Rapid thermal processing of TiN coatings deposited by chemical and physical vapor deposition using a low-energy, high-current electron beam : Microstructural studies and properties
Monolithic TiN coatings deposited onto cemented carbide cutting tool inserts coated by chemical vapor deposition (CVD) or physical vapor deposition (PVD) methods, respectively, were subjected to pulsed intense electron beam treatments in the energy range 3 to 5 J·cm−2. The temperature profiles for t...
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| Veröffentlicht in: | Metallurgical and Materials Transactions. A, Physical Metallurgy and Materials Science Physical Metallurgy and Materials Science, 1999-11, Vol.30 (11), p.2931-2939 |
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| container_title | Metallurgical and Materials Transactions. A, Physical Metallurgy and Materials Science |
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| creator | PERRY, A. J MATOSSIAN, J. N ROTSHTEIN, V. P MARKOV, A. B BULL, S. J PROSKUROVSKY, D. I RICE-EVANS, P. C PAGE, T. F GEIST, D. E TAYLOR, J VAJO, J. J DOTY, R. E |
| description | Monolithic TiN coatings deposited onto cemented carbide cutting tool inserts coated by chemical vapor deposition (CVD) or physical vapor deposition (PVD) methods, respectively, were subjected to pulsed intense electron beam treatments in the energy range 3 to 5 J·cm−2. The temperature profiles for this rapid thermal processing (RTP) covered the range between fusion of the cobalt binder in the carbide to surface fusion of the TiN coatings. The treatment caused extensive cracking in all coatings, removed the atomic level defects, vacancies and dislocations, and the residual stress in the PVD coatings, but caused little change in the CVD coatings. There was some nitorgen loss very close to the surface but no change in the stoichiometry of the bulk of the nitride. In contrast, no changes were found in the carbide substrate below the PVD coatings, but microscopic changes were found immediately below the surface in the carbide under the CVD coatings. Steel turning tests suggest that treatment of the PVD coatings at the lowest power used, 3 J·cm−2, reduced the flank wear by a factor of 2 but had no effect on any of the CVD coatings. |
| doi_str_mv | 10.1007/s11661-999-0130-9 |
| format | Article |
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J ; MATOSSIAN, J. N ; ROTSHTEIN, V. P ; MARKOV, A. B ; BULL, S. J ; PROSKUROVSKY, D. I ; RICE-EVANS, P. C ; PAGE, T. F ; GEIST, D. E ; TAYLOR, J ; VAJO, J. J ; DOTY, R. E</creator><creatorcontrib>PERRY, A. J ; MATOSSIAN, J. N ; ROTSHTEIN, V. P ; MARKOV, A. B ; BULL, S. J ; PROSKUROVSKY, D. I ; RICE-EVANS, P. C ; PAGE, T. F ; GEIST, D. E ; TAYLOR, J ; VAJO, J. J ; DOTY, R. E ; AIMS Marketing, San Diego, CA (US)</creatorcontrib><description>Monolithic TiN coatings deposited onto cemented carbide cutting tool inserts coated by chemical vapor deposition (CVD) or physical vapor deposition (PVD) methods, respectively, were subjected to pulsed intense electron beam treatments in the energy range 3 to 5 J·cm−2. The temperature profiles for this rapid thermal processing (RTP) covered the range between fusion of the cobalt binder in the carbide to surface fusion of the TiN coatings. The treatment caused extensive cracking in all coatings, removed the atomic level defects, vacancies and dislocations, and the residual stress in the PVD coatings, but caused little change in the CVD coatings. There was some nitorgen loss very close to the surface but no change in the stoichiometry of the bulk of the nitride. In contrast, no changes were found in the carbide substrate below the PVD coatings, but microscopic changes were found immediately below the surface in the carbide under the CVD coatings. Steel turning tests suggest that treatment of the PVD coatings at the lowest power used, 3 J·cm−2, reduced the flank wear by a factor of 2 but had no effect on any of the CVD coatings.</description><identifier>ISSN: 1073-5623</identifier><identifier>EISSN: 1543-1940</identifier><identifier>DOI: 10.1007/s11661-999-0130-9</identifier><identifier>CODEN: MMTAEB</identifier><language>eng</language><publisher>New York, NY: Springer</publisher><subject>Carbide cutting tools ; Carbide tools ; Cemented carbides ; Chemical vapor deposition ; Coatings ; CRACKS ; CUTTING TOOLS ; ELECTRON BEAMS ; ENERGY LEVELS ; HEAT TREATMENTS ; Inserts ; MATERIALS SCIENCE ; MELTING ; MICROSTRUCTURE ; Physical vapor deposition ; Residual stress ; Stoichiometry ; STRESS RELAXATION ; Substrates ; Temperature profiles ; Titanium nitride ; TITANIUM NITRIDES ; Tool wear ; Turning (machining) ; VAPOR DEPOSITED COATINGS</subject><ispartof>Metallurgical and Materials Transactions. 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A, Physical Metallurgy and Materials Science</title><description>Monolithic TiN coatings deposited onto cemented carbide cutting tool inserts coated by chemical vapor deposition (CVD) or physical vapor deposition (PVD) methods, respectively, were subjected to pulsed intense electron beam treatments in the energy range 3 to 5 J·cm−2. The temperature profiles for this rapid thermal processing (RTP) covered the range between fusion of the cobalt binder in the carbide to surface fusion of the TiN coatings. The treatment caused extensive cracking in all coatings, removed the atomic level defects, vacancies and dislocations, and the residual stress in the PVD coatings, but caused little change in the CVD coatings. There was some nitorgen loss very close to the surface but no change in the stoichiometry of the bulk of the nitride. In contrast, no changes were found in the carbide substrate below the PVD coatings, but microscopic changes were found immediately below the surface in the carbide under the CVD coatings. Steel turning tests suggest that treatment of the PVD coatings at the lowest power used, 3 J·cm−2, reduced the flank wear by a factor of 2 but had no effect on any of the CVD coatings.</description><subject>Carbide cutting tools</subject><subject>Carbide tools</subject><subject>Cemented carbides</subject><subject>Chemical vapor deposition</subject><subject>Coatings</subject><subject>CRACKS</subject><subject>CUTTING TOOLS</subject><subject>ELECTRON BEAMS</subject><subject>ENERGY LEVELS</subject><subject>HEAT TREATMENTS</subject><subject>Inserts</subject><subject>MATERIALS SCIENCE</subject><subject>MELTING</subject><subject>MICROSTRUCTURE</subject><subject>Physical vapor deposition</subject><subject>Residual stress</subject><subject>Stoichiometry</subject><subject>STRESS RELAXATION</subject><subject>Substrates</subject><subject>Temperature profiles</subject><subject>Titanium nitride</subject><subject>TITANIUM NITRIDES</subject><subject>Tool wear</subject><subject>Turning (machining)</subject><subject>VAPOR DEPOSITED COATINGS</subject><issn>1073-5623</issn><issn>1543-1940</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1999</creationdate><recordtype>article</recordtype><sourceid>8G5</sourceid><sourceid>BENPR</sourceid><sourceid>GUQSH</sourceid><sourceid>M2O</sourceid><recordid>eNp1UU1v1DAUjBBIlMIP4GYBRwx2HDsxN1SVD6mAhMrZsp9fNq5242A7oP1f_ECcblFPnOyRZubNe9M0zzl7wxnr32bOleJUa00ZF4zqB80Zl52gXHfsYf2zXlCpWvG4eZLzDWOMa6HOmj_f7RI8KROmg92TJUXAnMO8I3Ek1-ErgWhLhZl4XGIOBT1xRwITHgJUgZ09WaZjvgW_7BLTP2KIM1lvnSzZx98UZ0y742syhd1EYU0J50Jwj1BSZTq0B_KOfAmQYi5phbKm6pjL6gPm05gUF0ylwqfNo9HuMz67e8-bHx8ury8-0atvHz9fvL-iIKQstLfWji0MzgkUqJnsJB-E1A704Jn2ndQt2GHwI4If3YBeWWid02xgbtBMnDcvT741UjAZ6vYwQZznGtq02w17oe5ZNeDPFXMxN3FNcw1mWqU61fdt11XWi_-yuOirldwG8hNpu0JOOJolhYNNR8OZ2Xo2p55N7dlsPRtdNa_ujG2uJYzJzhDyvbAVUnRa_AX6datp</recordid><startdate>19991101</startdate><enddate>19991101</enddate><creator>PERRY, A. 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A, Physical Metallurgy and Materials Science</jtitle><date>1999-11-01</date><risdate>1999</risdate><volume>30</volume><issue>11</issue><spage>2931</spage><epage>2939</epage><pages>2931-2939</pages><issn>1073-5623</issn><eissn>1543-1940</eissn><coden>MMTAEB</coden><abstract>Monolithic TiN coatings deposited onto cemented carbide cutting tool inserts coated by chemical vapor deposition (CVD) or physical vapor deposition (PVD) methods, respectively, were subjected to pulsed intense electron beam treatments in the energy range 3 to 5 J·cm−2. The temperature profiles for this rapid thermal processing (RTP) covered the range between fusion of the cobalt binder in the carbide to surface fusion of the TiN coatings. The treatment caused extensive cracking in all coatings, removed the atomic level defects, vacancies and dislocations, and the residual stress in the PVD coatings, but caused little change in the CVD coatings. There was some nitorgen loss very close to the surface but no change in the stoichiometry of the bulk of the nitride. In contrast, no changes were found in the carbide substrate below the PVD coatings, but microscopic changes were found immediately below the surface in the carbide under the CVD coatings. Steel turning tests suggest that treatment of the PVD coatings at the lowest power used, 3 J·cm−2, reduced the flank wear by a factor of 2 but had no effect on any of the CVD coatings.</abstract><cop>New York, NY</cop><pub>Springer</pub><doi>10.1007/s11661-999-0130-9</doi><tpages>9</tpages></addata></record> |
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| identifier | ISSN: 1073-5623 |
| ispartof | Metallurgical and Materials Transactions. A, Physical Metallurgy and Materials Science, 1999-11, Vol.30 (11), p.2931-2939 |
| issn | 1073-5623 1543-1940 |
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| source | Springer Nature - Complete Springer Journals |
| subjects | Carbide cutting tools Carbide tools Cemented carbides Chemical vapor deposition Coatings CRACKS CUTTING TOOLS ELECTRON BEAMS ENERGY LEVELS HEAT TREATMENTS Inserts MATERIALS SCIENCE MELTING MICROSTRUCTURE Physical vapor deposition Residual stress Stoichiometry STRESS RELAXATION Substrates Temperature profiles Titanium nitride TITANIUM NITRIDES Tool wear Turning (machining) VAPOR DEPOSITED COATINGS |
| title | Rapid thermal processing of TiN coatings deposited by chemical and physical vapor deposition using a low-energy, high-current electron beam : Microstructural studies and properties |
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