqeuVdq2NbCJadaSnjf1VfX1rHuM4dcKKcvnsMalWEomBBe0a7qusOiZZWJIKYKVx-jm8k1JiTxlJc9ZyZKVPGUlWf0KOhmJBA</recordid><startdate>20070401</startdate><enddate>20070401</enddate><creator>P., Raghavendra Kumar</creator><creator>Singh, Ajai K.</creator><creator>Drake, J. 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E.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c273t-f8fa42b5963f5bee6f9681a5b2000b58ac2e5649a8b05d87abf73e2d2b2709543</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2007</creationdate><topic>Chlorine</topic><topic>Crystal structure</topic><topic>Crystals</topic><topic>Dichloromethane</topic><topic>Imines</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Palladium</topic><topic>Self-assembly</topic><topic>Single crystals</topic><topic>Tellurium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>P., Raghavendra Kumar</creatorcontrib><creatorcontrib>Singh, Ajai K.</creatorcontrib><creatorcontrib>Drake, J. E.</creatorcontrib><creatorcontrib>Hursthouse, M. B.</creatorcontrib><creatorcontrib>Little, M. E.</creatorcontrib><collection>CrossRef</collection><jtitle>Structural chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>P., Raghavendra Kumar</au><au>Singh, Ajai K.</au><au>Drake, J. E.</au><au>Hursthouse, M. B.</au><au>Little, M. E.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Tellurium-chlorine secondary interactions in palladium(II) complex of MeOC6H4TeCH2CH2NHCH(CH3)C6H4-2-OH resulting in self-assembled bimolecular aggregates with short palladium-palladium distances</atitle><jtitle>Structural chemistry</jtitle><date>2007-04-01</date><risdate>2007</risdate><volume>18</volume><issue>2</issue><spage>203</spage><epage>207</epage><pages>203-207</pages><issn>1040-0400</issn><eissn>1572-9001</eissn><abstract>A non-Schiff base (Te, N, O) ligand MeOC6 H4TeCH2CH2NHCH(CH3)C6H4–2–OH (LH) having a chiral center and its palladium(II) complex [PdClL]·CH2Cl2 (1) have been synthesized. Both have characteristic 1H and 13C NMR spectra. The single crystal structure of the complex 1 has been determined by X-ray diffraction methods. The monoclinic crystals of 1 (space group P21/n) have a=14.581(5) Å, b=13.160(5) Å and c=20.249(5) Å, β=99.398(5)°. The TeCl secondary interactions [3.303(2)–3.352(2) Å] between two nearly square planar palladium complex molecules results in a bimolecular aggregate having a PdPd distance 3.203(1) Å. The Pd–Te, Pd–N and Pd–O bond lengths are 2.5005(7)/2.4914(7), 2.060(4)/2.061(4) and 2.054(3)/2.044(3) Å, respectively.</abstract><cop>New York</cop><pub>Springer Nature B.V</pub><doi>10.1007/s11224-006-9077-2</doi><tpages>5</tpages></addata></record> |
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| subjects | Chlorine Crystal structure Crystals Dichloromethane Imines NMR Nuclear magnetic resonance Palladium Self-assembly Single crystals Tellurium |
| title | Tellurium-chlorine secondary interactions in palladium(II) complex of MeOC6H4TeCH2CH2NHCH(CH3)C6H4-2-OH resulting in self-assembled bimolecular aggregates with short palladium-palladium distances |
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