Space-charge effects on Fourier transform ion cyclotron resonance signals: Experimental observations and three-dimensional trajectory simulations
Space-charge effects were studied by monitoring Fourier transform ion cyclotron resonance spectra while scanning the laser wavelength near the origin of a two-photon resonant 3s ← n Rydberg transition of acetaldehyde. The rotational contour of the origin band permits the experimental control of spac...
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| Veröffentlicht in: | Journal of the American Society for Mass Spectrometry 1997-04, Vol.8 (4), p.319-326 |
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| creator | Han, Seung-Jin Shin, Seung Koo |
| description | Space-charge effects were studied by monitoring Fourier transform ion cyclotron resonance spectra while scanning the laser wavelength near the origin of a two-photon resonant 3s ← n Rydberg transition of acetaldehyde. The rotational contour of the origin band permits the experimental control of space-charge density. Both the frequency shift and the inhomogeneous line broadening were observed as a function of space-charge density. Three-dimensional ion trajectories in the presence of Coulomb interactions between ions were simulated under the quadratic and exact trapping potentials. The simulated Fourier transform ion cyclotron resonance spectra were obtained from the image-charge signals induced by a uniform field of chirp or impulse excitation. Comparisons of experiments with three-dimensional simulations reveal that the inhomogeneous line broadening observed in experiments is most likely due to both large-amplitude oscillations of ions and Coulomb interactions between different
m/q ions. |
| doi_str_mv | 10.1016/S1044-0305(96)00292-9 |
| format | Article |
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m/q ions.</description><identifier>ISSN: 1044-0305</identifier><identifier>EISSN: 1879-1123</identifier><identifier>DOI: 10.1016/S1044-0305(96)00292-9</identifier><language>eng</language><publisher>New York, NY: Elsevier Inc</publisher><subject>Acetaldehyde ; Charge density ; Chemistry ; Chirp ; Cyclotron resonance ; Exact sciences and technology ; Fourier transforms ; Frequency shift ; Ion trajectories ; Ions ; Line broadening ; Mass spectrometry ; Organic chemistry ; Reactivity and mechanisms ; Simulation ; Spectra</subject><ispartof>Journal of the American Society for Mass Spectrometry, 1997-04, Vol.8 (4), p.319-326</ispartof><rights>1997 American Society for Mass Spectrometry</rights><rights>1997 INIST-CNRS</rights><rights>American Society for Mass Spectrometry 1997</rights><rights>American Society for Mass Spectrometry 1997.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c392t-c841546eba89c3d305b9c17a2ecc2c0115ab0611ba25d715d831212f1488ae293</citedby><cites>FETCH-LOGICAL-c392t-c841546eba89c3d305b9c17a2ecc2c0115ab0611ba25d715d831212f1488ae293</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,777,781,27905,27906</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=2621560$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Han, Seung-Jin</creatorcontrib><creatorcontrib>Shin, Seung Koo</creatorcontrib><title>Space-charge effects on Fourier transform ion cyclotron resonance signals: Experimental observations and three-dimensional trajectory simulations</title><title>Journal of the American Society for Mass Spectrometry</title><description>Space-charge effects were studied by monitoring Fourier transform ion cyclotron resonance spectra while scanning the laser wavelength near the origin of a two-photon resonant 3s ← n Rydberg transition of acetaldehyde. The rotational contour of the origin band permits the experimental control of space-charge density. Both the frequency shift and the inhomogeneous line broadening were observed as a function of space-charge density. Three-dimensional ion trajectories in the presence of Coulomb interactions between ions were simulated under the quadratic and exact trapping potentials. The simulated Fourier transform ion cyclotron resonance spectra were obtained from the image-charge signals induced by a uniform field of chirp or impulse excitation. Comparisons of experiments with three-dimensional simulations reveal that the inhomogeneous line broadening observed in experiments is most likely due to both large-amplitude oscillations of ions and Coulomb interactions between different
m/q ions.</description><subject>Acetaldehyde</subject><subject>Charge density</subject><subject>Chemistry</subject><subject>Chirp</subject><subject>Cyclotron resonance</subject><subject>Exact sciences and technology</subject><subject>Fourier transforms</subject><subject>Frequency shift</subject><subject>Ion trajectories</subject><subject>Ions</subject><subject>Line broadening</subject><subject>Mass spectrometry</subject><subject>Organic chemistry</subject><subject>Reactivity and mechanisms</subject><subject>Simulation</subject><subject>Spectra</subject><issn>1044-0305</issn><issn>1879-1123</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1997</creationdate><recordtype>article</recordtype><sourceid>8G5</sourceid><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><sourceid>GUQSH</sourceid><sourceid>M2O</sourceid><recordid>eNqFkc9u1DAQxiPUSvQPj4BkCQ5wSPHYsRNzqaqqhUqVOBTOljOZtFll48XOVuxj8MZMuqVHOHlk_-Ybz_cVxVuQZyDBfroDWVWl1NJ8cPajlMqp0r0qjqCpXQmg9AHXf5HXxXHOKymhlq4-Kn7fbQJSiQ8h3ZOgviecs4iTuI7bNFAScwpT7mNai4FvcYdjnBNXiXKcwoQk8nA_hTF_Fle_NpSGNU1zGEVsM6XHMHNXFmHqxPyQiMpuec98yQhLr3hcTDvWWG_HPXxaHPYsR2-ez5Pix_XV98uv5e23LzeXF7claqfmEpsKTGWpDY1D3fFmrUOogyJEhRLAhFZagDYo09VgukaDAtVD1TSBlNMnxbu97ibFn1vKs1_xyssmXllrQDeVbf5FgTOq0rqSiimzpzDFnBP1fsNGhLTzIP2SkX_KyC8BeGf9U0Z--cP7Z_WQMYw9e41DfmlWVoGxkrHzPUbsxyOn4jMOxN53Q2IDfReH_wz6A7gpp-8</recordid><startdate>19970401</startdate><enddate>19970401</enddate><creator>Han, Seung-Jin</creator><creator>Shin, Seung Koo</creator><general>Elsevier Inc</general><general>Elsevier Science</general><general>Springer Nature B.V</general><scope>6I.</scope><scope>AAFTH</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7X7</scope><scope>7XB</scope><scope>88E</scope><scope>8FE</scope><scope>8FG</scope><scope>8FI</scope><scope>8FJ</scope><scope>8FK</scope><scope>8G5</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>ARAPS</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>FYUFA</scope><scope>GHDGH</scope><scope>GNUQQ</scope><scope>GUQSH</scope><scope>HCIFZ</scope><scope>K9.</scope><scope>M0S</scope><scope>M1P</scope><scope>M2O</scope><scope>MBDVC</scope><scope>P5Z</scope><scope>P62</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>Q9U</scope></search><sort><creationdate>19970401</creationdate><title>Space-charge effects on Fourier transform ion cyclotron resonance signals: Experimental observations and three-dimensional trajectory simulations</title><author>Han, Seung-Jin ; 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The rotational contour of the origin band permits the experimental control of space-charge density. Both the frequency shift and the inhomogeneous line broadening were observed as a function of space-charge density. Three-dimensional ion trajectories in the presence of Coulomb interactions between ions were simulated under the quadratic and exact trapping potentials. The simulated Fourier transform ion cyclotron resonance spectra were obtained from the image-charge signals induced by a uniform field of chirp or impulse excitation. Comparisons of experiments with three-dimensional simulations reveal that the inhomogeneous line broadening observed in experiments is most likely due to both large-amplitude oscillations of ions and Coulomb interactions between different
m/q ions.</abstract><cop>New York, NY</cop><pub>Elsevier Inc</pub><doi>10.1016/S1044-0305(96)00292-9</doi><tpages>8</tpages><oa>free_for_read</oa></addata></record> |
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| source | Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; Springer Nature - Complete Springer Journals; Alma/SFX Local Collection; Free Full-Text Journals in Chemistry |
| subjects | Acetaldehyde Charge density Chemistry Chirp Cyclotron resonance Exact sciences and technology Fourier transforms Frequency shift Ion trajectories Ions Line broadening Mass spectrometry Organic chemistry Reactivity and mechanisms Simulation Spectra |
| title | Space-charge effects on Fourier transform ion cyclotron resonance signals: Experimental observations and three-dimensional trajectory simulations |
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