The dark side of social media: Two deaths related with chloroform intoxication
A suicide pact is an agreement between people to commit suicide together, which usually takes place at the same time, in the same place, by using the same method. Social media serve as a way of communication between people. Thus, they use such platforms to find potential suicide pact partners. Chlor...
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Veröffentlicht in: | Journal of forensic sciences 2022-05, Vol.67 (3), p.1300-1307 |
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creator | Tusiewicz, Kaja Wachełko, Olga Zawadzki, Marcin Chłopaś‐Konowałek, Agnieszka Jurek, Tomasz Kawecki, Jerzy Szpot, Paweł |
description | A suicide pact is an agreement between people to commit suicide together, which usually takes place at the same time, in the same place, by using the same method. Social media serve as a way of communication between people. Thus, they use such platforms to find potential suicide pact partners. Chloroform, although being regarded to as a slightly forgotten poison, is still linked to homicide and suicide cases. Death due to an acute chloroform ingestion may be a result of central nervous system depression. In this paper, we present application of headspace gas chromatographic method using a dual column/dual flame ionization detector (HS‐GC‐FID/FID) for the determination of chloroform in two fatal intoxication cases, as well as chloroform stability study. Analysis of biological samples revealed chloroform concentrations of 135.8, 16.1, 8.1, and 37.1 µg/ml in blood, urine, vitreous humor, and bile, respectively. Kidney, liver, and muscle specimens contained 119.5, 99.6, and 28.4 µg/g of chloroform, respectively. The results of stability studies indicate the highest decrease of chloroform in room temperature, so it is advised to store samples in a freezer. The addition of sodium fluoride is recommended as in blood samples collected to the test tubes without any preservative agent, the detection of chloroform after 91 days is almost impossible. It is important to emphasize that even old poisons can cause a lot of concerns today, as here described cases are linked to chloroform intoxication, as well as with possible danger which social media bring about nowadays. |
doi_str_mv | 10.1111/1556-4029.14974 |
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Social media serve as a way of communication between people. Thus, they use such platforms to find potential suicide pact partners. Chloroform, although being regarded to as a slightly forgotten poison, is still linked to homicide and suicide cases. Death due to an acute chloroform ingestion may be a result of central nervous system depression. In this paper, we present application of headspace gas chromatographic method using a dual column/dual flame ionization detector (HS‐GC‐FID/FID) for the determination of chloroform in two fatal intoxication cases, as well as chloroform stability study. Analysis of biological samples revealed chloroform concentrations of 135.8, 16.1, 8.1, and 37.1 µg/ml in blood, urine, vitreous humor, and bile, respectively. Kidney, liver, and muscle specimens contained 119.5, 99.6, and 28.4 µg/g of chloroform, respectively. The results of stability studies indicate the highest decrease of chloroform in room temperature, so it is advised to store samples in a freezer. The addition of sodium fluoride is recommended as in blood samples collected to the test tubes without any preservative agent, the detection of chloroform after 91 days is almost impossible. It is important to emphasize that even old poisons can cause a lot of concerns today, as here described cases are linked to chloroform intoxication, as well as with possible danger which social media bring about nowadays.</description><identifier>ISSN: 0022-1198</identifier><identifier>EISSN: 1556-4029</identifier><identifier>DOI: 10.1111/1556-4029.14974</identifier><identifier>PMID: 34994396</identifier><language>eng</language><publisher>United States: Wiley Subscription Services, Inc</publisher><subject>Biological properties ; Blood ; Central nervous system ; Chloroform ; Chloroform - analysis ; chloroform intoxication ; chloroform stability ; Chromatography, Gas - methods ; cybersuicide ; Digital media ; fatal intoxication ; Flame Ionization ; Flame ionization detectors ; Gas chromatography ; Homicide ; HS‐GC‐FID/FID ; Humans ; Ingestion ; Intoxication ; Muscles ; Poisons ; Preservatives ; Room temperature ; Social Media ; Social networks ; Sodium fluoride ; Stability analysis ; suicide pact ; Suicides & suicide attempts ; Tubes ; Vitreous humour</subject><ispartof>Journal of forensic sciences, 2022-05, Vol.67 (3), p.1300-1307</ispartof><rights>2022 American Academy of Forensic Sciences.</rights><rights>2022 American Academy of Forensic Sciences</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3384-ab40563732a20f1ff47de794ed8a6a9942d4995ec693eb354d72301f83e167b53</citedby><cites>FETCH-LOGICAL-c3384-ab40563732a20f1ff47de794ed8a6a9942d4995ec693eb354d72301f83e167b53</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1111%2F1556-4029.14974$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1111%2F1556-4029.14974$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/34994396$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Tusiewicz, Kaja</creatorcontrib><creatorcontrib>Wachełko, Olga</creatorcontrib><creatorcontrib>Zawadzki, Marcin</creatorcontrib><creatorcontrib>Chłopaś‐Konowałek, Agnieszka</creatorcontrib><creatorcontrib>Jurek, Tomasz</creatorcontrib><creatorcontrib>Kawecki, Jerzy</creatorcontrib><creatorcontrib>Szpot, Paweł</creatorcontrib><title>The dark side of social media: Two deaths related with chloroform intoxication</title><title>Journal of forensic sciences</title><addtitle>J Forensic Sci</addtitle><description>A suicide pact is an agreement between people to commit suicide together, which usually takes place at the same time, in the same place, by using the same method. Social media serve as a way of communication between people. Thus, they use such platforms to find potential suicide pact partners. Chloroform, although being regarded to as a slightly forgotten poison, is still linked to homicide and suicide cases. Death due to an acute chloroform ingestion may be a result of central nervous system depression. In this paper, we present application of headspace gas chromatographic method using a dual column/dual flame ionization detector (HS‐GC‐FID/FID) for the determination of chloroform in two fatal intoxication cases, as well as chloroform stability study. Analysis of biological samples revealed chloroform concentrations of 135.8, 16.1, 8.1, and 37.1 µg/ml in blood, urine, vitreous humor, and bile, respectively. Kidney, liver, and muscle specimens contained 119.5, 99.6, and 28.4 µg/g of chloroform, respectively. The results of stability studies indicate the highest decrease of chloroform in room temperature, so it is advised to store samples in a freezer. The addition of sodium fluoride is recommended as in blood samples collected to the test tubes without any preservative agent, the detection of chloroform after 91 days is almost impossible. It is important to emphasize that even old poisons can cause a lot of concerns today, as here described cases are linked to chloroform intoxication, as well as with possible danger which social media bring about nowadays.</description><subject>Biological properties</subject><subject>Blood</subject><subject>Central nervous system</subject><subject>Chloroform</subject><subject>Chloroform - analysis</subject><subject>chloroform intoxication</subject><subject>chloroform stability</subject><subject>Chromatography, Gas - methods</subject><subject>cybersuicide</subject><subject>Digital media</subject><subject>fatal intoxication</subject><subject>Flame Ionization</subject><subject>Flame ionization detectors</subject><subject>Gas chromatography</subject><subject>Homicide</subject><subject>HS‐GC‐FID/FID</subject><subject>Humans</subject><subject>Ingestion</subject><subject>Intoxication</subject><subject>Muscles</subject><subject>Poisons</subject><subject>Preservatives</subject><subject>Room temperature</subject><subject>Social Media</subject><subject>Social networks</subject><subject>Sodium fluoride</subject><subject>Stability analysis</subject><subject>suicide pact</subject><subject>Suicides & suicide attempts</subject><subject>Tubes</subject><subject>Vitreous humour</subject><issn>0022-1198</issn><issn>1556-4029</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkD1PwzAQhi0EoqUwsyFLzGn9nZgNVZQPVXQps-XEjuKS1sVOVfrvSUjpyi0nnZ577_QAcIvRGLc1wZyLhCEix5jJlJ2B4WlyDoYIEZJgLLMBuIpxhRASWOBLMKBMSkalGIL3ZWWh0eETRmcs9CWMvnC6hmtrnH6Ay72HxuqmijDYWjfWwL1rKlhUtQ--9GEN3abx367QjfOba3BR6jram2MfgY_Z03L6kswXz6_Tx3lSUJqxROcMcUFTSjRBJS5LlhqbSmZNpoVufyOm_ZDbQkhqc8qZSQlFuMyoxSLNOR2B-z53G_zXzsZGrfwubNqTigieCoIz0VGTniqCjzHYUm2DW-twUBipzp_qbKnOlvr1127cHXN3eWvgxP8JawHeA3tX28N_eepttuiDfwD_gnid</recordid><startdate>202205</startdate><enddate>202205</enddate><creator>Tusiewicz, Kaja</creator><creator>Wachełko, Olga</creator><creator>Zawadzki, Marcin</creator><creator>Chłopaś‐Konowałek, Agnieszka</creator><creator>Jurek, Tomasz</creator><creator>Kawecki, Jerzy</creator><creator>Szpot, Paweł</creator><general>Wiley Subscription Services, Inc</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>K7.</scope></search><sort><creationdate>202205</creationdate><title>The dark side of social media: Two deaths related with chloroform intoxication</title><author>Tusiewicz, Kaja ; Wachełko, Olga ; Zawadzki, Marcin ; Chłopaś‐Konowałek, Agnieszka ; Jurek, Tomasz ; Kawecki, Jerzy ; Szpot, Paweł</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3384-ab40563732a20f1ff47de794ed8a6a9942d4995ec693eb354d72301f83e167b53</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Biological properties</topic><topic>Blood</topic><topic>Central nervous system</topic><topic>Chloroform</topic><topic>Chloroform - analysis</topic><topic>chloroform intoxication</topic><topic>chloroform stability</topic><topic>Chromatography, Gas - methods</topic><topic>cybersuicide</topic><topic>Digital media</topic><topic>fatal intoxication</topic><topic>Flame Ionization</topic><topic>Flame ionization detectors</topic><topic>Gas chromatography</topic><topic>Homicide</topic><topic>HS‐GC‐FID/FID</topic><topic>Humans</topic><topic>Ingestion</topic><topic>Intoxication</topic><topic>Muscles</topic><topic>Poisons</topic><topic>Preservatives</topic><topic>Room temperature</topic><topic>Social Media</topic><topic>Social networks</topic><topic>Sodium fluoride</topic><topic>Stability analysis</topic><topic>suicide pact</topic><topic>Suicides & suicide attempts</topic><topic>Tubes</topic><topic>Vitreous humour</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Tusiewicz, Kaja</creatorcontrib><creatorcontrib>Wachełko, Olga</creatorcontrib><creatorcontrib>Zawadzki, Marcin</creatorcontrib><creatorcontrib>Chłopaś‐Konowałek, Agnieszka</creatorcontrib><creatorcontrib>Jurek, Tomasz</creatorcontrib><creatorcontrib>Kawecki, Jerzy</creatorcontrib><creatorcontrib>Szpot, Paweł</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>ProQuest Criminal Justice (Alumni)</collection><jtitle>Journal of forensic sciences</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Tusiewicz, Kaja</au><au>Wachełko, Olga</au><au>Zawadzki, Marcin</au><au>Chłopaś‐Konowałek, Agnieszka</au><au>Jurek, Tomasz</au><au>Kawecki, Jerzy</au><au>Szpot, Paweł</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The dark side of social media: Two deaths related with chloroform intoxication</atitle><jtitle>Journal of forensic sciences</jtitle><addtitle>J Forensic Sci</addtitle><date>2022-05</date><risdate>2022</risdate><volume>67</volume><issue>3</issue><spage>1300</spage><epage>1307</epage><pages>1300-1307</pages><issn>0022-1198</issn><eissn>1556-4029</eissn><abstract>A suicide pact is an agreement between people to commit suicide together, which usually takes place at the same time, in the same place, by using the same method. Social media serve as a way of communication between people. Thus, they use such platforms to find potential suicide pact partners. Chloroform, although being regarded to as a slightly forgotten poison, is still linked to homicide and suicide cases. Death due to an acute chloroform ingestion may be a result of central nervous system depression. In this paper, we present application of headspace gas chromatographic method using a dual column/dual flame ionization detector (HS‐GC‐FID/FID) for the determination of chloroform in two fatal intoxication cases, as well as chloroform stability study. Analysis of biological samples revealed chloroform concentrations of 135.8, 16.1, 8.1, and 37.1 µg/ml in blood, urine, vitreous humor, and bile, respectively. Kidney, liver, and muscle specimens contained 119.5, 99.6, and 28.4 µg/g of chloroform, respectively. The results of stability studies indicate the highest decrease of chloroform in room temperature, so it is advised to store samples in a freezer. The addition of sodium fluoride is recommended as in blood samples collected to the test tubes without any preservative agent, the detection of chloroform after 91 days is almost impossible. It is important to emphasize that even old poisons can cause a lot of concerns today, as here described cases are linked to chloroform intoxication, as well as with possible danger which social media bring about nowadays.</abstract><cop>United States</cop><pub>Wiley Subscription Services, Inc</pub><pmid>34994396</pmid><doi>10.1111/1556-4029.14974</doi><tpages>8</tpages></addata></record> |
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subjects | Biological properties Blood Central nervous system Chloroform Chloroform - analysis chloroform intoxication chloroform stability Chromatography, Gas - methods cybersuicide Digital media fatal intoxication Flame Ionization Flame ionization detectors Gas chromatography Homicide HS‐GC‐FID/FID Humans Ingestion Intoxication Muscles Poisons Preservatives Room temperature Social Media Social networks Sodium fluoride Stability analysis suicide pact Suicides & suicide attempts Tubes Vitreous humour |
title | The dark side of social media: Two deaths related with chloroform intoxication |
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