Insights into kinetics extraction of the homogeneous electrocatalytic reaction between TMPD and ascorbic acid by cyclic voltammetry

[Display omitted] •Reaction rate constant between TMPD•+ and AA is determined by a finite element model.•The waveform transition behavior hinders the kinetics extraction of redox mediation.•A rate constant of 2.61 (mol m−3)−1 s−1 is obtained from the proposed methodology. As a continued research int...

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Veröffentlicht in:	Journal of electroanalytical chemistry (Lausanne, Switzerland) Switzerland), 2022-01, Vol.904, p.115948, Article 115948
Hauptverfasser:	Liang, Xiaohua, Song, Peng, Wang, Zhan, Qin, Zhenping, Guo, Hongxia
Format:	Artikel
Sprache:	eng
Schlagworte:	Ascorbic acid Chemical analysis Diamines Energy conversion Finite element method Finite element simulation Homogeneous electrocatalytic reaction Kinetics Kinetics extraction Oxidation Reaction kinetics Redox mediation Substrates Voltammetry Waveforms
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