Buddledin C from Pulicaria prostrata and selective synthesis of its epoxy derivative
The structure of the sesquiterpene ketone buddledin C isolated from Pulicaria prostrata (Gilib.) Aschers., was confirmed by XSA. The stereochemistry of its epoxide, which was formed selectively by treating it with hydrogen peroxide in alkaline solution, was proposed based on quantum-chemical and mol...
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| Veröffentlicht in: | Chemistry of natural compounds 2006-01, Vol.42 (1), p.41-45 |
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| container_title | Chemistry of natural compounds |
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| creator | Sadyrbekov, D. T. Atazhanova, G. A. Kulyyasov, A. T. Raldugin, V. A. Gatilov, Yu. V. Shakirov, M. M. Edil’baeva, T. T. Turdybekov, K. M. Adekenov, S. M. |
| description | The structure of the sesquiterpene ketone buddledin C isolated from Pulicaria prostrata (Gilib.) Aschers., was confirmed by XSA. The stereochemistry of its epoxide, which was formed selectively by treating it with hydrogen peroxide in alkaline solution, was proposed based on quantum-chemical and molecular-mechanical calculations. |
| doi_str_mv | 10.1007/s10600-006-0032-7 |
| format | Article |
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| ispartof | Chemistry of natural compounds, 2006-01, Vol.42 (1), p.41-45 |
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| language | eng |
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| source | SpringerLink Journals - AutoHoldings |
| subjects | Hydrogen peroxide Ketones Quantum chemistry Stereochemistry |
| title | Buddledin C from Pulicaria prostrata and selective synthesis of its epoxy derivative |
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