Effect of enzymes on the scouring and bleaching properties of flax roves in supercritical CO2

Supercritical CO 2 (SC-CO 2 ) scouring and bleaching of flax roves was developed by using enzymes instead of chemical additives. Effect of dosage of enzyme, enzyme ratio, temperature, pressure, time and CO 2 flowrate on the scouring and bleaching properties of flax roves was investigated. The result...

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Veröffentlicht in:Cellulose (London) 2022-05, Vol.29 (7), p.3721-3731
Hauptverfasser: Zhang, Juan, Qiao, Yan, Zheng, Huanda, Gao, Shihui, Zheng, Laijiu
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container_end_page 3731
container_issue 7
container_start_page 3721
container_title Cellulose (London)
container_volume 29
creator Zhang, Juan
Qiao, Yan
Zheng, Huanda
Gao, Shihui
Zheng, Laijiu
description Supercritical CO 2 (SC-CO 2 ) scouring and bleaching of flax roves was developed by using enzymes instead of chemical additives. Effect of dosage of enzyme, enzyme ratio, temperature, pressure, time and CO 2 flowrate on the scouring and bleaching properties of flax roves was investigated. The results showed that the whiteness and residual gum content were significantly improved under appropriate conditions. Scouring and bleaching of flax roves by SC-CO 2 in combination with compound enzymes consisting of cellulose, xylanase and glucose oxidase could increase whiteness and reduce residual gum content. Moreover, glucose oxidase catalyzes the oxidation of β- d -glucose to produce H 2 O 2 , leading to the bleaching of fibers. An optimized scouring and bleaching of flax roves in SC-CO 2 was recommended at 50 °C and 15 MPa for 60 min with a dosage of enzyme of 3% (% weight of flax roves), an enzyme ratio (in mass) of 1:2:1 (cellulase: xylanase: glucose oxidase) and a CO 2 flowrate of 30 g/min. SEM displays more vertical grooves and bulges appeared on the fiber surface. The breaking strength and elongation at break of the samples were improved with the variation of scouring and bleaching conditions in comparison with the original flax roves.
doi_str_mv 10.1007/s10570-022-04497-7
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Effect of dosage of enzyme, enzyme ratio, temperature, pressure, time and CO 2 flowrate on the scouring and bleaching properties of flax roves was investigated. The results showed that the whiteness and residual gum content were significantly improved under appropriate conditions. Scouring and bleaching of flax roves by SC-CO 2 in combination with compound enzymes consisting of cellulose, xylanase and glucose oxidase could increase whiteness and reduce residual gum content. Moreover, glucose oxidase catalyzes the oxidation of β- d -glucose to produce H 2 O 2 , leading to the bleaching of fibers. An optimized scouring and bleaching of flax roves in SC-CO 2 was recommended at 50 °C and 15 MPa for 60 min with a dosage of enzyme of 3% (% weight of flax roves), an enzyme ratio (in mass) of 1:2:1 (cellulase: xylanase: glucose oxidase) and a CO 2 flowrate of 30 g/min. SEM displays more vertical grooves and bulges appeared on the fiber surface. 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subjects Additives
Bioorganic Chemistry
Bleaching
Carbon dioxide
Cellulase
Ceramics
Chemistry
Chemistry and Materials Science
Composites
Dosage
Elongation
Enzymes
Flax
Glass
Glucose
Glucose oxidase
Grooves
Hydrogen peroxide
Natural Materials
Organic Chemistry
Original Research
Oxidation
Physical Chemistry
Polymer Sciences
Scouring
Sustainable Development
Xylanase
title Effect of enzymes on the scouring and bleaching properties of flax roves in supercritical CO2
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