Investigation on the optical sensing behaviors in single Eu3+-activated Sr2InSbO6 phosphors under green light excitation
•Luminescent behaviors of Sr2InSbO6:Eu3+ phosphors were presented under green light excitation.•The crystal structure and concentration quenching were investigated in detail.•The emission intensity remained 91.61% at 425 K.•The sensing sensitivity was analyzed based on the temperature-dependent deca...
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Veröffentlicht in: | Journal of alloys and compounds 2022-06, Vol.906, p.164322, Article 164322 |
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creator | Li, Li Li, Xinji Xia, Weidi Wang, Yongjie Ling, Faling Jiang, Sha Xiang, Guotao Zhou, Xianju Li, Dengfeng Hua, Yongbin |
description | •Luminescent behaviors of Sr2InSbO6:Eu3+ phosphors were presented under green light excitation.•The crystal structure and concentration quenching were investigated in detail.•The emission intensity remained 91.61% at 425 K.•The sensing sensitivity was analyzed based on the temperature-dependent decay curves.•The sensing sensitivity could be affected by the doping concentration of Eu3+ ions.
The sensing sensitivities of the Sr2InSbO6:Eu3+ phosphors with different doping concentrations were investigated based on the temperature-dependent decay curves. The crystal and electronic structure were studied by the X-ray diffractometer (XRD), Rietveld refinement, and X-ray photoelectron spectroscopy (XPS). In addition, the luminescent behaviors (e.g., photoluminescence spectra, concentration quenching, thermal stability, and luminescent dynamic) were investigated under the green light excitation (λex = 529 nm). The dominated peak was assigned to the 5D0 → 7F1 transition emitting an orange-red emission. Moreover, the obtained sample exhibited excellent thermal stability that the emission intensity remained 91.61% at 425 K. Eventually, the relative sensing sensitivity of the Sr2EuSbO6 phosphor was 0.766% K−1 and the doping concentration of Eu3+ ions greatly affected the sensing sensitivity. This work is the first time to investigate the single Eu3+-activated luminescent materials under the green light excitation. |
doi_str_mv | 10.1016/j.jallcom.2022.164322 |
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The sensing sensitivities of the Sr2InSbO6:Eu3+ phosphors with different doping concentrations were investigated based on the temperature-dependent decay curves. The crystal and electronic structure were studied by the X-ray diffractometer (XRD), Rietveld refinement, and X-ray photoelectron spectroscopy (XPS). In addition, the luminescent behaviors (e.g., photoluminescence spectra, concentration quenching, thermal stability, and luminescent dynamic) were investigated under the green light excitation (λex = 529 nm). The dominated peak was assigned to the 5D0 → 7F1 transition emitting an orange-red emission. Moreover, the obtained sample exhibited excellent thermal stability that the emission intensity remained 91.61% at 425 K. Eventually, the relative sensing sensitivity of the Sr2EuSbO6 phosphor was 0.766% K−1 and the doping concentration of Eu3+ ions greatly affected the sensing sensitivity. This work is the first time to investigate the single Eu3+-activated luminescent materials under the green light excitation.</description><identifier>ISSN: 0925-8388</identifier><identifier>EISSN: 1873-4669</identifier><identifier>DOI: 10.1016/j.jallcom.2022.164322</identifier><language>eng</language><publisher>Lausanne: Elsevier B.V</publisher><subject>Concentration ; Crystal structure ; Decay curves ; Doping ; Dynamic stability ; Electronic structure ; Europium ; Excitation ; Green-light excitation ; Investigations ; Phosphors ; Photoelectrons ; Photoluminescence ; Sensing sensitivity ; Sensitivity ; Spectrum analysis ; Temperature dependence ; Thermal stability ; X ray photoelectron spectroscopy</subject><ispartof>Journal of alloys and compounds, 2022-06, Vol.906, p.164322, Article 164322</ispartof><rights>2022 Elsevier B.V.</rights><rights>Copyright Elsevier BV Jun 15, 2022</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c267t-208b19bd25f683a54b6f282ccbcae88b198e49b9fba7c639de1a3ef94d31d02a3</citedby><cites>FETCH-LOGICAL-c267t-208b19bd25f683a54b6f282ccbcae88b198e49b9fba7c639de1a3ef94d31d02a3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.jallcom.2022.164322$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids></links><search><creatorcontrib>Li, Li</creatorcontrib><creatorcontrib>Li, Xinji</creatorcontrib><creatorcontrib>Xia, Weidi</creatorcontrib><creatorcontrib>Wang, Yongjie</creatorcontrib><creatorcontrib>Ling, Faling</creatorcontrib><creatorcontrib>Jiang, Sha</creatorcontrib><creatorcontrib>Xiang, Guotao</creatorcontrib><creatorcontrib>Zhou, Xianju</creatorcontrib><creatorcontrib>Li, Dengfeng</creatorcontrib><creatorcontrib>Hua, Yongbin</creatorcontrib><title>Investigation on the optical sensing behaviors in single Eu3+-activated Sr2InSbO6 phosphors under green light excitation</title><title>Journal of alloys and compounds</title><description>•Luminescent behaviors of Sr2InSbO6:Eu3+ phosphors were presented under green light excitation.•The crystal structure and concentration quenching were investigated in detail.•The emission intensity remained 91.61% at 425 K.•The sensing sensitivity was analyzed based on the temperature-dependent decay curves.•The sensing sensitivity could be affected by the doping concentration of Eu3+ ions.
The sensing sensitivities of the Sr2InSbO6:Eu3+ phosphors with different doping concentrations were investigated based on the temperature-dependent decay curves. The crystal and electronic structure were studied by the X-ray diffractometer (XRD), Rietveld refinement, and X-ray photoelectron spectroscopy (XPS). In addition, the luminescent behaviors (e.g., photoluminescence spectra, concentration quenching, thermal stability, and luminescent dynamic) were investigated under the green light excitation (λex = 529 nm). The dominated peak was assigned to the 5D0 → 7F1 transition emitting an orange-red emission. Moreover, the obtained sample exhibited excellent thermal stability that the emission intensity remained 91.61% at 425 K. Eventually, the relative sensing sensitivity of the Sr2EuSbO6 phosphor was 0.766% K−1 and the doping concentration of Eu3+ ions greatly affected the sensing sensitivity. This work is the first time to investigate the single Eu3+-activated luminescent materials under the green light excitation.</description><subject>Concentration</subject><subject>Crystal structure</subject><subject>Decay curves</subject><subject>Doping</subject><subject>Dynamic stability</subject><subject>Electronic structure</subject><subject>Europium</subject><subject>Excitation</subject><subject>Green-light excitation</subject><subject>Investigations</subject><subject>Phosphors</subject><subject>Photoelectrons</subject><subject>Photoluminescence</subject><subject>Sensing sensitivity</subject><subject>Sensitivity</subject><subject>Spectrum analysis</subject><subject>Temperature dependence</subject><subject>Thermal stability</subject><subject>X ray photoelectron spectroscopy</subject><issn>0925-8388</issn><issn>1873-4669</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNqFUMtKBDEQDKLg-vgEIeBRZs1jJpOcRMTHguBBPYdMpmc3w5isSXbRvzfrehe6aeiurqIKoQtK5pRQcT3ORzNNNnzMGWFsTkXNGTtAMypbXtVCqEM0I4o1leRSHqOTlEZCCFWcztDXwm8hZbc02QWPS-UV4LDOzpoJJ_DJ-SXuYGW2LsSEnce7zQT4fsOvKmOz25oMPX6NbOFfuxeB16uQShfwxvcQ8TICeDy55Spj-LIu_0qdoaPBTAnO_-Ypen-4f7t7qp5fHhd3t8-VZaLNFSOyo6rrWTMIyU1Td2JgklnbWQNyd5NQq04NnWmt4KoHajgMqu457Qkz_BRd7nnXMXxuilU9hk30RVIz0RQN2qq2oJo9ysaQUoRBr6P7MPFbU6J3IetR_4WsdyHrfcjl72b_B8XC1kHUyTrwFnoXwWbdB_cPww-mjoob</recordid><startdate>20220615</startdate><enddate>20220615</enddate><creator>Li, Li</creator><creator>Li, Xinji</creator><creator>Xia, Weidi</creator><creator>Wang, Yongjie</creator><creator>Ling, Faling</creator><creator>Jiang, Sha</creator><creator>Xiang, Guotao</creator><creator>Zhou, Xianju</creator><creator>Li, Dengfeng</creator><creator>Hua, Yongbin</creator><general>Elsevier B.V</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20220615</creationdate><title>Investigation on the optical sensing behaviors in single Eu3+-activated Sr2InSbO6 phosphors under green light excitation</title><author>Li, Li ; Li, Xinji ; Xia, Weidi ; Wang, Yongjie ; Ling, Faling ; Jiang, Sha ; Xiang, Guotao ; Zhou, Xianju ; Li, Dengfeng ; Hua, Yongbin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c267t-208b19bd25f683a54b6f282ccbcae88b198e49b9fba7c639de1a3ef94d31d02a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Concentration</topic><topic>Crystal structure</topic><topic>Decay curves</topic><topic>Doping</topic><topic>Dynamic stability</topic><topic>Electronic structure</topic><topic>Europium</topic><topic>Excitation</topic><topic>Green-light excitation</topic><topic>Investigations</topic><topic>Phosphors</topic><topic>Photoelectrons</topic><topic>Photoluminescence</topic><topic>Sensing sensitivity</topic><topic>Sensitivity</topic><topic>Spectrum analysis</topic><topic>Temperature dependence</topic><topic>Thermal stability</topic><topic>X ray photoelectron spectroscopy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Li, Li</creatorcontrib><creatorcontrib>Li, Xinji</creatorcontrib><creatorcontrib>Xia, Weidi</creatorcontrib><creatorcontrib>Wang, Yongjie</creatorcontrib><creatorcontrib>Ling, Faling</creatorcontrib><creatorcontrib>Jiang, Sha</creatorcontrib><creatorcontrib>Xiang, Guotao</creatorcontrib><creatorcontrib>Zhou, Xianju</creatorcontrib><creatorcontrib>Li, Dengfeng</creatorcontrib><creatorcontrib>Hua, Yongbin</creatorcontrib><collection>CrossRef</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of alloys and compounds</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Li, Li</au><au>Li, Xinji</au><au>Xia, Weidi</au><au>Wang, Yongjie</au><au>Ling, Faling</au><au>Jiang, Sha</au><au>Xiang, Guotao</au><au>Zhou, Xianju</au><au>Li, Dengfeng</au><au>Hua, Yongbin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Investigation on the optical sensing behaviors in single Eu3+-activated Sr2InSbO6 phosphors under green light excitation</atitle><jtitle>Journal of alloys and compounds</jtitle><date>2022-06-15</date><risdate>2022</risdate><volume>906</volume><spage>164322</spage><pages>164322-</pages><artnum>164322</artnum><issn>0925-8388</issn><eissn>1873-4669</eissn><abstract>•Luminescent behaviors of Sr2InSbO6:Eu3+ phosphors were presented under green light excitation.•The crystal structure and concentration quenching were investigated in detail.•The emission intensity remained 91.61% at 425 K.•The sensing sensitivity was analyzed based on the temperature-dependent decay curves.•The sensing sensitivity could be affected by the doping concentration of Eu3+ ions.
The sensing sensitivities of the Sr2InSbO6:Eu3+ phosphors with different doping concentrations were investigated based on the temperature-dependent decay curves. The crystal and electronic structure were studied by the X-ray diffractometer (XRD), Rietveld refinement, and X-ray photoelectron spectroscopy (XPS). In addition, the luminescent behaviors (e.g., photoluminescence spectra, concentration quenching, thermal stability, and luminescent dynamic) were investigated under the green light excitation (λex = 529 nm). The dominated peak was assigned to the 5D0 → 7F1 transition emitting an orange-red emission. Moreover, the obtained sample exhibited excellent thermal stability that the emission intensity remained 91.61% at 425 K. Eventually, the relative sensing sensitivity of the Sr2EuSbO6 phosphor was 0.766% K−1 and the doping concentration of Eu3+ ions greatly affected the sensing sensitivity. This work is the first time to investigate the single Eu3+-activated luminescent materials under the green light excitation.</abstract><cop>Lausanne</cop><pub>Elsevier B.V</pub><doi>10.1016/j.jallcom.2022.164322</doi></addata></record> |
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subjects | Concentration Crystal structure Decay curves Doping Dynamic stability Electronic structure Europium Excitation Green-light excitation Investigations Phosphors Photoelectrons Photoluminescence Sensing sensitivity Sensitivity Spectrum analysis Temperature dependence Thermal stability X ray photoelectron spectroscopy |
title | Investigation on the optical sensing behaviors in single Eu3+-activated Sr2InSbO6 phosphors under green light excitation |
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