Geochemical and stable isotope (δ13C & δ18O) signatures of Calcrete in and around Pandalgudi, Southern Tamilnadu, India and its implications on Palaeoclimate
Calcrete is an authigenic impure regolith carbonate deposit. It occurs as widespread deposits, which rest over the Proterozoic metamorphic basement rocks of the Pandalgudi region, Viruthunagar district of Tamilnadu, India. They occur as gravel, nodular, lumpy, chalky, and laminated or layered forms....
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description | Calcrete is an authigenic impure regolith carbonate deposit. It occurs as widespread deposits, which rest over the Proterozoic metamorphic basement rocks of the Pandalgudi region, Viruthunagar district of Tamilnadu, India. They occur as gravel, nodular, lumpy, chalky, and laminated or layered forms. Petro-mineralogical observation reveals micritic and microsparitic calcite precipitation around the detrital quartz and feldspar minerals, displacive and replacive structure in hornblende, hypersthene, and biotic minerals, veining, void lining, and lensoidal precipitation in the clay matrix. The X-ray diffraction analysis reveals the presence of clay minerals of montmorillonite, palygorskite, sepiolite, illite, chlorite, smectite, and kaolin. A major element geochemical analysis of calcrete samples indicates the predominant composition of CaO, MgO, SiO
2
, Al
2
O
3
, and Fe
2
O
3
against MnO, Na
2
O, K
2
O, TiO
2
, and P
2
O
5
. Geostatistical evaluation of major element geochemistry of calcrete through the methods of multiple correlations, principal component analysis (PCA), and cluster analysis illustrates the interrelationship and affinity among the major oxides. Depth-wise distribution trend analysis of stable isotopes of carbon δ
13
C and oxygen δ
18
O of calcrete profiles represents the meteoric diagenetic environment of freshwater carbonate sources. Proxies of major element geochemistry, clay mineralogy, and stable isotope signature of calcrete deposits illustrate arid and semiarid climates. |
doi_str_mv | 10.1007/s12517-022-10134-1 |
format | Article |
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2
, Al
2
O
3
, and Fe
2
O
3
against MnO, Na
2
O, K
2
O, TiO
2
, and P
2
O
5
. Geostatistical evaluation of major element geochemistry of calcrete through the methods of multiple correlations, principal component analysis (PCA), and cluster analysis illustrates the interrelationship and affinity among the major oxides. Depth-wise distribution trend analysis of stable isotopes of carbon δ
13
C and oxygen δ
18
O of calcrete profiles represents the meteoric diagenetic environment of freshwater carbonate sources. Proxies of major element geochemistry, clay mineralogy, and stable isotope signature of calcrete deposits illustrate arid and semiarid climates.</description><identifier>ISSN: 1866-7511</identifier><identifier>EISSN: 1866-7538</identifier><identifier>DOI: 10.1007/s12517-022-10134-1</identifier><language>eng</language><publisher>Cham: Springer International Publishing</publisher><subject>Aluminum oxide ; Aridity ; Basement rock ; Calcite ; Calcrete ; Carbonates ; Chemical precipitation ; Chlorite ; Clay ; Clay minerals ; Climate ; Cluster analysis ; Diagenesis ; Earth and Environmental Science ; Earth science ; Earth Sciences ; Feldspars ; Ferric oxide ; Freshwater ; Geochemistry ; Gravel ; Illite ; Illites ; Inland water environment ; Isotopes ; Kaolin ; Mineralogy ; Minerals ; Montmorillonite ; Montmorillonites ; Original Paper ; Oxides ; Palaeoclimate ; Paleoclimate ; Palygorskite ; Phosphorus pentoxide ; Precambrian ; Preferred orientation ; Principal components analysis ; Regolith ; Semiarid climates ; Sepiolite ; Silica ; Silicon dioxide ; Smectites ; Stable isotopes ; Titanium dioxide ; Trend analysis ; X-ray diffraction</subject><ispartof>Arabian journal of geosciences, 2022, Vol.15 (9), Article 913</ispartof><rights>Saudi Society for Geosciences 2022</rights><rights>Saudi Society for Geosciences 2022.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c1151-372d17e0df353eea37c7683be18264c9e2a2022fc926e7fc25e50980eafee8d33</cites><orcidid>0000-0002-5744-0870 ; 0000-0002-9821-8184 ; 0000-0002-7569-4997 ; 0000-0003-3910-5195 ; 0000-0001-7584-0600</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s12517-022-10134-1$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s12517-022-10134-1$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Venu, Udayanapillai Alagaiah</creatorcontrib><creatorcontrib>Velmayil, Perumal</creatorcontrib><creatorcontrib>Armstrong-Altrin, John Selvamony</creatorcontrib><creatorcontrib>Sial, Alcides</creatorcontrib><creatorcontrib>Manavalan, Satyanarayanan</creatorcontrib><title>Geochemical and stable isotope (δ13C & δ18O) signatures of Calcrete in and around Pandalgudi, Southern Tamilnadu, India and its implications on Palaeoclimate</title><title>Arabian journal of geosciences</title><addtitle>Arab J Geosci</addtitle><description>Calcrete is an authigenic impure regolith carbonate deposit. It occurs as widespread deposits, which rest over the Proterozoic metamorphic basement rocks of the Pandalgudi region, Viruthunagar district of Tamilnadu, India. They occur as gravel, nodular, lumpy, chalky, and laminated or layered forms. Petro-mineralogical observation reveals micritic and microsparitic calcite precipitation around the detrital quartz and feldspar minerals, displacive and replacive structure in hornblende, hypersthene, and biotic minerals, veining, void lining, and lensoidal precipitation in the clay matrix. The X-ray diffraction analysis reveals the presence of clay minerals of montmorillonite, palygorskite, sepiolite, illite, chlorite, smectite, and kaolin. A major element geochemical analysis of calcrete samples indicates the predominant composition of CaO, MgO, SiO
2
, Al
2
O
3
, and Fe
2
O
3
against MnO, Na
2
O, K
2
O, TiO
2
, and P
2
O
5
. Geostatistical evaluation of major element geochemistry of calcrete through the methods of multiple correlations, principal component analysis (PCA), and cluster analysis illustrates the interrelationship and affinity among the major oxides. Depth-wise distribution trend analysis of stable isotopes of carbon δ
13
C and oxygen δ
18
O of calcrete profiles represents the meteoric diagenetic environment of freshwater carbonate sources. Proxies of major element geochemistry, clay mineralogy, and stable isotope signature of calcrete deposits illustrate arid and semiarid climates.</description><subject>Aluminum oxide</subject><subject>Aridity</subject><subject>Basement rock</subject><subject>Calcite</subject><subject>Calcrete</subject><subject>Carbonates</subject><subject>Chemical precipitation</subject><subject>Chlorite</subject><subject>Clay</subject><subject>Clay minerals</subject><subject>Climate</subject><subject>Cluster analysis</subject><subject>Diagenesis</subject><subject>Earth and Environmental Science</subject><subject>Earth science</subject><subject>Earth Sciences</subject><subject>Feldspars</subject><subject>Ferric oxide</subject><subject>Freshwater</subject><subject>Geochemistry</subject><subject>Gravel</subject><subject>Illite</subject><subject>Illites</subject><subject>Inland water environment</subject><subject>Isotopes</subject><subject>Kaolin</subject><subject>Mineralogy</subject><subject>Minerals</subject><subject>Montmorillonite</subject><subject>Montmorillonites</subject><subject>Original Paper</subject><subject>Oxides</subject><subject>Palaeoclimate</subject><subject>Paleoclimate</subject><subject>Palygorskite</subject><subject>Phosphorus pentoxide</subject><subject>Precambrian</subject><subject>Preferred orientation</subject><subject>Principal components analysis</subject><subject>Regolith</subject><subject>Semiarid climates</subject><subject>Sepiolite</subject><subject>Silica</subject><subject>Silicon dioxide</subject><subject>Smectites</subject><subject>Stable isotopes</subject><subject>Titanium dioxide</subject><subject>Trend analysis</subject><subject>X-ray diffraction</subject><issn>1866-7511</issn><issn>1866-7538</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp9kcFqGzEQhpfSQt20L9CToFASyKYaKSvJx2Aax2BIIOlZyNpZR0aWHEl76NP0JfIceaYodmhuOf1z-L__H2aa5jvQM6BU_srAOpAtZawFCvy8hQ_NBJQQrey4-vh_BvjcfMl5Q6lQVKpJ82-O0d7j1lnjiQk9ycWsPBKXY4k7JMdPj8Bn5Cepqq5PSHbrYMqYMJM4kJnxNmGp9rCHTYpjlZs6G78ee3dKbuNY7jEFcme2zgfTj6dkEXpn9oArmbjtztf64mKooaHS3tSlvNuagl-bT4PxGb-96lHz5_L33eyqXV7PF7OLZWsBOmi5ZD1IpP3AO45ouLRSKL5CUEyc2ykyw-pxBjtlAuVgWYcdnSqKZkBUPedHzY9D7i7FhxFz0Zs4plArNRNdpZSQorrYwWVTzDnhoHeprpn-aqD65RH68Ahdu_T-ERoqxA9QruawxvQW_Q71DOytjUA</recordid><startdate>2022</startdate><enddate>2022</enddate><creator>Venu, Udayanapillai Alagaiah</creator><creator>Velmayil, Perumal</creator><creator>Armstrong-Altrin, John Selvamony</creator><creator>Sial, Alcides</creator><creator>Manavalan, Satyanarayanan</creator><general>Springer International Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7UA</scope><scope>C1K</scope><scope>F1W</scope><scope>H96</scope><scope>L.G</scope><orcidid>https://orcid.org/0000-0002-5744-0870</orcidid><orcidid>https://orcid.org/0000-0002-9821-8184</orcidid><orcidid>https://orcid.org/0000-0002-7569-4997</orcidid><orcidid>https://orcid.org/0000-0003-3910-5195</orcidid><orcidid>https://orcid.org/0000-0001-7584-0600</orcidid></search><sort><creationdate>2022</creationdate><title>Geochemical and stable isotope (δ13C & δ18O) signatures of Calcrete in and around Pandalgudi, Southern Tamilnadu, India and its implications on Palaeoclimate</title><author>Venu, Udayanapillai Alagaiah ; Velmayil, Perumal ; Armstrong-Altrin, John Selvamony ; Sial, Alcides ; Manavalan, Satyanarayanan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1151-372d17e0df353eea37c7683be18264c9e2a2022fc926e7fc25e50980eafee8d33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Aluminum oxide</topic><topic>Aridity</topic><topic>Basement rock</topic><topic>Calcite</topic><topic>Calcrete</topic><topic>Carbonates</topic><topic>Chemical precipitation</topic><topic>Chlorite</topic><topic>Clay</topic><topic>Clay minerals</topic><topic>Climate</topic><topic>Cluster analysis</topic><topic>Diagenesis</topic><topic>Earth and Environmental Science</topic><topic>Earth science</topic><topic>Earth Sciences</topic><topic>Feldspars</topic><topic>Ferric oxide</topic><topic>Freshwater</topic><topic>Geochemistry</topic><topic>Gravel</topic><topic>Illite</topic><topic>Illites</topic><topic>Inland water environment</topic><topic>Isotopes</topic><topic>Kaolin</topic><topic>Mineralogy</topic><topic>Minerals</topic><topic>Montmorillonite</topic><topic>Montmorillonites</topic><topic>Original Paper</topic><topic>Oxides</topic><topic>Palaeoclimate</topic><topic>Paleoclimate</topic><topic>Palygorskite</topic><topic>Phosphorus pentoxide</topic><topic>Precambrian</topic><topic>Preferred orientation</topic><topic>Principal components analysis</topic><topic>Regolith</topic><topic>Semiarid climates</topic><topic>Sepiolite</topic><topic>Silica</topic><topic>Silicon dioxide</topic><topic>Smectites</topic><topic>Stable isotopes</topic><topic>Titanium dioxide</topic><topic>Trend analysis</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Venu, Udayanapillai Alagaiah</creatorcontrib><creatorcontrib>Velmayil, Perumal</creatorcontrib><creatorcontrib>Armstrong-Altrin, John Selvamony</creatorcontrib><creatorcontrib>Sial, Alcides</creatorcontrib><creatorcontrib>Manavalan, Satyanarayanan</creatorcontrib><collection>CrossRef</collection><collection>Water Resources Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ASFA: Aquatic Sciences and Fisheries Abstracts</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) 2: Ocean Technology, Policy & Non-Living Resources</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) Professional</collection><jtitle>Arabian journal of geosciences</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Venu, Udayanapillai Alagaiah</au><au>Velmayil, Perumal</au><au>Armstrong-Altrin, John Selvamony</au><au>Sial, Alcides</au><au>Manavalan, Satyanarayanan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Geochemical and stable isotope (δ13C & δ18O) signatures of Calcrete in and around Pandalgudi, Southern Tamilnadu, India and its implications on Palaeoclimate</atitle><jtitle>Arabian journal of geosciences</jtitle><stitle>Arab J Geosci</stitle><date>2022</date><risdate>2022</risdate><volume>15</volume><issue>9</issue><artnum>913</artnum><issn>1866-7511</issn><eissn>1866-7538</eissn><abstract>Calcrete is an authigenic impure regolith carbonate deposit. It occurs as widespread deposits, which rest over the Proterozoic metamorphic basement rocks of the Pandalgudi region, Viruthunagar district of Tamilnadu, India. They occur as gravel, nodular, lumpy, chalky, and laminated or layered forms. Petro-mineralogical observation reveals micritic and microsparitic calcite precipitation around the detrital quartz and feldspar minerals, displacive and replacive structure in hornblende, hypersthene, and biotic minerals, veining, void lining, and lensoidal precipitation in the clay matrix. The X-ray diffraction analysis reveals the presence of clay minerals of montmorillonite, palygorskite, sepiolite, illite, chlorite, smectite, and kaolin. A major element geochemical analysis of calcrete samples indicates the predominant composition of CaO, MgO, SiO
2
, Al
2
O
3
, and Fe
2
O
3
against MnO, Na
2
O, K
2
O, TiO
2
, and P
2
O
5
. Geostatistical evaluation of major element geochemistry of calcrete through the methods of multiple correlations, principal component analysis (PCA), and cluster analysis illustrates the interrelationship and affinity among the major oxides. Depth-wise distribution trend analysis of stable isotopes of carbon δ
13
C and oxygen δ
18
O of calcrete profiles represents the meteoric diagenetic environment of freshwater carbonate sources. Proxies of major element geochemistry, clay mineralogy, and stable isotope signature of calcrete deposits illustrate arid and semiarid climates.</abstract><cop>Cham</cop><pub>Springer International Publishing</pub><doi>10.1007/s12517-022-10134-1</doi><orcidid>https://orcid.org/0000-0002-5744-0870</orcidid><orcidid>https://orcid.org/0000-0002-9821-8184</orcidid><orcidid>https://orcid.org/0000-0002-7569-4997</orcidid><orcidid>https://orcid.org/0000-0003-3910-5195</orcidid><orcidid>https://orcid.org/0000-0001-7584-0600</orcidid></addata></record> |
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source | SpringerLink Journals - AutoHoldings |
subjects | Aluminum oxide Aridity Basement rock Calcite Calcrete Carbonates Chemical precipitation Chlorite Clay Clay minerals Climate Cluster analysis Diagenesis Earth and Environmental Science Earth science Earth Sciences Feldspars Ferric oxide Freshwater Geochemistry Gravel Illite Illites Inland water environment Isotopes Kaolin Mineralogy Minerals Montmorillonite Montmorillonites Original Paper Oxides Palaeoclimate Paleoclimate Palygorskite Phosphorus pentoxide Precambrian Preferred orientation Principal components analysis Regolith Semiarid climates Sepiolite Silica Silicon dioxide Smectites Stable isotopes Titanium dioxide Trend analysis X-ray diffraction |
title | Geochemical and stable isotope (δ13C & δ18O) signatures of Calcrete in and around Pandalgudi, Southern Tamilnadu, India and its implications on Palaeoclimate |
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