Preparation of ultrathin polypyrrole films using an adhesion promoter
Adhesive ultrathin polypyrrole films were deposited on Si/SiO2 substrates modified with the new adhesion promoter 11-(Pyrrol-1-yl Undecyl) TrichloroSilane (PUTS). The oxidation potential of PUTS in solution was determined electrochemically by cyclic voltammetry. Self-assembled monolayers of PUTS wer...
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| Veröffentlicht in: | Journal of solid state electrochemistry 2007-01, Vol.11 (1), p.1-9 |
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| container_title | Journal of solid state electrochemistry |
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| creator | Intelmann, C. M. Rammelt, U. Plieth, W. Cai, X. Jähne, E. Adler, H. -P. |
| description | Adhesive ultrathin polypyrrole films were deposited on Si/SiO2 substrates modified with the new adhesion promoter 11-(Pyrrol-1-yl Undecyl) TrichloroSilane (PUTS). The oxidation potential of PUTS in solution was determined electrochemically by cyclic voltammetry. Self-assembled monolayers of PUTS were investigated by cyclic voltammetry, contact angle measurements, ellipsometry, and X-ray photoelectron spectroscopy. Several oxidants for the deposition of pyrrole on adhesion promoter modified substrates were tested and a strong dependence on the obtained film morphology was found. It was possible to deposit chemically ultrathin polypyrrole films on insulating substrates. |
| doi_str_mv | 10.1007/s10008-005-0013-y |
| format | Article |
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M. ; Rammelt, U. ; Plieth, W. ; Cai, X. ; Jähne, E. ; Adler, H. -P.</creator><creatorcontrib>Intelmann, C. M. ; Rammelt, U. ; Plieth, W. ; Cai, X. ; Jähne, E. ; Adler, H. -P.</creatorcontrib><description>Adhesive ultrathin polypyrrole films were deposited on Si/SiO2 substrates modified with the new adhesion promoter 11-(Pyrrol-1-yl Undecyl) TrichloroSilane (PUTS). The oxidation potential of PUTS in solution was determined electrochemically by cyclic voltammetry. Self-assembled monolayers of PUTS were investigated by cyclic voltammetry, contact angle measurements, ellipsometry, and X-ray photoelectron spectroscopy. Several oxidants for the deposition of pyrrole on adhesion promoter modified substrates were tested and a strong dependence on the obtained film morphology was found. It was possible to deposit chemically ultrathin polypyrrole films on insulating substrates.</description><identifier>ISSN: 1432-8488</identifier><identifier>EISSN: 1433-0768</identifier><identifier>DOI: 10.1007/s10008-005-0013-y</identifier><language>eng</language><publisher>Heidelberg: Springer Nature B.V</publisher><subject>Adhesion ; Contact angle ; Electrons ; Ellipsometry ; Oxidation ; Oxidizing agents ; Photoelectrons ; Polypyrroles ; Self-assembled monolayers ; Self-assembly ; Silicon dioxide ; Silicon substrates ; Voltammetry</subject><ispartof>Journal of solid state electrochemistry, 2007-01, Vol.11 (1), p.1-9</ispartof><rights>Springer-Verlag 2005.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c310t-8c6a305b1a00f10deeab90c1d848c0f39a881432c1f6c0b9618c7ec5b280317d3</citedby><cites>FETCH-LOGICAL-c310t-8c6a305b1a00f10deeab90c1d848c0f39a881432c1f6c0b9618c7ec5b280317d3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Intelmann, C. 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It was possible to deposit chemically ultrathin polypyrrole films on insulating substrates.</description><subject>Adhesion</subject><subject>Contact angle</subject><subject>Electrons</subject><subject>Ellipsometry</subject><subject>Oxidation</subject><subject>Oxidizing agents</subject><subject>Photoelectrons</subject><subject>Polypyrroles</subject><subject>Self-assembled monolayers</subject><subject>Self-assembly</subject><subject>Silicon dioxide</subject><subject>Silicon substrates</subject><subject>Voltammetry</subject><issn>1432-8488</issn><issn>1433-0768</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2007</creationdate><recordtype>article</recordtype><recordid>eNotkD1PwzAQhi0EEqXwA9gsMRvu4sZxRlQVilQJBpgtx7FpqjQOdjLk3-MQhvuS3rv39BByj_CIAMVTTBkkA8hTIGfTBVnhhnMGhZCXf33G5EbKa3IT4ylpCoGwIruPYHsd9ND4jnpHx3ZIw7HpaO_bqZ9C8K2lrmnPkY6x6b6p7qiujzbOC33wZz_YcEuunG6jvfuva_L1svvc7tnh_fVt-3xghiMMTBqhOeQVagCHUFurqxIM1ukxA46XWsr5UYNOGKhKgdIU1uRVJoFjUfM1eVjuJuOf0cZBnfwYumSpMiFygXmZQ1LhojLBxxisU31ozjpMCkHNtNRCSyVaaqalJv4LV01dtw</recordid><startdate>20070101</startdate><enddate>20070101</enddate><creator>Intelmann, C. 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M.</creatorcontrib><creatorcontrib>Rammelt, U.</creatorcontrib><creatorcontrib>Plieth, W.</creatorcontrib><creatorcontrib>Cai, X.</creatorcontrib><creatorcontrib>Jähne, E.</creatorcontrib><creatorcontrib>Adler, H. -P.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of solid state electrochemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Intelmann, C. 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Several oxidants for the deposition of pyrrole on adhesion promoter modified substrates were tested and a strong dependence on the obtained film morphology was found. It was possible to deposit chemically ultrathin polypyrrole films on insulating substrates.</abstract><cop>Heidelberg</cop><pub>Springer Nature B.V</pub><doi>10.1007/s10008-005-0013-y</doi><tpages>9</tpages></addata></record> |
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| language | eng |
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| subjects | Adhesion Contact angle Electrons Ellipsometry Oxidation Oxidizing agents Photoelectrons Polypyrroles Self-assembled monolayers Self-assembly Silicon dioxide Silicon substrates Voltammetry |
| title | Preparation of ultrathin polypyrrole films using an adhesion promoter |
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