Synthesis of amidoximated polyacrylonitrile/sodium alginate composite hydrogel beed and its use in selective and recyclable removal of U(VI)

In this study, a novel type of composite hydrogel bead (PSH) was prepared by mixing of amidoximated polyacrylonitrile (PAO) and sodium alginate (SA). The structure of PSH was characterized with FT-IR, SEM and XPS. The influences of adsorption conditions on uranium(VI) adsorption by PSH were investig...

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Veröffentlicht in:Journal of radioanalytical and nuclear chemistry 2022-04, Vol.331 (4), p.1669-1682
Hauptverfasser: Zhu, Bingyu, Li, Le, Dai, Zhongran, Tang, Shuangyang, Zhen, Deshuai, Sun, Lin, Chen, Lei, Tuo, Chen, Tang, Ziwei
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container_end_page 1682
container_issue 4
container_start_page 1669
container_title Journal of radioanalytical and nuclear chemistry
container_volume 331
creator Zhu, Bingyu
Li, Le
Dai, Zhongran
Tang, Shuangyang
Zhen, Deshuai
Sun, Lin
Chen, Lei
Tuo, Chen
Tang, Ziwei
description In this study, a novel type of composite hydrogel bead (PSH) was prepared by mixing of amidoximated polyacrylonitrile (PAO) and sodium alginate (SA). The structure of PSH was characterized with FT-IR, SEM and XPS. The influences of adsorption conditions on uranium(VI) adsorption by PSH were investigated by batch experiments. The kinetic and isotherm data were consistent with pseudo-second-order and Langmuir models, respectively. PSH displayed high selective adsorption capacity for uranium(VI). The maximum adsorption amount can reach 133.33 mg g −1 . PSH was separated from aqueous solution easy and showed an excellent regeneration capacity. This research demonstrated that PSH had a broad prospect of application in the field of repairing uranium-containing wastewater.
doi_str_mv 10.1007/s10967-022-08233-0
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subjects Adsorption
Analysis
Aqueous solutions
Chemistry
Chemistry and Materials Science
Diagnostic Radiology
Hadrons
Heavy Ions
Hydrogels
Inorganic Chemistry
Nuclear Chemistry
Nuclear Physics
Physical Chemistry
Polyacrylonitrile
Selective adsorption
Sodium alginate
Uranium
Wastewater
X ray photoelectron spectroscopy
title Synthesis of amidoximated polyacrylonitrile/sodium alginate composite hydrogel beed and its use in selective and recyclable removal of U(VI)
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