LFO Perovskites as Oxygen Carriers for Chemical Looping Oxygen Uncoupling (CLOU)

Alternative energy technologies at their current state cannot fully replace the existing fossil fuel-based energy production that has led to a rise in the atmospheric CO 2 concentration. CO 2 sequestration is a compelling solution to greatly reduce CO 2 emissions from sources like fossil fuel-based...

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Veröffentlicht in:Journal of thermal analysis and calorimetry 2022-06, Vol.147 (12), p.6605-6613
Hauptverfasser: Ahmad, Ali, Al Mamun, Md. Abdullah, Al-Mamun, Md, Huque, Saiful, Ismail, Mohammad
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container_end_page 6613
container_issue 12
container_start_page 6605
container_title Journal of thermal analysis and calorimetry
container_volume 147
creator Ahmad, Ali
Al Mamun, Md. Abdullah
Al-Mamun, Md
Huque, Saiful
Ismail, Mohammad
description Alternative energy technologies at their current state cannot fully replace the existing fossil fuel-based energy production that has led to a rise in the atmospheric CO 2 concentration. CO 2 sequestration is a compelling solution to greatly reduce CO 2 emissions from sources like fossil fuel-based power plants. Chemical-looping oxygen uncoupling process releases gaseous oxygen for combustion at high temperatures in the fuel reactor. The choice of oxygen carrier material (OCM) is pivotal to the chemical-looping process. In this study, citrate gel technique has been used to prepare the OCMs. A total of 5 (five) perovskites were prepared with varying degree of substitution of general formula La 0.6 A′ 0.4 B′ 1-y Fe y O 3 where y  = (0.8, 0.9) including the base LaFeO 3 . Calcined OCMs were characterized with XRD, SEM and BET analysis. OCMs showed an increase in surface area after oxygen release in a thermogravimetric experiment. Oxygen evolution rate ranged from 0.0043 to 0.0521 Kg O 2 /Kg OCM in a single cycle operation.
doi_str_mv 10.1007/s10973-021-10995-w
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ispartof Journal of thermal analysis and calorimetry, 2022-06, Vol.147 (12), p.6605-6613
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subjects Analytical Chemistry
Carbon dioxide
Carbon dioxide concentration
Carbon sequestration
Chemistry
Chemistry and Materials Science
Combustion
Energy minerals
Energy technology
Evolution
Fluidized bed combustion
Fossil fuels
High temperature
Hydrogen as fuel
Inorganic Chemistry
Measurement Science and Instrumentation
Nuclear fuels
Oxygen
Perovskites
Physical Chemistry
Polymer Sciences
Power plants
title LFO Perovskites as Oxygen Carriers for Chemical Looping Oxygen Uncoupling (CLOU)
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