Sorption and Reaction of Biomass Derived HC Blends and Their Constituents on a Commercial Pt–Pd/Al2O3 Oxidation Catalyst
Within the Research Cluster of Excellence “The Fuel Science Center” at RWTH Aachen University, the production and application of new fuels from bio-based carbon feedstocks and CO 2 with hydrogen from renewable electricity generation is being investigated. In this study, the storage and oxidation of...
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| Veröffentlicht in: | Catalysis letters 2022-06, Vol.152 (6), p.1880-1894 |
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| creator | Schönberger, Ariel Augusto Haselmann, Greta Marie Wolkenar, Bernd Schönebaum, Simon Mauermann, Peter Sterlepper, Stefan Pischinger, Stefan Simon, Ulrich |
| description | Within the Research Cluster of Excellence “The Fuel Science Center” at RWTH Aachen University, the production and application of new fuels from bio-based carbon feedstocks and CO
2
with hydrogen from renewable electricity generation is being investigated. In this study, the storage and oxidation of ethanol, 1-butanol, 2-butanone, cyclopentanone, and cyclopentane as well as two blends thereof on a series production Pt–Pd/Al
2
O
3
oxidation catalyst were investigated. Hydrocarbon (HC) storage and temperature-programmed surface reaction (TPSR) experiments were carried out to analyze their adsorption and desorption behavior. In addition, the individual HCs and both blends were investigated using Diffuse Reflectance Infrared Fourier Transform Spectroscopy (TP-DRIFTS). In general, all oxygenated HCs are adsorbed more strongly than cyclopentane due to their higher polarity. Interestingly, it could be observed that the two different blends [blend 1: ethanol (50 mol %), 2-butanone (21 mol %), cyclopentanone (14 mol %) and cyclopentane (15 mol %); blend 2: 1-butanol (45 mol %), ethanol (29 mol %) and cyclopentane (27 mol %)] exhibit a different storage behavior compared to the single hydrocarbons. It was shown that the presence of 1-butanol and cyclopentane in blend 2 strongly inhibits the oxidation of ethanol. As a result, the ethanol light-off temperature was increased by at least 100 K. A difference was also found in the storage behavior of cyclopentane. While no significant storage could be detected in the pure compound experiment, the experiments with both mixtures showed a larger amount stored. The presence of adsorbed species of the hydrocarbons and their corresponding reaction products has been demonstrated and gives an insight into the storage mechanism of blends.
Graphic Abstract |
| doi_str_mv | 10.1007/s10562-021-03771-w |
| format | Article |
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2
with hydrogen from renewable electricity generation is being investigated. In this study, the storage and oxidation of ethanol, 1-butanol, 2-butanone, cyclopentanone, and cyclopentane as well as two blends thereof on a series production Pt–Pd/Al
2
O
3
oxidation catalyst were investigated. Hydrocarbon (HC) storage and temperature-programmed surface reaction (TPSR) experiments were carried out to analyze their adsorption and desorption behavior. In addition, the individual HCs and both blends were investigated using Diffuse Reflectance Infrared Fourier Transform Spectroscopy (TP-DRIFTS). In general, all oxygenated HCs are adsorbed more strongly than cyclopentane due to their higher polarity. Interestingly, it could be observed that the two different blends [blend 1: ethanol (50 mol %), 2-butanone (21 mol %), cyclopentanone (14 mol %) and cyclopentane (15 mol %); blend 2: 1-butanol (45 mol %), ethanol (29 mol %) and cyclopentane (27 mol %)] exhibit a different storage behavior compared to the single hydrocarbons. It was shown that the presence of 1-butanol and cyclopentane in blend 2 strongly inhibits the oxidation of ethanol. As a result, the ethanol light-off temperature was increased by at least 100 K. A difference was also found in the storage behavior of cyclopentane. While no significant storage could be detected in the pure compound experiment, the experiments with both mixtures showed a larger amount stored. The presence of adsorbed species of the hydrocarbons and their corresponding reaction products has been demonstrated and gives an insight into the storage mechanism of blends.
Graphic Abstract</description><identifier>ISSN: 1011-372X</identifier><identifier>EISSN: 1572-879X</identifier><identifier>DOI: 10.1007/s10562-021-03771-w</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Aluminum oxide ; Butanol ; Catalysis ; Catalysts ; Chemistry ; Chemistry and Materials Science ; Ethanol ; Fourier transforms ; Hydrocarbons ; Industrial Chemistry/Chemical Engineering ; Mixtures ; Organometallic Chemistry ; Oxidation ; Palladium ; Physical Chemistry ; Platinum ; Reaction products ; Surface reactions</subject><ispartof>Catalysis letters, 2022-06, Vol.152 (6), p.1880-1894</ispartof><rights>The Author(s) 2021</rights><rights>The Author(s) 2021. This work is published under http://creativecommons.org/licenses/by/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c363t-361b4f9f327c1406009ffcbc9a42c34b920b24bec5872f824b6a5725331b5c63</citedby><cites>FETCH-LOGICAL-c363t-361b4f9f327c1406009ffcbc9a42c34b920b24bec5872f824b6a5725331b5c63</cites><orcidid>0000-0002-0490-1178</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10562-021-03771-w$$EPDF$$P50$$Gspringer$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10562-021-03771-w$$EHTML$$P50$$Gspringer$$Hfree_for_read</linktohtml><link.rule.ids>315,781,785,27929,27930,41493,42562,51324</link.rule.ids></links><search><creatorcontrib>Schönberger, Ariel Augusto</creatorcontrib><creatorcontrib>Haselmann, Greta Marie</creatorcontrib><creatorcontrib>Wolkenar, Bernd</creatorcontrib><creatorcontrib>Schönebaum, Simon</creatorcontrib><creatorcontrib>Mauermann, Peter</creatorcontrib><creatorcontrib>Sterlepper, Stefan</creatorcontrib><creatorcontrib>Pischinger, Stefan</creatorcontrib><creatorcontrib>Simon, Ulrich</creatorcontrib><title>Sorption and Reaction of Biomass Derived HC Blends and Their Constituents on a Commercial Pt–Pd/Al2O3 Oxidation Catalyst</title><title>Catalysis letters</title><addtitle>Catal Lett</addtitle><description>Within the Research Cluster of Excellence “The Fuel Science Center” at RWTH Aachen University, the production and application of new fuels from bio-based carbon feedstocks and CO
2
with hydrogen from renewable electricity generation is being investigated. In this study, the storage and oxidation of ethanol, 1-butanol, 2-butanone, cyclopentanone, and cyclopentane as well as two blends thereof on a series production Pt–Pd/Al
2
O
3
oxidation catalyst were investigated. Hydrocarbon (HC) storage and temperature-programmed surface reaction (TPSR) experiments were carried out to analyze their adsorption and desorption behavior. In addition, the individual HCs and both blends were investigated using Diffuse Reflectance Infrared Fourier Transform Spectroscopy (TP-DRIFTS). In general, all oxygenated HCs are adsorbed more strongly than cyclopentane due to their higher polarity. Interestingly, it could be observed that the two different blends [blend 1: ethanol (50 mol %), 2-butanone (21 mol %), cyclopentanone (14 mol %) and cyclopentane (15 mol %); blend 2: 1-butanol (45 mol %), ethanol (29 mol %) and cyclopentane (27 mol %)] exhibit a different storage behavior compared to the single hydrocarbons. It was shown that the presence of 1-butanol and cyclopentane in blend 2 strongly inhibits the oxidation of ethanol. As a result, the ethanol light-off temperature was increased by at least 100 K. A difference was also found in the storage behavior of cyclopentane. While no significant storage could be detected in the pure compound experiment, the experiments with both mixtures showed a larger amount stored. The presence of adsorbed species of the hydrocarbons and their corresponding reaction products has been demonstrated and gives an insight into the storage mechanism of blends.
Graphic Abstract</description><subject>Aluminum oxide</subject><subject>Butanol</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Ethanol</subject><subject>Fourier transforms</subject><subject>Hydrocarbons</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Mixtures</subject><subject>Organometallic Chemistry</subject><subject>Oxidation</subject><subject>Palladium</subject><subject>Physical Chemistry</subject><subject>Platinum</subject><subject>Reaction products</subject><subject>Surface reactions</subject><issn>1011-372X</issn><issn>1572-879X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><sourceid>C6C</sourceid><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp9UMtOwzAQtBBIlMIPcLLEOdSPJE6ObXgUqVIr6KE3y3EccJVHsV1KOfEP_CFfgpsgceO0s6uZ2d0B4BKja4wQG1mMopgEiOAAUcZwsDsCAxwxEiQsXR17jDAOKCOrU3Bm7RohlDKcDsDHU2s2TrcNFE0BH5WQXdOWcKLbWlgLb5TRb6qA0wxOKtUUtmMuX5Q2MGsb67TbqsZZePDwk7pWRmpRwYX7_vxaFKNxReYUzt91ITrvTDhR7a07ByelqKy6-K1DsLy7XWbTYDa_f8jGs0DSmLqAxjgPy7SkhEkcothfXpYyl6kIiaRhnhKUkzBXMkoYKRMPY-EfjyjFeSRjOgRXve3GtK9bZR1ft1vT-I2cxDFNCKVJ6FmkZ0nTWmtUyTdG18LsOUb8EDHvI-Y-Yt5FzHdeRHuR9eTmWZk_639UP1Bsf8g</recordid><startdate>20220601</startdate><enddate>20220601</enddate><creator>Schönberger, Ariel Augusto</creator><creator>Haselmann, Greta Marie</creator><creator>Wolkenar, Bernd</creator><creator>Schönebaum, Simon</creator><creator>Mauermann, Peter</creator><creator>Sterlepper, Stefan</creator><creator>Pischinger, Stefan</creator><creator>Simon, Ulrich</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>C6C</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><orcidid>https://orcid.org/0000-0002-0490-1178</orcidid></search><sort><creationdate>20220601</creationdate><title>Sorption and Reaction of Biomass Derived HC Blends and Their Constituents on a Commercial Pt–Pd/Al2O3 Oxidation Catalyst</title><author>Schönberger, Ariel Augusto ; Haselmann, Greta Marie ; Wolkenar, Bernd ; Schönebaum, Simon ; Mauermann, Peter ; Sterlepper, Stefan ; Pischinger, Stefan ; Simon, Ulrich</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c363t-361b4f9f327c1406009ffcbc9a42c34b920b24bec5872f824b6a5725331b5c63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Aluminum oxide</topic><topic>Butanol</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Ethanol</topic><topic>Fourier transforms</topic><topic>Hydrocarbons</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Mixtures</topic><topic>Organometallic Chemistry</topic><topic>Oxidation</topic><topic>Palladium</topic><topic>Physical Chemistry</topic><topic>Platinum</topic><topic>Reaction products</topic><topic>Surface reactions</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Schönberger, Ariel Augusto</creatorcontrib><creatorcontrib>Haselmann, Greta Marie</creatorcontrib><creatorcontrib>Wolkenar, Bernd</creatorcontrib><creatorcontrib>Schönebaum, Simon</creatorcontrib><creatorcontrib>Mauermann, Peter</creatorcontrib><creatorcontrib>Sterlepper, Stefan</creatorcontrib><creatorcontrib>Pischinger, Stefan</creatorcontrib><creatorcontrib>Simon, Ulrich</creatorcontrib><collection>Springer Nature OA/Free Journals</collection><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Catalysis letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Schönberger, Ariel Augusto</au><au>Haselmann, Greta Marie</au><au>Wolkenar, Bernd</au><au>Schönebaum, Simon</au><au>Mauermann, Peter</au><au>Sterlepper, Stefan</au><au>Pischinger, Stefan</au><au>Simon, Ulrich</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Sorption and Reaction of Biomass Derived HC Blends and Their Constituents on a Commercial Pt–Pd/Al2O3 Oxidation Catalyst</atitle><jtitle>Catalysis letters</jtitle><stitle>Catal Lett</stitle><date>2022-06-01</date><risdate>2022</risdate><volume>152</volume><issue>6</issue><spage>1880</spage><epage>1894</epage><pages>1880-1894</pages><issn>1011-372X</issn><eissn>1572-879X</eissn><abstract>Within the Research Cluster of Excellence “The Fuel Science Center” at RWTH Aachen University, the production and application of new fuels from bio-based carbon feedstocks and CO
2
with hydrogen from renewable electricity generation is being investigated. In this study, the storage and oxidation of ethanol, 1-butanol, 2-butanone, cyclopentanone, and cyclopentane as well as two blends thereof on a series production Pt–Pd/Al
2
O
3
oxidation catalyst were investigated. Hydrocarbon (HC) storage and temperature-programmed surface reaction (TPSR) experiments were carried out to analyze their adsorption and desorption behavior. In addition, the individual HCs and both blends were investigated using Diffuse Reflectance Infrared Fourier Transform Spectroscopy (TP-DRIFTS). In general, all oxygenated HCs are adsorbed more strongly than cyclopentane due to their higher polarity. Interestingly, it could be observed that the two different blends [blend 1: ethanol (50 mol %), 2-butanone (21 mol %), cyclopentanone (14 mol %) and cyclopentane (15 mol %); blend 2: 1-butanol (45 mol %), ethanol (29 mol %) and cyclopentane (27 mol %)] exhibit a different storage behavior compared to the single hydrocarbons. It was shown that the presence of 1-butanol and cyclopentane in blend 2 strongly inhibits the oxidation of ethanol. As a result, the ethanol light-off temperature was increased by at least 100 K. A difference was also found in the storage behavior of cyclopentane. While no significant storage could be detected in the pure compound experiment, the experiments with both mixtures showed a larger amount stored. The presence of adsorbed species of the hydrocarbons and their corresponding reaction products has been demonstrated and gives an insight into the storage mechanism of blends.
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| subjects | Aluminum oxide Butanol Catalysis Catalysts Chemistry Chemistry and Materials Science Ethanol Fourier transforms Hydrocarbons Industrial Chemistry/Chemical Engineering Mixtures Organometallic Chemistry Oxidation Palladium Physical Chemistry Platinum Reaction products Surface reactions |
| title | Sorption and Reaction of Biomass Derived HC Blends and Their Constituents on a Commercial Pt–Pd/Al2O3 Oxidation Catalyst |
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