LFO Perovskites as Oxygen Carriers for Chemical Looping Oxygen Uncoupling (CLOU)
Alternative energy technologies at their current state cannot fully replace the existing fossil fuel-based energy production that has led to a rise in the atmospheric CO 2 concentration. CO 2 sequestration is a compelling solution to greatly reduce CO 2 emissions from sources like fossil fuel-based...
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Veröffentlicht in: | Journal of thermal analysis and calorimetry 2022-06, Vol.147 (12), p.6605-6613 |
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creator | Ahmad, Ali Al Mamun, Md. Abdullah Al-Mamun, Md Huque, Saiful Ismail, Mohammad |
description | Alternative energy technologies at their current state cannot fully replace the existing fossil fuel-based energy production that has led to a rise in the atmospheric CO
2
concentration. CO
2
sequestration is a compelling solution to greatly reduce CO
2
emissions from sources like fossil fuel-based power plants. Chemical-looping oxygen uncoupling process releases gaseous oxygen for combustion at high temperatures in the fuel reactor. The choice of oxygen carrier material (OCM) is pivotal to the chemical-looping process. In this study, citrate gel technique has been used to prepare the OCMs. A total of 5 (five) perovskites were prepared with varying degree of substitution of general formula La
0.6
A′
0.4
B′
1-y
Fe
y
O
3
where
y
= (0.8, 0.9) including the base LaFeO
3
. Calcined OCMs were characterized with XRD, SEM and BET analysis. OCMs showed an increase in surface area after oxygen release in a thermogravimetric experiment. Oxygen evolution rate ranged from 0.0043 to 0.0521 Kg O
2
/Kg OCM in a single cycle operation. |
doi_str_mv | 10.1007/s10973-021-10995-w |
format | Article |
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2
concentration. CO
2
sequestration is a compelling solution to greatly reduce CO
2
emissions from sources like fossil fuel-based power plants. Chemical-looping oxygen uncoupling process releases gaseous oxygen for combustion at high temperatures in the fuel reactor. The choice of oxygen carrier material (OCM) is pivotal to the chemical-looping process. In this study, citrate gel technique has been used to prepare the OCMs. A total of 5 (five) perovskites were prepared with varying degree of substitution of general formula La
0.6
A′
0.4
B′
1-y
Fe
y
O
3
where
y
= (0.8, 0.9) including the base LaFeO
3
. Calcined OCMs were characterized with XRD, SEM and BET analysis. OCMs showed an increase in surface area after oxygen release in a thermogravimetric experiment. Oxygen evolution rate ranged from 0.0043 to 0.0521 Kg O
2
/Kg OCM in a single cycle operation.</description><identifier>ISSN: 1388-6150</identifier><identifier>EISSN: 1588-2926</identifier><identifier>DOI: 10.1007/s10973-021-10995-w</identifier><language>eng</language><publisher>Cham: Springer International Publishing</publisher><subject>Analytical Chemistry ; Carbon dioxide ; Carbon dioxide concentration ; Carbon sequestration ; Chemistry ; Chemistry and Materials Science ; Combustion ; Energy minerals ; Energy technology ; Evolution ; Fluidized bed combustion ; Fossil fuels ; High temperature ; Hydrogen as fuel ; Inorganic Chemistry ; Measurement Science and Instrumentation ; Nuclear fuels ; Oxygen ; Perovskites ; Physical Chemistry ; Polymer Sciences ; Power plants</subject><ispartof>Journal of thermal analysis and calorimetry, 2022-06, Vol.147 (12), p.6605-6613</ispartof><rights>Akadémiai Kiadó, Budapest, Hungary 2021</rights><rights>COPYRIGHT 2022 Springer</rights><rights>Akadémiai Kiadó, Budapest, Hungary 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c358t-c7851832056f4074f70f82e57de4ceeb1ec51deb399d040700bd0a63f5be56f43</citedby><cites>FETCH-LOGICAL-c358t-c7851832056f4074f70f82e57de4ceeb1ec51deb399d040700bd0a63f5be56f43</cites><orcidid>0000-0003-2330-1546</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10973-021-10995-w$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10973-021-10995-w$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Ahmad, Ali</creatorcontrib><creatorcontrib>Al Mamun, Md. Abdullah</creatorcontrib><creatorcontrib>Al-Mamun, Md</creatorcontrib><creatorcontrib>Huque, Saiful</creatorcontrib><creatorcontrib>Ismail, Mohammad</creatorcontrib><title>LFO Perovskites as Oxygen Carriers for Chemical Looping Oxygen Uncoupling (CLOU)</title><title>Journal of thermal analysis and calorimetry</title><addtitle>J Therm Anal Calorim</addtitle><description>Alternative energy technologies at their current state cannot fully replace the existing fossil fuel-based energy production that has led to a rise in the atmospheric CO
2
concentration. CO
2
sequestration is a compelling solution to greatly reduce CO
2
emissions from sources like fossil fuel-based power plants. Chemical-looping oxygen uncoupling process releases gaseous oxygen for combustion at high temperatures in the fuel reactor. The choice of oxygen carrier material (OCM) is pivotal to the chemical-looping process. In this study, citrate gel technique has been used to prepare the OCMs. A total of 5 (five) perovskites were prepared with varying degree of substitution of general formula La
0.6
A′
0.4
B′
1-y
Fe
y
O
3
where
y
= (0.8, 0.9) including the base LaFeO
3
. Calcined OCMs were characterized with XRD, SEM and BET analysis. OCMs showed an increase in surface area after oxygen release in a thermogravimetric experiment. Oxygen evolution rate ranged from 0.0043 to 0.0521 Kg O
2
/Kg OCM in a single cycle operation.</description><subject>Analytical Chemistry</subject><subject>Carbon dioxide</subject><subject>Carbon dioxide concentration</subject><subject>Carbon sequestration</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Combustion</subject><subject>Energy minerals</subject><subject>Energy technology</subject><subject>Evolution</subject><subject>Fluidized bed combustion</subject><subject>Fossil fuels</subject><subject>High temperature</subject><subject>Hydrogen as fuel</subject><subject>Inorganic Chemistry</subject><subject>Measurement Science and Instrumentation</subject><subject>Nuclear fuels</subject><subject>Oxygen</subject><subject>Perovskites</subject><subject>Physical Chemistry</subject><subject>Polymer Sciences</subject><subject>Power plants</subject><issn>1388-6150</issn><issn>1588-2926</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp9kM9PgzAYhonRxDn9BzyReNED8yulQI8LcWpCwg7u3PDjKzIZxZY5999bROPN9NA3X56nP17HuSawIADRvSHAI-qBTzybOPMOJ86MsDj2fO6HpzZTm0PC4Ny5MGYLYCkgM2edrjJ3jVp9mLdmQOPmxs0-jzV2bpJr3aA2rlTaTV5x15R566ZK9U1X_0KbrlT7vh0nt0mabe4unTOZtwavfva5s1k9vCRPXpo9PifL1CspiwevjGJGYuoDC2UAUSAjkLGPLKowKBELgiUjFRaU8wosAFBUkIdUsgJHhc6dm-ncXqv3PZpBbNVed_ZK4Ych4ZwHAJZaTFSdtyiaTqpB56Vd1fgd1aFs7HwZAfVpSPko-JNQamWMRil63exyfRQExFi1mKoWtmrxXbU4WIlOkrFwV6P-e8s_1henYIBF</recordid><startdate>20220601</startdate><enddate>20220601</enddate><creator>Ahmad, Ali</creator><creator>Al Mamun, Md. Abdullah</creator><creator>Al-Mamun, Md</creator><creator>Huque, Saiful</creator><creator>Ismail, Mohammad</creator><general>Springer International Publishing</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0003-2330-1546</orcidid></search><sort><creationdate>20220601</creationdate><title>LFO Perovskites as Oxygen Carriers for Chemical Looping Oxygen Uncoupling (CLOU)</title><author>Ahmad, Ali ; Al Mamun, Md. Abdullah ; Al-Mamun, Md ; Huque, Saiful ; Ismail, Mohammad</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c358t-c7851832056f4074f70f82e57de4ceeb1ec51deb399d040700bd0a63f5be56f43</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Analytical Chemistry</topic><topic>Carbon dioxide</topic><topic>Carbon dioxide concentration</topic><topic>Carbon sequestration</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Combustion</topic><topic>Energy minerals</topic><topic>Energy technology</topic><topic>Evolution</topic><topic>Fluidized bed combustion</topic><topic>Fossil fuels</topic><topic>High temperature</topic><topic>Hydrogen as fuel</topic><topic>Inorganic Chemistry</topic><topic>Measurement Science and Instrumentation</topic><topic>Nuclear fuels</topic><topic>Oxygen</topic><topic>Perovskites</topic><topic>Physical Chemistry</topic><topic>Polymer Sciences</topic><topic>Power plants</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ahmad, Ali</creatorcontrib><creatorcontrib>Al Mamun, Md. Abdullah</creatorcontrib><creatorcontrib>Al-Mamun, Md</creatorcontrib><creatorcontrib>Huque, Saiful</creatorcontrib><creatorcontrib>Ismail, Mohammad</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of thermal analysis and calorimetry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ahmad, Ali</au><au>Al Mamun, Md. Abdullah</au><au>Al-Mamun, Md</au><au>Huque, Saiful</au><au>Ismail, Mohammad</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>LFO Perovskites as Oxygen Carriers for Chemical Looping Oxygen Uncoupling (CLOU)</atitle><jtitle>Journal of thermal analysis and calorimetry</jtitle><stitle>J Therm Anal Calorim</stitle><date>2022-06-01</date><risdate>2022</risdate><volume>147</volume><issue>12</issue><spage>6605</spage><epage>6613</epage><pages>6605-6613</pages><issn>1388-6150</issn><eissn>1588-2926</eissn><abstract>Alternative energy technologies at their current state cannot fully replace the existing fossil fuel-based energy production that has led to a rise in the atmospheric CO
2
concentration. CO
2
sequestration is a compelling solution to greatly reduce CO
2
emissions from sources like fossil fuel-based power plants. Chemical-looping oxygen uncoupling process releases gaseous oxygen for combustion at high temperatures in the fuel reactor. The choice of oxygen carrier material (OCM) is pivotal to the chemical-looping process. In this study, citrate gel technique has been used to prepare the OCMs. A total of 5 (five) perovskites were prepared with varying degree of substitution of general formula La
0.6
A′
0.4
B′
1-y
Fe
y
O
3
where
y
= (0.8, 0.9) including the base LaFeO
3
. Calcined OCMs were characterized with XRD, SEM and BET analysis. OCMs showed an increase in surface area after oxygen release in a thermogravimetric experiment. Oxygen evolution rate ranged from 0.0043 to 0.0521 Kg O
2
/Kg OCM in a single cycle operation.</abstract><cop>Cham</cop><pub>Springer International Publishing</pub><doi>10.1007/s10973-021-10995-w</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0003-2330-1546</orcidid></addata></record> |
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issn | 1388-6150 1588-2926 |
language | eng |
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source | SpringerNature Journals |
subjects | Analytical Chemistry Carbon dioxide Carbon dioxide concentration Carbon sequestration Chemistry Chemistry and Materials Science Combustion Energy minerals Energy technology Evolution Fluidized bed combustion Fossil fuels High temperature Hydrogen as fuel Inorganic Chemistry Measurement Science and Instrumentation Nuclear fuels Oxygen Perovskites Physical Chemistry Polymer Sciences Power plants |
title | LFO Perovskites as Oxygen Carriers for Chemical Looping Oxygen Uncoupling (CLOU) |
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