Supramolecular assemblies of Zn() complexes with a D-π-A ligand for sensing specific organic molecules
It is an attractive but challenging proposition to develop effective fluorescent sensors for detecting specific organic compounds. In this study, we designed and synthesized three Zn( ii ) complexes, namely [Zn(3N3PY) 2 ](NO 3 ) 2 ·3.5CH 3 OH ( 1 ), [Zn(3N3PY)(BIN)]·1.5DMF ( 2 ) and [Zn(3N3PY)(BIN)...
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| Veröffentlicht in: | CrystEngComm 2022-05, Vol.24 (19), p.3612-362 |
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| creator | Huang, Zi-Qing Chen, Jia-Qi Zhao, Shu-Man Qiu, Zhao-Feng Zhao, Yue Sun, Wei-Yin |
| description | It is an attractive but challenging proposition to develop effective fluorescent sensors for detecting specific organic compounds. In this study, we designed and synthesized three Zn(
ii
) complexes, namely [Zn(3N3PY)
2
](NO
3
)
2
·3.5CH
3
OH (
1
), [Zn(3N3PY)(BIN)]·1.5DMF (
2
) and [Zn(3N3PY)(BIN)
0.5
(HCOO)] (
3
) (H
2
BIN = 2,2′-biisonicotinic acid, HCOO
−
= formate), using a D-π-A ligand 4′-(4-(1
H
-1,2,4-triazol-1-yl)phenyl)-2,2′:6′,2′′-terpyridine (3N3PY) with mononuclear, one-dimensional (1D) chain and dinuclear structures, respectively. The three-dimensional (3D) supramolecular assemblies were achieved by the linkage of the Zn(
ii
) complexes through π-π and hydrogen bonding interactions. The assemblies demonstrated intense luminescence and exhibited an excellent ability for sensing specific organic molecules namely 2,4,6-trinitrophenol (TNP), 4-methylbenzaldehyde (4-MB) and decabromodiphenyl oxide (DBDPO).
Three Zn(
ii
) supramolecular assemblies are fabricated with a D-π-A ligand and present good fluorescent sensing properties for specific organic molecules. |
| doi_str_mv | 10.1039/d2ce00452f |
| format | Article |
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ii
) complexes, namely [Zn(3N3PY)
2
](NO
3
)
2
·3.5CH
3
OH (
1
), [Zn(3N3PY)(BIN)]·1.5DMF (
2
) and [Zn(3N3PY)(BIN)
0.5
(HCOO)] (
3
) (H
2
BIN = 2,2′-biisonicotinic acid, HCOO
−
= formate), using a D-π-A ligand 4′-(4-(1
H
-1,2,4-triazol-1-yl)phenyl)-2,2′:6′,2′′-terpyridine (3N3PY) with mononuclear, one-dimensional (1D) chain and dinuclear structures, respectively. The three-dimensional (3D) supramolecular assemblies were achieved by the linkage of the Zn(
ii
) complexes through π-π and hydrogen bonding interactions. The assemblies demonstrated intense luminescence and exhibited an excellent ability for sensing specific organic molecules namely 2,4,6-trinitrophenol (TNP), 4-methylbenzaldehyde (4-MB) and decabromodiphenyl oxide (DBDPO).
Three Zn(
ii
) supramolecular assemblies are fabricated with a D-π-A ligand and present good fluorescent sensing properties for specific organic molecules.</description><identifier>ISSN: 1466-8033</identifier><identifier>EISSN: 1466-8033</identifier><identifier>DOI: 10.1039/d2ce00452f</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Assemblies ; Fluorescence ; Hydrogen bonding ; Ligands ; Organic chemistry ; Organic compounds</subject><ispartof>CrystEngComm, 2022-05, Vol.24 (19), p.3612-362</ispartof><rights>Copyright Royal Society of Chemistry 2022</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c281t-57e661cc6160d0cbe1fdee56ad1aaabbb5792f7648b8641afb68def5af4fff703</citedby><cites>FETCH-LOGICAL-c281t-57e661cc6160d0cbe1fdee56ad1aaabbb5792f7648b8641afb68def5af4fff703</cites><orcidid>0000-0001-6094-4087 ; 0000-0001-8966-9728</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27923,27924</link.rule.ids></links><search><creatorcontrib>Huang, Zi-Qing</creatorcontrib><creatorcontrib>Chen, Jia-Qi</creatorcontrib><creatorcontrib>Zhao, Shu-Man</creatorcontrib><creatorcontrib>Qiu, Zhao-Feng</creatorcontrib><creatorcontrib>Zhao, Yue</creatorcontrib><creatorcontrib>Sun, Wei-Yin</creatorcontrib><title>Supramolecular assemblies of Zn() complexes with a D-π-A ligand for sensing specific organic molecules</title><title>CrystEngComm</title><description>It is an attractive but challenging proposition to develop effective fluorescent sensors for detecting specific organic compounds. In this study, we designed and synthesized three Zn(
ii
) complexes, namely [Zn(3N3PY)
2
](NO
3
)
2
·3.5CH
3
OH (
1
), [Zn(3N3PY)(BIN)]·1.5DMF (
2
) and [Zn(3N3PY)(BIN)
0.5
(HCOO)] (
3
) (H
2
BIN = 2,2′-biisonicotinic acid, HCOO
−
= formate), using a D-π-A ligand 4′-(4-(1
H
-1,2,4-triazol-1-yl)phenyl)-2,2′:6′,2′′-terpyridine (3N3PY) with mononuclear, one-dimensional (1D) chain and dinuclear structures, respectively. The three-dimensional (3D) supramolecular assemblies were achieved by the linkage of the Zn(
ii
) complexes through π-π and hydrogen bonding interactions. The assemblies demonstrated intense luminescence and exhibited an excellent ability for sensing specific organic molecules namely 2,4,6-trinitrophenol (TNP), 4-methylbenzaldehyde (4-MB) and decabromodiphenyl oxide (DBDPO).
Three Zn(
ii
) supramolecular assemblies are fabricated with a D-π-A ligand and present good fluorescent sensing properties for specific organic molecules.</description><subject>Assemblies</subject><subject>Fluorescence</subject><subject>Hydrogen bonding</subject><subject>Ligands</subject><subject>Organic chemistry</subject><subject>Organic compounds</subject><issn>1466-8033</issn><issn>1466-8033</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNpNkE1LxDAQhoMouK5evAsBLypUM2mado_Lfqiw4EG9eClJOlm7tE1Ntqg3_6F_yeou6ukdZh7egYeQY2CXwOLRVcENMiYSbnfIAISUUcbiePffvE8OQlgxBgKADcjyvmu9ql2FpquUpyoErHVVYqDO0qfm7JwaV7cVvvWb13L9TBWdRp8f0ZhW5VI1BbXO04BNKJslDS2a0paGOt_f-twWYzgke1ZVAY-2OSSP89nD5CZa3F3fTsaLyPAM1lGSopRgjATJCmY0gi0QE6kKUEpprZN0xG0qRaYzKUBZLbMCbaKssNamLB6S001v691Lh2Gdr1znm_5lzqVMgHMYiZ662FDGuxA82rz1Za38ew4s_xaZT_lk9iNy3sMnG9gH88v9iY6_ALCIcWI</recordid><startdate>20220517</startdate><enddate>20220517</enddate><creator>Huang, Zi-Qing</creator><creator>Chen, Jia-Qi</creator><creator>Zhao, Shu-Man</creator><creator>Qiu, Zhao-Feng</creator><creator>Zhao, Yue</creator><creator>Sun, Wei-Yin</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0001-6094-4087</orcidid><orcidid>https://orcid.org/0000-0001-8966-9728</orcidid></search><sort><creationdate>20220517</creationdate><title>Supramolecular assemblies of Zn() complexes with a D-π-A ligand for sensing specific organic molecules</title><author>Huang, Zi-Qing ; Chen, Jia-Qi ; Zhao, Shu-Man ; Qiu, Zhao-Feng ; Zhao, Yue ; Sun, Wei-Yin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c281t-57e661cc6160d0cbe1fdee56ad1aaabbb5792f7648b8641afb68def5af4fff703</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Assemblies</topic><topic>Fluorescence</topic><topic>Hydrogen bonding</topic><topic>Ligands</topic><topic>Organic chemistry</topic><topic>Organic compounds</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Huang, Zi-Qing</creatorcontrib><creatorcontrib>Chen, Jia-Qi</creatorcontrib><creatorcontrib>Zhao, Shu-Man</creatorcontrib><creatorcontrib>Qiu, Zhao-Feng</creatorcontrib><creatorcontrib>Zhao, Yue</creatorcontrib><creatorcontrib>Sun, Wei-Yin</creatorcontrib><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>CrystEngComm</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Huang, Zi-Qing</au><au>Chen, Jia-Qi</au><au>Zhao, Shu-Man</au><au>Qiu, Zhao-Feng</au><au>Zhao, Yue</au><au>Sun, Wei-Yin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Supramolecular assemblies of Zn() complexes with a D-π-A ligand for sensing specific organic molecules</atitle><jtitle>CrystEngComm</jtitle><date>2022-05-17</date><risdate>2022</risdate><volume>24</volume><issue>19</issue><spage>3612</spage><epage>362</epage><pages>3612-362</pages><issn>1466-8033</issn><eissn>1466-8033</eissn><abstract>It is an attractive but challenging proposition to develop effective fluorescent sensors for detecting specific organic compounds. In this study, we designed and synthesized three Zn(
ii
) complexes, namely [Zn(3N3PY)
2
](NO
3
)
2
·3.5CH
3
OH (
1
), [Zn(3N3PY)(BIN)]·1.5DMF (
2
) and [Zn(3N3PY)(BIN)
0.5
(HCOO)] (
3
) (H
2
BIN = 2,2′-biisonicotinic acid, HCOO
−
= formate), using a D-π-A ligand 4′-(4-(1
H
-1,2,4-triazol-1-yl)phenyl)-2,2′:6′,2′′-terpyridine (3N3PY) with mononuclear, one-dimensional (1D) chain and dinuclear structures, respectively. The three-dimensional (3D) supramolecular assemblies were achieved by the linkage of the Zn(
ii
) complexes through π-π and hydrogen bonding interactions. The assemblies demonstrated intense luminescence and exhibited an excellent ability for sensing specific organic molecules namely 2,4,6-trinitrophenol (TNP), 4-methylbenzaldehyde (4-MB) and decabromodiphenyl oxide (DBDPO).
Three Zn(
ii
) supramolecular assemblies are fabricated with a D-π-A ligand and present good fluorescent sensing properties for specific organic molecules.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d2ce00452f</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0001-6094-4087</orcidid><orcidid>https://orcid.org/0000-0001-8966-9728</orcidid></addata></record> |
| fulltext | fulltext |
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| issn | 1466-8033 1466-8033 |
| language | eng |
| recordid | cdi_proquest_journals_2665122194 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Assemblies Fluorescence Hydrogen bonding Ligands Organic chemistry Organic compounds |
| title | Supramolecular assemblies of Zn() complexes with a D-π-A ligand for sensing specific organic molecules |
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