The discrete evolution of the structure of hydrogenated palladium-based alloys
The discrete character of the diffraction-angle dependence of displacements in the position of the components of diffraction peaks of hydrogenated Pd-Mo and Pd-Ta alloys is established using precise x-ray diffractometry. Such behavior is interpreted in terms of discontinuous transitions between long...
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| Veröffentlicht in: | Physics of the solid state 2004-03, Vol.46 (3), p.411-419 |
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| container_title | Physics of the solid state |
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| creator | Avdyukhina, V. M. Anishchenko, A. A. Katsnel’son, A. A. Olemskoi, A. I. Revkevich, G. P. |
| description | The discrete character of the diffraction-angle dependence of displacements in the position of the components of diffraction peaks of hydrogenated Pd-Mo and Pd-Ta alloys is established using precise x-ray diffractometry. Such behavior is interpreted in terms of discontinuous transitions between long-lived metastable states under the assumption of a multivalley structure of the thermodynamic potential in k space. This assumption makes it possible to explain the fact that the components of diffraction reflections were narrow over the storage time (which was as long as several thousand hours). |
| doi_str_mv | 10.1134/1.1687852 |
| format | Article |
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| subjects | Diffraction Hydrogenation Metastable state Palladium Palladium base alloys |
| title | The discrete evolution of the structure of hydrogenated palladium-based alloys |
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