Investigation on the optical sensing behaviors in single Eu3+-activated Sr2InSbO6 phosphors under green light excitation

•Luminescent behaviors of Sr2InSbO6:Eu3+ phosphors were presented under green light excitation.•The crystal structure and concentration quenching were investigated in detail.•The emission intensity remained 91.61% at 425 K.•The sensing sensitivity was analyzed based on the temperature-dependent deca...

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Veröffentlicht in:Journal of alloys and compounds 2022-06, Vol.906, p.164322, Article 164322
Hauptverfasser: Li, Li, Li, Xinji, Xia, Weidi, Wang, Yongjie, Ling, Faling, Jiang, Sha, Xiang, Guotao, Zhou, Xianju, Li, Dengfeng, Hua, Yongbin
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container_title Journal of alloys and compounds
container_volume 906
creator Li, Li
Li, Xinji
Xia, Weidi
Wang, Yongjie
Ling, Faling
Jiang, Sha
Xiang, Guotao
Zhou, Xianju
Li, Dengfeng
Hua, Yongbin
description •Luminescent behaviors of Sr2InSbO6:Eu3+ phosphors were presented under green light excitation.•The crystal structure and concentration quenching were investigated in detail.•The emission intensity remained 91.61% at 425 K.•The sensing sensitivity was analyzed based on the temperature-dependent decay curves.•The sensing sensitivity could be affected by the doping concentration of Eu3+ ions. The sensing sensitivities of the Sr2InSbO6:Eu3+ phosphors with different doping concentrations were investigated based on the temperature-dependent decay curves. The crystal and electronic structure were studied by the X-ray diffractometer (XRD), Rietveld refinement, and X-ray photoelectron spectroscopy (XPS). In addition, the luminescent behaviors (e.g., photoluminescence spectra, concentration quenching, thermal stability, and luminescent dynamic) were investigated under the green light excitation (λex = 529 nm). The dominated peak was assigned to the 5D0 → 7F1 transition emitting an orange-red emission. Moreover, the obtained sample exhibited excellent thermal stability that the emission intensity remained 91.61% at 425 K. Eventually, the relative sensing sensitivity of the Sr2EuSbO6 phosphor was 0.766% K−1 and the doping concentration of Eu3+ ions greatly affected the sensing sensitivity. This work is the first time to investigate the single Eu3+-activated luminescent materials under the green light excitation.
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The sensing sensitivities of the Sr2InSbO6:Eu3+ phosphors with different doping concentrations were investigated based on the temperature-dependent decay curves. The crystal and electronic structure were studied by the X-ray diffractometer (XRD), Rietveld refinement, and X-ray photoelectron spectroscopy (XPS). In addition, the luminescent behaviors (e.g., photoluminescence spectra, concentration quenching, thermal stability, and luminescent dynamic) were investigated under the green light excitation (λex = 529 nm). The dominated peak was assigned to the 5D0 → 7F1 transition emitting an orange-red emission. Moreover, the obtained sample exhibited excellent thermal stability that the emission intensity remained 91.61% at 425 K. Eventually, the relative sensing sensitivity of the Sr2EuSbO6 phosphor was 0.766% K−1 and the doping concentration of Eu3+ ions greatly affected the sensing sensitivity. This work is the first time to investigate the single Eu3+-activated luminescent materials under the green light excitation.</description><identifier>ISSN: 0925-8388</identifier><identifier>EISSN: 1873-4669</identifier><identifier>DOI: 10.1016/j.jallcom.2022.164322</identifier><language>eng</language><publisher>Lausanne: Elsevier B.V</publisher><subject>Concentration ; Crystal structure ; Decay curves ; Doping ; Dynamic stability ; Electronic structure ; Europium ; Excitation ; Green-light excitation ; Investigations ; Phosphors ; Photoelectrons ; Photoluminescence ; Sensing sensitivity ; Sensitivity ; Spectrum analysis ; Temperature dependence ; Thermal stability ; X ray photoelectron spectroscopy</subject><ispartof>Journal of alloys and compounds, 2022-06, Vol.906, p.164322, Article 164322</ispartof><rights>2022 Elsevier B.V.</rights><rights>Copyright Elsevier BV Jun 15, 2022</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c267t-208b19bd25f683a54b6f282ccbcae88b198e49b9fba7c639de1a3ef94d31d02a3</citedby><cites>FETCH-LOGICAL-c267t-208b19bd25f683a54b6f282ccbcae88b198e49b9fba7c639de1a3ef94d31d02a3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.jallcom.2022.164322$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids></links><search><creatorcontrib>Li, Li</creatorcontrib><creatorcontrib>Li, Xinji</creatorcontrib><creatorcontrib>Xia, Weidi</creatorcontrib><creatorcontrib>Wang, Yongjie</creatorcontrib><creatorcontrib>Ling, Faling</creatorcontrib><creatorcontrib>Jiang, Sha</creatorcontrib><creatorcontrib>Xiang, Guotao</creatorcontrib><creatorcontrib>Zhou, Xianju</creatorcontrib><creatorcontrib>Li, Dengfeng</creatorcontrib><creatorcontrib>Hua, Yongbin</creatorcontrib><title>Investigation on the optical sensing behaviors in single Eu3+-activated Sr2InSbO6 phosphors under green light excitation</title><title>Journal of alloys and compounds</title><description>•Luminescent behaviors of Sr2InSbO6:Eu3+ phosphors were presented under green light excitation.•The crystal structure and concentration quenching were investigated in detail.•The emission intensity remained 91.61% at 425 K.•The sensing sensitivity was analyzed based on the temperature-dependent decay curves.•The sensing sensitivity could be affected by the doping concentration of Eu3+ ions. The sensing sensitivities of the Sr2InSbO6:Eu3+ phosphors with different doping concentrations were investigated based on the temperature-dependent decay curves. The crystal and electronic structure were studied by the X-ray diffractometer (XRD), Rietveld refinement, and X-ray photoelectron spectroscopy (XPS). In addition, the luminescent behaviors (e.g., photoluminescence spectra, concentration quenching, thermal stability, and luminescent dynamic) were investigated under the green light excitation (λex = 529 nm). The dominated peak was assigned to the 5D0 → 7F1 transition emitting an orange-red emission. Moreover, the obtained sample exhibited excellent thermal stability that the emission intensity remained 91.61% at 425 K. Eventually, the relative sensing sensitivity of the Sr2EuSbO6 phosphor was 0.766% K−1 and the doping concentration of Eu3+ ions greatly affected the sensing sensitivity. 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The sensing sensitivities of the Sr2InSbO6:Eu3+ phosphors with different doping concentrations were investigated based on the temperature-dependent decay curves. The crystal and electronic structure were studied by the X-ray diffractometer (XRD), Rietveld refinement, and X-ray photoelectron spectroscopy (XPS). In addition, the luminescent behaviors (e.g., photoluminescence spectra, concentration quenching, thermal stability, and luminescent dynamic) were investigated under the green light excitation (λex = 529 nm). The dominated peak was assigned to the 5D0 → 7F1 transition emitting an orange-red emission. Moreover, the obtained sample exhibited excellent thermal stability that the emission intensity remained 91.61% at 425 K. Eventually, the relative sensing sensitivity of the Sr2EuSbO6 phosphor was 0.766% K−1 and the doping concentration of Eu3+ ions greatly affected the sensing sensitivity. This work is the first time to investigate the single Eu3+-activated luminescent materials under the green light excitation.</abstract><cop>Lausanne</cop><pub>Elsevier B.V</pub><doi>10.1016/j.jallcom.2022.164322</doi></addata></record>
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subjects Concentration
Crystal structure
Decay curves
Doping
Dynamic stability
Electronic structure
Europium
Excitation
Green-light excitation
Investigations
Phosphors
Photoelectrons
Photoluminescence
Sensing sensitivity
Sensitivity
Spectrum analysis
Temperature dependence
Thermal stability
X ray photoelectron spectroscopy
title Investigation on the optical sensing behaviors in single Eu3+-activated Sr2InSbO6 phosphors under green light excitation
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