Production of Alcohols and Olefins from CO and H2 on a Cobalt Catalyst at High Pressures and in the Gas Circulation Mode
The results of a study of the synthesis of products from CO and H 2 on a supported industrial Co–Al 2 O 3 /SiO 2 catalyst under medium and high pressures in the gas circulation mode are presented. It was found that an increase in pressure from 2.0 to 8.0 MPa led to an increase in the amount of forme...
Gespeichert in:
| Veröffentlicht in: | Kinetics and catalysis 2022-04, Vol.63 (2), p.218-225 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 225 |
|---|---|
| container_issue | 2 |
| container_start_page | 218 |
| container_title | Kinetics and catalysis |
| container_volume | 63 |
| creator | Zubkov, I. N. Soromotin, V. N. Savost’yanov, A. P. Mitchenko, S. A. Yakovenko, R. E. |
| description | The results of a study of the synthesis of products from CO and H
2
on a supported industrial Co–Al
2
O
3
/SiO
2
catalyst under medium and high pressures in the gas circulation mode are presented. It was found that an increase in pressure from 2.0 to 8.0 MPa led to an increase in the amount of formed alcohols and synthesis olefins by factors of 10.5 and 2.0, respectively. It was determined that alcohols obtained in the synthesis were not the products of olefin hydration. The effect of an increase in selectivity for C
5+
products with temperature at a high pressure in the gas recirculation mode, which is atypical for the Fischer–Tropsch synthesis, was confirmed. |
| doi_str_mv | 10.1134/S0023158422020148 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2665136866</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2665136866</sourcerecordid><originalsourceid>FETCH-LOGICAL-c1838-f070cc14bcbbdc712d882f92d14d0703e9ff87665a5168aaa69ca80d113c15413</originalsourceid><addsrcrecordid>eNp1kE9LAzEQxYMoWKsfwFvA82omyabZY1m0FZQW1POSzZ92y3ZTk12w3960FTyIlxmY93vz4CF0C-QegPGHN0Iog1xySgklwOUZGoEgMmMUyDkaHeTsoF-iqxg3hBAOvBihr2XwZtB94zvsHZ622q99G7HqDF601jVdxC74LS4Xx9uc4kQqXPpatT0uVa_afeyx6vG8Wa3xMtgYhzSOdNPhfm3xTEVcNkEPrToGvXpjr9GFU220Nz97jD6eHt_LefaymD2X05dMg2Qyc2RCtAZe67o2egLUSEldQQ1wkyRmC-fkRIhc5SCkUkoUWkliUikacg5sjO5Of3fBfw429tXGD6FLkRVNNmBCCpEoOFE6-BiDddUuNFsV9hWQ6lBw9afg5KEnT0xst7Lh9_P_pm9YkXra</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2665136866</pqid></control><display><type>article</type><title>Production of Alcohols and Olefins from CO and H2 on a Cobalt Catalyst at High Pressures and in the Gas Circulation Mode</title><source>Springer Nature - Complete Springer Journals</source><creator>Zubkov, I. N. ; Soromotin, V. N. ; Savost’yanov, A. P. ; Mitchenko, S. A. ; Yakovenko, R. E.</creator><creatorcontrib>Zubkov, I. N. ; Soromotin, V. N. ; Savost’yanov, A. P. ; Mitchenko, S. A. ; Yakovenko, R. E.</creatorcontrib><description>The results of a study of the synthesis of products from CO and H
2
on a supported industrial Co–Al
2
O
3
/SiO
2
catalyst under medium and high pressures in the gas circulation mode are presented. It was found that an increase in pressure from 2.0 to 8.0 MPa led to an increase in the amount of formed alcohols and synthesis olefins by factors of 10.5 and 2.0, respectively. It was determined that alcohols obtained in the synthesis were not the products of olefin hydration. The effect of an increase in selectivity for C
5+
products with temperature at a high pressure in the gas recirculation mode, which is atypical for the Fischer–Tropsch synthesis, was confirmed.</description><identifier>ISSN: 0023-1584</identifier><identifier>EISSN: 1608-3210</identifier><identifier>DOI: 10.1134/S0023158422020148</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Alcohol ; Alcohols ; Alkenes ; Aluminum oxide ; Catalysis ; Catalysts ; Chemistry ; Chemistry and Materials Science ; Fischer-Tropsch process ; High pressure ; Physical Chemistry ; Selectivity ; Silicon dioxide</subject><ispartof>Kinetics and catalysis, 2022-04, Vol.63 (2), p.218-225</ispartof><rights>Pleiades Publishing, Ltd. 2022. ISSN 0023-1584, Kinetics and Catalysis, 2022, Vol. 63, No. 2, pp. 218–225. © Pleiades Publishing, Ltd., 2022. Russian Text © The Author(s), 2022, published in Kinetika i Kataliz, 2022, Vol. 63, No. 2, pp. 249–257.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c1838-f070cc14bcbbdc712d882f92d14d0703e9ff87665a5168aaa69ca80d113c15413</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0023158422020148$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0023158422020148$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,777,781,27905,27906,41469,42538,51300</link.rule.ids></links><search><creatorcontrib>Zubkov, I. N.</creatorcontrib><creatorcontrib>Soromotin, V. N.</creatorcontrib><creatorcontrib>Savost’yanov, A. P.</creatorcontrib><creatorcontrib>Mitchenko, S. A.</creatorcontrib><creatorcontrib>Yakovenko, R. E.</creatorcontrib><title>Production of Alcohols and Olefins from CO and H2 on a Cobalt Catalyst at High Pressures and in the Gas Circulation Mode</title><title>Kinetics and catalysis</title><addtitle>Kinet Catal</addtitle><description>The results of a study of the synthesis of products from CO and H
2
on a supported industrial Co–Al
2
O
3
/SiO
2
catalyst under medium and high pressures in the gas circulation mode are presented. It was found that an increase in pressure from 2.0 to 8.0 MPa led to an increase in the amount of formed alcohols and synthesis olefins by factors of 10.5 and 2.0, respectively. It was determined that alcohols obtained in the synthesis were not the products of olefin hydration. The effect of an increase in selectivity for C
5+
products with temperature at a high pressure in the gas recirculation mode, which is atypical for the Fischer–Tropsch synthesis, was confirmed.</description><subject>Alcohol</subject><subject>Alcohols</subject><subject>Alkenes</subject><subject>Aluminum oxide</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Fischer-Tropsch process</subject><subject>High pressure</subject><subject>Physical Chemistry</subject><subject>Selectivity</subject><subject>Silicon dioxide</subject><issn>0023-1584</issn><issn>1608-3210</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp1kE9LAzEQxYMoWKsfwFvA82omyabZY1m0FZQW1POSzZ92y3ZTk12w3960FTyIlxmY93vz4CF0C-QegPGHN0Iog1xySgklwOUZGoEgMmMUyDkaHeTsoF-iqxg3hBAOvBihr2XwZtB94zvsHZ622q99G7HqDF601jVdxC74LS4Xx9uc4kQqXPpatT0uVa_afeyx6vG8Wa3xMtgYhzSOdNPhfm3xTEVcNkEPrToGvXpjr9GFU220Nz97jD6eHt_LefaymD2X05dMg2Qyc2RCtAZe67o2egLUSEldQQ1wkyRmC-fkRIhc5SCkUkoUWkliUikacg5sjO5Of3fBfw429tXGD6FLkRVNNmBCCpEoOFE6-BiDddUuNFsV9hWQ6lBw9afg5KEnT0xst7Lh9_P_pm9YkXra</recordid><startdate>20220401</startdate><enddate>20220401</enddate><creator>Zubkov, I. N.</creator><creator>Soromotin, V. N.</creator><creator>Savost’yanov, A. P.</creator><creator>Mitchenko, S. A.</creator><creator>Yakovenko, R. E.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20220401</creationdate><title>Production of Alcohols and Olefins from CO and H2 on a Cobalt Catalyst at High Pressures and in the Gas Circulation Mode</title><author>Zubkov, I. N. ; Soromotin, V. N. ; Savost’yanov, A. P. ; Mitchenko, S. A. ; Yakovenko, R. E.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1838-f070cc14bcbbdc712d882f92d14d0703e9ff87665a5168aaa69ca80d113c15413</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Alcohol</topic><topic>Alcohols</topic><topic>Alkenes</topic><topic>Aluminum oxide</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Fischer-Tropsch process</topic><topic>High pressure</topic><topic>Physical Chemistry</topic><topic>Selectivity</topic><topic>Silicon dioxide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zubkov, I. N.</creatorcontrib><creatorcontrib>Soromotin, V. N.</creatorcontrib><creatorcontrib>Savost’yanov, A. P.</creatorcontrib><creatorcontrib>Mitchenko, S. A.</creatorcontrib><creatorcontrib>Yakovenko, R. E.</creatorcontrib><collection>CrossRef</collection><jtitle>Kinetics and catalysis</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zubkov, I. N.</au><au>Soromotin, V. N.</au><au>Savost’yanov, A. P.</au><au>Mitchenko, S. A.</au><au>Yakovenko, R. E.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Production of Alcohols and Olefins from CO and H2 on a Cobalt Catalyst at High Pressures and in the Gas Circulation Mode</atitle><jtitle>Kinetics and catalysis</jtitle><stitle>Kinet Catal</stitle><date>2022-04-01</date><risdate>2022</risdate><volume>63</volume><issue>2</issue><spage>218</spage><epage>225</epage><pages>218-225</pages><issn>0023-1584</issn><eissn>1608-3210</eissn><abstract>The results of a study of the synthesis of products from CO and H
2
on a supported industrial Co–Al
2
O
3
/SiO
2
catalyst under medium and high pressures in the gas circulation mode are presented. It was found that an increase in pressure from 2.0 to 8.0 MPa led to an increase in the amount of formed alcohols and synthesis olefins by factors of 10.5 and 2.0, respectively. It was determined that alcohols obtained in the synthesis were not the products of olefin hydration. The effect of an increase in selectivity for C
5+
products with temperature at a high pressure in the gas recirculation mode, which is atypical for the Fischer–Tropsch synthesis, was confirmed.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0023158422020148</doi><tpages>8</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0023-1584 |
| ispartof | Kinetics and catalysis, 2022-04, Vol.63 (2), p.218-225 |
| issn | 0023-1584 1608-3210 |
| language | eng |
| recordid | cdi_proquest_journals_2665136866 |
| source | Springer Nature - Complete Springer Journals |
| subjects | Alcohol Alcohols Alkenes Aluminum oxide Catalysis Catalysts Chemistry Chemistry and Materials Science Fischer-Tropsch process High pressure Physical Chemistry Selectivity Silicon dioxide |
| title | Production of Alcohols and Olefins from CO and H2 on a Cobalt Catalyst at High Pressures and in the Gas Circulation Mode |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-21T05%3A35%3A01IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Production%20of%20Alcohols%20and%20Olefins%20from%20CO%20and%20H2%20on%20a%20Cobalt%20Catalyst%20at%20High%20Pressures%20and%20in%20the%20Gas%20Circulation%20Mode&rft.jtitle=Kinetics%20and%20catalysis&rft.au=Zubkov,%20I.%20N.&rft.date=2022-04-01&rft.volume=63&rft.issue=2&rft.spage=218&rft.epage=225&rft.pages=218-225&rft.issn=0023-1584&rft.eissn=1608-3210&rft_id=info:doi/10.1134/S0023158422020148&rft_dat=%3Cproquest_cross%3E2665136866%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2665136866&rft_id=info:pmid/&rfr_iscdi=true |