Construction of a room-temperature phosphorescence system by cucurbit[8]uril-based supramolecular assembly
A bromophenylpyridine derivative (BH-PY) was designed and synthesized as the guest molecule included in the cavity of cucurbit[8]uril (CB[8]) to form a 2:1 host–guest complex, which displays good room-temperature phosphorescence (RTP) in aqueous solutions. The interaction and optical properties of C...
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| Veröffentlicht in: | Journal of inclusion phenomena and macrocyclic chemistry 2022-06, Vol.102 (5-6), p.429-437 |
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| container_issue | 5-6 |
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| container_title | Journal of inclusion phenomena and macrocyclic chemistry |
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| creator | Chen, Yuhe Yang, Jingsha Zhang, Shuai Xi, Zeng Luo, Heng |
| description | A bromophenylpyridine derivative (BH-PY) was designed and synthesized as the guest molecule included in the cavity of cucurbit[8]uril (CB[8]) to form a 2:1 host–guest complex, which displays good room-temperature phosphorescence (RTP) in aqueous solutions. The interaction and optical properties of CB[8] with a guest in aqueous solution were investigated using
1
H NMR spectroscopy, UV–Vis absorbance spectra, fluorescence and phosphorescence spectra and X-ray diffraction analysis in detail. The result showed that the bromophenyl moieties of the two guest molecules are included in the cavity of the CB[8] in a ‘head-to-tail’ stacking way, whereas the other part of BH-PY remains outside the portal to form a 2:1 supramolecular structurce, and supramolecular assemblies were applied for targeted phosphorescent imaging of mitochondria. |
| doi_str_mv | 10.1007/s10847-022-01129-2 |
| format | Article |
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1
H NMR spectroscopy, UV–Vis absorbance spectra, fluorescence and phosphorescence spectra and X-ray diffraction analysis in detail. The result showed that the bromophenyl moieties of the two guest molecules are included in the cavity of the CB[8] in a ‘head-to-tail’ stacking way, whereas the other part of BH-PY remains outside the portal to form a 2:1 supramolecular structurce, and supramolecular assemblies were applied for targeted phosphorescent imaging of mitochondria.</description><identifier>ISSN: 1388-3127</identifier><identifier>EISSN: 1573-1111</identifier><identifier>DOI: 10.1007/s10847-022-01129-2</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Aqueous solutions ; Chemical synthesis ; Chemistry ; Chemistry and Materials Science ; Crystallography and Scattering Methods ; Food Science ; Mitochondria ; NMR spectroscopy ; Optical properties ; Organic Chemistry ; Phosphorescence ; Review Article ; Room temperature ; Spectra ; Spectrum analysis ; Supramolecular compounds</subject><ispartof>Journal of inclusion phenomena and macrocyclic chemistry, 2022-06, Vol.102 (5-6), p.429-437</ispartof><rights>The Author(s), under exclusive licence to Springer Nature B.V. 2022</rights><rights>The Author(s), under exclusive licence to Springer Nature B.V. 2022.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-58cb9f561f21789564c943957824cc3e2d839e65dd04869026ecc8891acd1a5f3</citedby><cites>FETCH-LOGICAL-c319t-58cb9f561f21789564c943957824cc3e2d839e65dd04869026ecc8891acd1a5f3</cites><orcidid>0000-0001-7379-8410</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10847-022-01129-2$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10847-022-01129-2$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51298</link.rule.ids></links><search><creatorcontrib>Chen, Yuhe</creatorcontrib><creatorcontrib>Yang, Jingsha</creatorcontrib><creatorcontrib>Zhang, Shuai</creatorcontrib><creatorcontrib>Xi, Zeng</creatorcontrib><creatorcontrib>Luo, Heng</creatorcontrib><title>Construction of a room-temperature phosphorescence system by cucurbit[8]uril-based supramolecular assembly</title><title>Journal of inclusion phenomena and macrocyclic chemistry</title><addtitle>J Incl Phenom Macrocycl Chem</addtitle><description>A bromophenylpyridine derivative (BH-PY) was designed and synthesized as the guest molecule included in the cavity of cucurbit[8]uril (CB[8]) to form a 2:1 host–guest complex, which displays good room-temperature phosphorescence (RTP) in aqueous solutions. The interaction and optical properties of CB[8] with a guest in aqueous solution were investigated using
1
H NMR spectroscopy, UV–Vis absorbance spectra, fluorescence and phosphorescence spectra and X-ray diffraction analysis in detail. The result showed that the bromophenyl moieties of the two guest molecules are included in the cavity of the CB[8] in a ‘head-to-tail’ stacking way, whereas the other part of BH-PY remains outside the portal to form a 2:1 supramolecular structurce, and supramolecular assemblies were applied for targeted phosphorescent imaging of mitochondria.</description><subject>Aqueous solutions</subject><subject>Chemical synthesis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Crystallography and Scattering Methods</subject><subject>Food Science</subject><subject>Mitochondria</subject><subject>NMR spectroscopy</subject><subject>Optical properties</subject><subject>Organic Chemistry</subject><subject>Phosphorescence</subject><subject>Review Article</subject><subject>Room temperature</subject><subject>Spectra</subject><subject>Spectrum analysis</subject><subject>Supramolecular compounds</subject><issn>1388-3127</issn><issn>1573-1111</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp9kMtKxTAQhoMoeLy8gKuA62gubZos5eANDrjRlUhI01R7aJuaaRZ9e6MV3DkwzMD8_wzzIXTB6BWjtLoGRlVREco5oYxxTfgB2rCyEoTlOMy9UIoIxqtjdAKwp5RLXogN2m_DCHNMbu7CiEOLLY4hDGT2w-SjnVP0ePoIkDN6cH50HsMCeYzrBbvkUqy7-VW9pdj1pLbgGwxpinYIvXeptxFbAD_U_XKGjlrbgz__rafo5e72eftAdk_3j9ubHXGC6ZmUytW6LSVrOauULmXhdCF0WSleOCc8b5TQXpZNQwsldX7EO6eUZtY1zJatOEWX694phs_kYTb7kOKYTxouZUGlUlJkFV9VLgaA6FszxW6wcTGMmm-mZmVqMlPzw9TwbBKrCbJ4fPfxb_U_ri-5NHun</recordid><startdate>20220601</startdate><enddate>20220601</enddate><creator>Chen, Yuhe</creator><creator>Yang, Jingsha</creator><creator>Zhang, Shuai</creator><creator>Xi, Zeng</creator><creator>Luo, Heng</creator><general>Springer Netherlands</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0001-7379-8410</orcidid></search><sort><creationdate>20220601</creationdate><title>Construction of a room-temperature phosphorescence system by cucurbit[8]uril-based supramolecular assembly</title><author>Chen, Yuhe ; Yang, Jingsha ; Zhang, Shuai ; Xi, Zeng ; Luo, Heng</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-58cb9f561f21789564c943957824cc3e2d839e65dd04869026ecc8891acd1a5f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Aqueous solutions</topic><topic>Chemical synthesis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Crystallography and Scattering Methods</topic><topic>Food Science</topic><topic>Mitochondria</topic><topic>NMR spectroscopy</topic><topic>Optical properties</topic><topic>Organic Chemistry</topic><topic>Phosphorescence</topic><topic>Review Article</topic><topic>Room temperature</topic><topic>Spectra</topic><topic>Spectrum analysis</topic><topic>Supramolecular compounds</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Chen, Yuhe</creatorcontrib><creatorcontrib>Yang, Jingsha</creatorcontrib><creatorcontrib>Zhang, Shuai</creatorcontrib><creatorcontrib>Xi, Zeng</creatorcontrib><creatorcontrib>Luo, Heng</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of inclusion phenomena and macrocyclic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chen, Yuhe</au><au>Yang, Jingsha</au><au>Zhang, Shuai</au><au>Xi, Zeng</au><au>Luo, Heng</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Construction of a room-temperature phosphorescence system by cucurbit[8]uril-based supramolecular assembly</atitle><jtitle>Journal of inclusion phenomena and macrocyclic chemistry</jtitle><stitle>J Incl Phenom Macrocycl Chem</stitle><date>2022-06-01</date><risdate>2022</risdate><volume>102</volume><issue>5-6</issue><spage>429</spage><epage>437</epage><pages>429-437</pages><issn>1388-3127</issn><eissn>1573-1111</eissn><abstract>A bromophenylpyridine derivative (BH-PY) was designed and synthesized as the guest molecule included in the cavity of cucurbit[8]uril (CB[8]) to form a 2:1 host–guest complex, which displays good room-temperature phosphorescence (RTP) in aqueous solutions. The interaction and optical properties of CB[8] with a guest in aqueous solution were investigated using
1
H NMR spectroscopy, UV–Vis absorbance spectra, fluorescence and phosphorescence spectra and X-ray diffraction analysis in detail. The result showed that the bromophenyl moieties of the two guest molecules are included in the cavity of the CB[8] in a ‘head-to-tail’ stacking way, whereas the other part of BH-PY remains outside the portal to form a 2:1 supramolecular structurce, and supramolecular assemblies were applied for targeted phosphorescent imaging of mitochondria.</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s10847-022-01129-2</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0001-7379-8410</orcidid></addata></record> |
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| source | Springer Nature - Complete Springer Journals |
| subjects | Aqueous solutions Chemical synthesis Chemistry Chemistry and Materials Science Crystallography and Scattering Methods Food Science Mitochondria NMR spectroscopy Optical properties Organic Chemistry Phosphorescence Review Article Room temperature Spectra Spectrum analysis Supramolecular compounds |
| title | Construction of a room-temperature phosphorescence system by cucurbit[8]uril-based supramolecular assembly |
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