Highly Efficient Zirconium Based Carbonaceous Solid Acid Catalyst for Selective Synthesis of 5-HMF from Fructose and Glucose in Isopropanol as a Solvent
A new zirconium based carbonaceous solid acid catalyst Zr@CC-PA with both Lewis and Bronsted acidic sites was prepared by simultaneous carbonization and phosphonation of glucose followed by incorporation of zirconium metal on the surface of the catalyst. The catalyst was easy to prepare and the synt...
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| Veröffentlicht in: | Catalysis letters 2022-06, Vol.152 (6), p.1703-1710 |
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| creator | Jori, Popat K. Jadhav, Vrushali H. |
| description | A new zirconium based carbonaceous solid acid catalyst Zr@CC-PA with both Lewis and Bronsted acidic sites was prepared by simultaneous carbonization and phosphonation of glucose followed by incorporation of zirconium metal on the surface of the catalyst. The catalyst was easy to prepare and the synthesized catalyst was well characterized using different techniques such as FT-IR, P-XRD, EDAX, SEM, TEM and XPS analysis. The catalytic activity was evaluated for synthesis of a very important platform chemical 5-HMF from fructose to glucose using isopropanol as a solvent. The catalyst was found to be highly efficient giving 86% yield of 5-HMF from fructose and 45% yield from glucose with high selectively. The catalyst can be reused at least four times without depreciation in its catalytic activity. The catalytic method developed is efficient, green and economical.
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| doi_str_mv | 10.1007/s10562-021-03764-9 |
| format | Article |
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Graphic abstract</description><subject>Analysis</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Catalytic activity</subject><subject>Chemical synthesis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Dextrose</subject><subject>Fructose</subject><subject>Glucose</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Isopropanol</subject><subject>Organometallic Chemistry</subject><subject>Physical Chemistry</subject><subject>Solvents</subject><subject>X ray photoelectron spectroscopy</subject><subject>Zirconium</subject><issn>1011-372X</issn><issn>1572-879X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp9UU1rGzEQXUIDTZP-gZ4EOSvVhyXtHl0Tx4GUHpxD6EVotSNHYVdyJW3A_6Q_t3JdCIVS5jDD8N7M472m-UTJDSVEfc6UCMkwYRQTruQCd2fNBRWK4VZ1T-_qTCjFXLGn982HnF8IIZ2i3UXzc-N3z-MB3TrnrYdQ0HefbAx-ntAXk2FAK5P6GIyFOGe0jaMf0NL6476Y8ZALcjGhLYxgi38FtD2E8gzZZxQdEnjzdY1cihNap9mWmAGZMKC7cbbH2Qd0n-M-xb0JcUQmI3N88Vp1XDXnzowZPv7pl83j-vZxtcEP3-7uV8sHbHkrC-5Nb7glwrUdb4E7IIMg0FMmlQNQoq8eOMP6wSnRWsGt7MRC9r0UjrHW8Mvm-nS2ivgxQy76Jc4p1I-aSclbxvlCvKF2ZgTtg4slGTv5bPVSVcOr-ZRW1M0_ULUGmHz1FJyv-78I7ESwKeacwOl98pNJB02JPuaqT7nqmqv-navuKomfSLmCww7Sm-L_sH4BKmqmJg</recordid><startdate>20220601</startdate><enddate>20220601</enddate><creator>Jori, Popat K.</creator><creator>Jadhav, Vrushali H.</creator><general>Springer US</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope></search><sort><creationdate>20220601</creationdate><title>Highly Efficient Zirconium Based Carbonaceous Solid Acid Catalyst for Selective Synthesis of 5-HMF from Fructose and Glucose in Isopropanol as a Solvent</title><author>Jori, Popat K. ; Jadhav, Vrushali H.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c386t-baba3c05f8938e3fe0d50eb1267fee75b572fa2bdf758c53c69546bb65f228a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Analysis</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Catalytic activity</topic><topic>Chemical synthesis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Dextrose</topic><topic>Fructose</topic><topic>Glucose</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Isopropanol</topic><topic>Organometallic Chemistry</topic><topic>Physical Chemistry</topic><topic>Solvents</topic><topic>X ray photoelectron spectroscopy</topic><topic>Zirconium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Jori, Popat K.</creatorcontrib><creatorcontrib>Jadhav, Vrushali H.</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central</collection><collection>SciTech Premium Collection</collection><collection>ProQuest Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Catalysis letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Jori, Popat K.</au><au>Jadhav, Vrushali H.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Highly Efficient Zirconium Based Carbonaceous Solid Acid Catalyst for Selective Synthesis of 5-HMF from Fructose and Glucose in Isopropanol as a Solvent</atitle><jtitle>Catalysis letters</jtitle><stitle>Catal Lett</stitle><date>2022-06-01</date><risdate>2022</risdate><volume>152</volume><issue>6</issue><spage>1703</spage><epage>1710</epage><pages>1703-1710</pages><issn>1011-372X</issn><eissn>1572-879X</eissn><abstract>A new zirconium based carbonaceous solid acid catalyst Zr@CC-PA with both Lewis and Bronsted acidic sites was prepared by simultaneous carbonization and phosphonation of glucose followed by incorporation of zirconium metal on the surface of the catalyst. The catalyst was easy to prepare and the synthesized catalyst was well characterized using different techniques such as FT-IR, P-XRD, EDAX, SEM, TEM and XPS analysis. The catalytic activity was evaluated for synthesis of a very important platform chemical 5-HMF from fructose to glucose using isopropanol as a solvent. The catalyst was found to be highly efficient giving 86% yield of 5-HMF from fructose and 45% yield from glucose with high selectively. The catalyst can be reused at least four times without depreciation in its catalytic activity. The catalytic method developed is efficient, green and economical.
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| ispartof | Catalysis letters, 2022-06, Vol.152 (6), p.1703-1710 |
| issn | 1011-372X 1572-879X |
| language | eng |
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| source | Springer Journals |
| subjects | Analysis Catalysis Catalysts Catalytic activity Chemical synthesis Chemistry Chemistry and Materials Science Dextrose Fructose Glucose Industrial Chemistry/Chemical Engineering Isopropanol Organometallic Chemistry Physical Chemistry Solvents X ray photoelectron spectroscopy Zirconium |
| title | Highly Efficient Zirconium Based Carbonaceous Solid Acid Catalyst for Selective Synthesis of 5-HMF from Fructose and Glucose in Isopropanol as a Solvent |
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