A highly active Au/Al2O3 catalyst for cyclohexane oxidation using molecular oxygen
The selective oxidation of cyclohexane to cyclohexanone and cyclohexanol has been investigated over Au/Al2O3 catalysts using molecular oxygen in a solvent-free system. The catalysts were prepared by a modified direct anionic exchange method and characterized by AAS, N2 adsorption and TEM. The result...
Gespeichert in:
| Veröffentlicht in: | Catalysis letters 2007-04, Vol.114 (3-4), p.202-205 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 205 |
|---|---|
| container_issue | 3-4 |
| container_start_page | 202 |
| container_title | Catalysis letters |
| container_volume | 114 |
| creator | XU, Li-Xin HE, Chao-Hong ZHU, Ming-Qiao SHENG FANG |
| description | The selective oxidation of cyclohexane to cyclohexanone and cyclohexanol has been investigated over Au/Al2O3 catalysts using molecular oxygen in a solvent-free system. The catalysts were prepared by a modified direct anionic exchange method and characterized by AAS, N2 adsorption and TEM. The results showed that the catalytic performance of Au/Al2O3 is very high in terms of turnover frequency. Moreover, the nano-size effect of gold is also reported in the reaction. |
| doi_str_mv | 10.1007/s10562-007-9058-0 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2665406833</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2258940445</sourcerecordid><originalsourceid>FETCH-LOGICAL-c434t-98c42bc26379cf6e66d429b9c84f4d89754fe1400685bdef229ad1be40eefdcf3</originalsourceid><addsrcrecordid>eNp9kF1LwzAYhYsoOKc_wLuAeBn35qNJc1mGXzAYiMLuSpomW0fXzKSV9d_bsYF3Xr0H3uecAydJ7gk8EQA5iwRSQfEosYI0w3CRTEgqKc6kWl2OGgjBTNLVdXIT4xYAlCRqknzkaFOvN82AtOnqH4vyfpY3dMmQ0Z1uhtgh5wMyg2n8xh50a5E_1JXuat-iPtbtGu18Y03f6DB-hrVtb5Mrp5to7853mny9PH_O3_Bi-fo-zxfYcMY7rDLDaWmoYFIZJ6wQFaeqVCbjjleZkil3lnAAkaVlZR2lSlektBysdZVxbJo8nHL3wX_3NnbF1vehHSsLKkTKRyNj_1I0zRQHztORIifKBB9jsK7Yh3qnw1AQKI4DF6eBi6M8DlzA6Hk8J-todOOCbk0d_4yZJIIpyX4B1Dh6cg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2258940445</pqid></control><display><type>article</type><title>A highly active Au/Al2O3 catalyst for cyclohexane oxidation using molecular oxygen</title><source>SpringerNature Journals</source><creator>XU, Li-Xin ; HE, Chao-Hong ; ZHU, Ming-Qiao ; SHENG FANG</creator><creatorcontrib>XU, Li-Xin ; HE, Chao-Hong ; ZHU, Ming-Qiao ; SHENG FANG</creatorcontrib><description>The selective oxidation of cyclohexane to cyclohexanone and cyclohexanol has been investigated over Au/Al2O3 catalysts using molecular oxygen in a solvent-free system. The catalysts were prepared by a modified direct anionic exchange method and characterized by AAS, N2 adsorption and TEM. The results showed that the catalytic performance of Au/Al2O3 is very high in terms of turnover frequency. Moreover, the nano-size effect of gold is also reported in the reaction.</description><identifier>ISSN: 1011-372X</identifier><identifier>EISSN: 1572-879X</identifier><identifier>DOI: 10.1007/s10562-007-9058-0</identifier><language>eng</language><publisher>Dordrecht: Springer</publisher><subject>Aluminum oxide ; Catalysis ; Catalysts ; Chemistry ; Cyclohexane ; Cyclohexanone ; Exact sciences and technology ; General and physical chemistry ; Gold ; Oxidation ; Oxygen ; Size effects ; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</subject><ispartof>Catalysis letters, 2007-04, Vol.114 (3-4), p.202-205</ispartof><rights>2007 INIST-CNRS</rights><rights>Catalysis Letters is a copyright of Springer, (2007). All Rights Reserved.</rights><rights>Springer Science+Business Media, LLC 2007.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c434t-98c42bc26379cf6e66d429b9c84f4d89754fe1400685bdef229ad1be40eefdcf3</citedby><cites>FETCH-LOGICAL-c434t-98c42bc26379cf6e66d429b9c84f4d89754fe1400685bdef229ad1be40eefdcf3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=18716397$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>XU, Li-Xin</creatorcontrib><creatorcontrib>HE, Chao-Hong</creatorcontrib><creatorcontrib>ZHU, Ming-Qiao</creatorcontrib><creatorcontrib>SHENG FANG</creatorcontrib><title>A highly active Au/Al2O3 catalyst for cyclohexane oxidation using molecular oxygen</title><title>Catalysis letters</title><description>The selective oxidation of cyclohexane to cyclohexanone and cyclohexanol has been investigated over Au/Al2O3 catalysts using molecular oxygen in a solvent-free system. The catalysts were prepared by a modified direct anionic exchange method and characterized by AAS, N2 adsorption and TEM. The results showed that the catalytic performance of Au/Al2O3 is very high in terms of turnover frequency. Moreover, the nano-size effect of gold is also reported in the reaction.</description><subject>Aluminum oxide</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Chemistry</subject><subject>Cyclohexane</subject><subject>Cyclohexanone</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Gold</subject><subject>Oxidation</subject><subject>Oxygen</subject><subject>Size effects</subject><subject>Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</subject><issn>1011-372X</issn><issn>1572-879X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2007</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp9kF1LwzAYhYsoOKc_wLuAeBn35qNJc1mGXzAYiMLuSpomW0fXzKSV9d_bsYF3Xr0H3uecAydJ7gk8EQA5iwRSQfEosYI0w3CRTEgqKc6kWl2OGgjBTNLVdXIT4xYAlCRqknzkaFOvN82AtOnqH4vyfpY3dMmQ0Z1uhtgh5wMyg2n8xh50a5E_1JXuat-iPtbtGu18Y03f6DB-hrVtb5Mrp5to7853mny9PH_O3_Bi-fo-zxfYcMY7rDLDaWmoYFIZJ6wQFaeqVCbjjleZkil3lnAAkaVlZR2lSlektBysdZVxbJo8nHL3wX_3NnbF1vehHSsLKkTKRyNj_1I0zRQHztORIifKBB9jsK7Yh3qnw1AQKI4DF6eBi6M8DlzA6Hk8J-todOOCbk0d_4yZJIIpyX4B1Dh6cg</recordid><startdate>20070401</startdate><enddate>20070401</enddate><creator>XU, Li-Xin</creator><creator>HE, Chao-Hong</creator><creator>ZHU, Ming-Qiao</creator><creator>SHENG FANG</creator><general>Springer</general><general>Springer Nature B.V</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope></search><sort><creationdate>20070401</creationdate><title>A highly active Au/Al2O3 catalyst for cyclohexane oxidation using molecular oxygen</title><author>XU, Li-Xin ; HE, Chao-Hong ; ZHU, Ming-Qiao ; SHENG FANG</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c434t-98c42bc26379cf6e66d429b9c84f4d89754fe1400685bdef229ad1be40eefdcf3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2007</creationdate><topic>Aluminum oxide</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Chemistry</topic><topic>Cyclohexane</topic><topic>Cyclohexanone</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>Gold</topic><topic>Oxidation</topic><topic>Oxygen</topic><topic>Size effects</topic><topic>Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>XU, Li-Xin</creatorcontrib><creatorcontrib>HE, Chao-Hong</creatorcontrib><creatorcontrib>ZHU, Ming-Qiao</creatorcontrib><creatorcontrib>SHENG FANG</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Catalysis letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>XU, Li-Xin</au><au>HE, Chao-Hong</au><au>ZHU, Ming-Qiao</au><au>SHENG FANG</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A highly active Au/Al2O3 catalyst for cyclohexane oxidation using molecular oxygen</atitle><jtitle>Catalysis letters</jtitle><date>2007-04-01</date><risdate>2007</risdate><volume>114</volume><issue>3-4</issue><spage>202</spage><epage>205</epage><pages>202-205</pages><issn>1011-372X</issn><eissn>1572-879X</eissn><abstract>The selective oxidation of cyclohexane to cyclohexanone and cyclohexanol has been investigated over Au/Al2O3 catalysts using molecular oxygen in a solvent-free system. The catalysts were prepared by a modified direct anionic exchange method and characterized by AAS, N2 adsorption and TEM. The results showed that the catalytic performance of Au/Al2O3 is very high in terms of turnover frequency. Moreover, the nano-size effect of gold is also reported in the reaction.</abstract><cop>Dordrecht</cop><pub>Springer</pub><doi>10.1007/s10562-007-9058-0</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1011-372X |
| ispartof | Catalysis letters, 2007-04, Vol.114 (3-4), p.202-205 |
| issn | 1011-372X 1572-879X |
| language | eng |
| recordid | cdi_proquest_journals_2665406833 |
| source | SpringerNature Journals |
| subjects | Aluminum oxide Catalysis Catalysts Chemistry Cyclohexane Cyclohexanone Exact sciences and technology General and physical chemistry Gold Oxidation Oxygen Size effects Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry |
| title | A highly active Au/Al2O3 catalyst for cyclohexane oxidation using molecular oxygen |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-25T22%3A55%3A36IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=A%20highly%20active%20Au/Al2O3%20catalyst%20for%20cyclohexane%20oxidation%20using%20molecular%20oxygen&rft.jtitle=Catalysis%20letters&rft.au=XU,%20Li-Xin&rft.date=2007-04-01&rft.volume=114&rft.issue=3-4&rft.spage=202&rft.epage=205&rft.pages=202-205&rft.issn=1011-372X&rft.eissn=1572-879X&rft_id=info:doi/10.1007/s10562-007-9058-0&rft_dat=%3Cproquest_cross%3E2258940445%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2258940445&rft_id=info:pmid/&rfr_iscdi=true |