Enhancement of the magnetic and optical properties of Ni0.5Zn0.5Fe2O4 nanoparticles by ruthenium doping
The characterization of Nanosized Ni 0.5 Zn 0.5 Ru x Fe 2− x O 4 (0.00 ≤ x ≤ 0.015), prepared by the wet chemical coprecipitation method, is reported in the current investigation. X-ray powder diffraction (XRD) analysis has confirmed the formation of a single phased spinel cubic structure. While t...
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| creator | Basma, H. Al Boukhari, J. Abd Al Nabi, M. Aridi, A. Sayed Hassan, R. Naoufal, D. Roumie, M. Awad, R. |
| description | The characterization of Nanosized Ni
0.5
Zn
0.5
Ru
x
Fe
2−
x
O
4
(0.00 ≤
x
≤ 0.015), prepared by the wet chemical coprecipitation method, is reported in the current investigation. X-ray powder diffraction (XRD) analysis has confirmed the formation of a single phased spinel cubic structure. While transmission electron microscopy (TEM) studies have shown an increase in the particle size for high content of Ru
3+
doping. The elemental composition of all samples was investigated using energy dispersive x-ray (EDX) measurements. The results showed a reciprocal relation between the Fe
3+
and Ru
3+
contents, suggesting the successful substitution of Ru
3+
in Fe
3+
sites. UV–Vis spectroscopy studies, via Urbach energy analysis, proposed a perturbation in the band structure of Ni
0.5
Zn
0.5
Fe
2
O
4
induced by Ru
3+
substitution, affecting both the direct and indirect bandgap energies. Excitation wavelength-dependent photoluminescence (PL) studies, presented for the first time, have shown a strong dependence of the emission spectra on both the excitation wavelength and Ru
3+
doping. The PL analysis suggests the utilization of Ni
0.5
Zn
0.5
Ru
x
Fe
2−
x
O
4
as a candidate for photocatalytic applications. Furthermore, VSM studies, have shown a transition from superparamagnetic to soft ferromagnetic for Ru
3+
doped samples. The saturation magnetization, coercivity, and effective anisotropy were enhanced as a result of Ru
3+
doping. Finally, photocatalysis experiments have shown an enhancement of the degradation rate of nitrobenzene for the sample with
x
= 0.0125 with the ability of magnetic recycling, in agreement with the PL and VSM studies. |
| doi_str_mv | 10.1007/s00339-022-05552-7 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2651736802</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2651736802</sourcerecordid><originalsourceid>FETCH-LOGICAL-c319t-e9eb90569aae4fb6661752f5a214f66526f019406d4be6d84c1421b519f709b43</originalsourceid><addsrcrecordid>eNp9kD9PwzAQxS0EEqXwBZgsMaec_6YeUdUCUkUXWFgsJ7HTVI0T7GTot8clSGzc4DvLv_fOegjdE1gQgPwxAjCmMqA0AyEEzfILNCOcpatkcIlmoHieLZmS1-gmxgOk4pTOUL32e-NL21o_4M7hYW9xa2pvh6bExle469NkjrgPXW_D0Nh4xt4aWIhPn46NpTuOvfFdb9JzeUxAccJhTE6-GVtcdX3j61t05cwx2rvfPkcfm_X76iXb7p5fV0_brGREDZlVtlAgpDLGcldIKUkuqBOGEu6kFFQ6IIqDrHhhZbXkJeGUFIIol4MqOJujh8k3_fdrtHHQh24MPq3UVAqSM7kEmig6UWXoYgzW6T40rQknTUCfA9VToDoFqn8C1XkSsUkUE-xrG_6s_1F9A55Ld3k</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2651736802</pqid></control><display><type>article</type><title>Enhancement of the magnetic and optical properties of Ni0.5Zn0.5Fe2O4 nanoparticles by ruthenium doping</title><source>SpringerLink (Online service)</source><creator>Basma, H. ; Al Boukhari, J. ; Abd Al Nabi, M. ; Aridi, A. ; Sayed Hassan, R. ; Naoufal, D. ; Roumie, M. ; Awad, R.</creator><creatorcontrib>Basma, H. ; Al Boukhari, J. ; Abd Al Nabi, M. ; Aridi, A. ; Sayed Hassan, R. ; Naoufal, D. ; Roumie, M. ; Awad, R.</creatorcontrib><description>The characterization of Nanosized Ni
0.5
Zn
0.5
Ru
x
Fe
2−
x
O
4
(0.00 ≤
x
≤ 0.015), prepared by the wet chemical coprecipitation method, is reported in the current investigation. X-ray powder diffraction (XRD) analysis has confirmed the formation of a single phased spinel cubic structure. While transmission electron microscopy (TEM) studies have shown an increase in the particle size for high content of Ru
3+
doping. The elemental composition of all samples was investigated using energy dispersive x-ray (EDX) measurements. The results showed a reciprocal relation between the Fe
3+
and Ru
3+
contents, suggesting the successful substitution of Ru
3+
in Fe
3+
sites. UV–Vis spectroscopy studies, via Urbach energy analysis, proposed a perturbation in the band structure of Ni
0.5
Zn
0.5
Fe
2
O
4
induced by Ru
3+
substitution, affecting both the direct and indirect bandgap energies. Excitation wavelength-dependent photoluminescence (PL) studies, presented for the first time, have shown a strong dependence of the emission spectra on both the excitation wavelength and Ru
3+
doping. The PL analysis suggests the utilization of Ni
0.5
Zn
0.5
Ru
x
Fe
2−
x
O
4
as a candidate for photocatalytic applications. Furthermore, VSM studies, have shown a transition from superparamagnetic to soft ferromagnetic for Ru
3+
doped samples. The saturation magnetization, coercivity, and effective anisotropy were enhanced as a result of Ru
3+
doping. Finally, photocatalysis experiments have shown an enhancement of the degradation rate of nitrobenzene for the sample with
x
= 0.0125 with the ability of magnetic recycling, in agreement with the PL and VSM studies.</description><identifier>ISSN: 0947-8396</identifier><identifier>EISSN: 1432-0630</identifier><identifier>DOI: 10.1007/s00339-022-05552-7</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Anisotropy ; Applied physics ; Characterization and Evaluation of Materials ; Coercivity ; Condensed Matter Physics ; Doping ; Emission spectra ; Excitation ; Ferromagnetism ; Machines ; Magnetic properties ; Magnetic saturation ; Manufacturing ; Materials science ; Nanoparticles ; Nanotechnology ; Nitrobenzene ; Optical and Electronic Materials ; Optical properties ; Perturbation ; Photocatalysis ; Photoluminescence ; Physics ; Physics and Astronomy ; Processes ; Ruthenium ; Spectrum analysis ; Substitutes ; Surfaces and Interfaces ; Thin Films ; X ray powder diffraction</subject><ispartof>Applied physics. A, Materials science & processing, 2022-05, Vol.128 (5), Article 409</ispartof><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH, DE part of Springer Nature 2022</rights><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH, DE part of Springer Nature 2022.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-e9eb90569aae4fb6661752f5a214f66526f019406d4be6d84c1421b519f709b43</citedby><cites>FETCH-LOGICAL-c319t-e9eb90569aae4fb6661752f5a214f66526f019406d4be6d84c1421b519f709b43</cites><orcidid>0000-0002-0060-5259</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00339-022-05552-7$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s00339-022-05552-7$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Basma, H.</creatorcontrib><creatorcontrib>Al Boukhari, J.</creatorcontrib><creatorcontrib>Abd Al Nabi, M.</creatorcontrib><creatorcontrib>Aridi, A.</creatorcontrib><creatorcontrib>Sayed Hassan, R.</creatorcontrib><creatorcontrib>Naoufal, D.</creatorcontrib><creatorcontrib>Roumie, M.</creatorcontrib><creatorcontrib>Awad, R.</creatorcontrib><title>Enhancement of the magnetic and optical properties of Ni0.5Zn0.5Fe2O4 nanoparticles by ruthenium doping</title><title>Applied physics. A, Materials science & processing</title><addtitle>Appl. Phys. A</addtitle><description>The characterization of Nanosized Ni
0.5
Zn
0.5
Ru
x
Fe
2−
x
O
4
(0.00 ≤
x
≤ 0.015), prepared by the wet chemical coprecipitation method, is reported in the current investigation. X-ray powder diffraction (XRD) analysis has confirmed the formation of a single phased spinel cubic structure. While transmission electron microscopy (TEM) studies have shown an increase in the particle size for high content of Ru
3+
doping. The elemental composition of all samples was investigated using energy dispersive x-ray (EDX) measurements. The results showed a reciprocal relation between the Fe
3+
and Ru
3+
contents, suggesting the successful substitution of Ru
3+
in Fe
3+
sites. UV–Vis spectroscopy studies, via Urbach energy analysis, proposed a perturbation in the band structure of Ni
0.5
Zn
0.5
Fe
2
O
4
induced by Ru
3+
substitution, affecting both the direct and indirect bandgap energies. Excitation wavelength-dependent photoluminescence (PL) studies, presented for the first time, have shown a strong dependence of the emission spectra on both the excitation wavelength and Ru
3+
doping. The PL analysis suggests the utilization of Ni
0.5
Zn
0.5
Ru
x
Fe
2−
x
O
4
as a candidate for photocatalytic applications. Furthermore, VSM studies, have shown a transition from superparamagnetic to soft ferromagnetic for Ru
3+
doped samples. The saturation magnetization, coercivity, and effective anisotropy were enhanced as a result of Ru
3+
doping. Finally, photocatalysis experiments have shown an enhancement of the degradation rate of nitrobenzene for the sample with
x
= 0.0125 with the ability of magnetic recycling, in agreement with the PL and VSM studies.</description><subject>Anisotropy</subject><subject>Applied physics</subject><subject>Characterization and Evaluation of Materials</subject><subject>Coercivity</subject><subject>Condensed Matter Physics</subject><subject>Doping</subject><subject>Emission spectra</subject><subject>Excitation</subject><subject>Ferromagnetism</subject><subject>Machines</subject><subject>Magnetic properties</subject><subject>Magnetic saturation</subject><subject>Manufacturing</subject><subject>Materials science</subject><subject>Nanoparticles</subject><subject>Nanotechnology</subject><subject>Nitrobenzene</subject><subject>Optical and Electronic Materials</subject><subject>Optical properties</subject><subject>Perturbation</subject><subject>Photocatalysis</subject><subject>Photoluminescence</subject><subject>Physics</subject><subject>Physics and Astronomy</subject><subject>Processes</subject><subject>Ruthenium</subject><subject>Spectrum analysis</subject><subject>Substitutes</subject><subject>Surfaces and Interfaces</subject><subject>Thin Films</subject><subject>X ray powder diffraction</subject><issn>0947-8396</issn><issn>1432-0630</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp9kD9PwzAQxS0EEqXwBZgsMaec_6YeUdUCUkUXWFgsJ7HTVI0T7GTot8clSGzc4DvLv_fOegjdE1gQgPwxAjCmMqA0AyEEzfILNCOcpatkcIlmoHieLZmS1-gmxgOk4pTOUL32e-NL21o_4M7hYW9xa2pvh6bExle469NkjrgPXW_D0Nh4xt4aWIhPn46NpTuOvfFdb9JzeUxAccJhTE6-GVtcdX3j61t05cwx2rvfPkcfm_X76iXb7p5fV0_brGREDZlVtlAgpDLGcldIKUkuqBOGEu6kFFQ6IIqDrHhhZbXkJeGUFIIol4MqOJujh8k3_fdrtHHQh24MPq3UVAqSM7kEmig6UWXoYgzW6T40rQknTUCfA9VToDoFqn8C1XkSsUkUE-xrG_6s_1F9A55Ld3k</recordid><startdate>20220501</startdate><enddate>20220501</enddate><creator>Basma, H.</creator><creator>Al Boukhari, J.</creator><creator>Abd Al Nabi, M.</creator><creator>Aridi, A.</creator><creator>Sayed Hassan, R.</creator><creator>Naoufal, D.</creator><creator>Roumie, M.</creator><creator>Awad, R.</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-0060-5259</orcidid></search><sort><creationdate>20220501</creationdate><title>Enhancement of the magnetic and optical properties of Ni0.5Zn0.5Fe2O4 nanoparticles by ruthenium doping</title><author>Basma, H. ; Al Boukhari, J. ; Abd Al Nabi, M. ; Aridi, A. ; Sayed Hassan, R. ; Naoufal, D. ; Roumie, M. ; Awad, R.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-e9eb90569aae4fb6661752f5a214f66526f019406d4be6d84c1421b519f709b43</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Anisotropy</topic><topic>Applied physics</topic><topic>Characterization and Evaluation of Materials</topic><topic>Coercivity</topic><topic>Condensed Matter Physics</topic><topic>Doping</topic><topic>Emission spectra</topic><topic>Excitation</topic><topic>Ferromagnetism</topic><topic>Machines</topic><topic>Magnetic properties</topic><topic>Magnetic saturation</topic><topic>Manufacturing</topic><topic>Materials science</topic><topic>Nanoparticles</topic><topic>Nanotechnology</topic><topic>Nitrobenzene</topic><topic>Optical and Electronic Materials</topic><topic>Optical properties</topic><topic>Perturbation</topic><topic>Photocatalysis</topic><topic>Photoluminescence</topic><topic>Physics</topic><topic>Physics and Astronomy</topic><topic>Processes</topic><topic>Ruthenium</topic><topic>Spectrum analysis</topic><topic>Substitutes</topic><topic>Surfaces and Interfaces</topic><topic>Thin Films</topic><topic>X ray powder diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Basma, H.</creatorcontrib><creatorcontrib>Al Boukhari, J.</creatorcontrib><creatorcontrib>Abd Al Nabi, M.</creatorcontrib><creatorcontrib>Aridi, A.</creatorcontrib><creatorcontrib>Sayed Hassan, R.</creatorcontrib><creatorcontrib>Naoufal, D.</creatorcontrib><creatorcontrib>Roumie, M.</creatorcontrib><creatorcontrib>Awad, R.</creatorcontrib><collection>CrossRef</collection><jtitle>Applied physics. A, Materials science & processing</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Basma, H.</au><au>Al Boukhari, J.</au><au>Abd Al Nabi, M.</au><au>Aridi, A.</au><au>Sayed Hassan, R.</au><au>Naoufal, D.</au><au>Roumie, M.</au><au>Awad, R.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Enhancement of the magnetic and optical properties of Ni0.5Zn0.5Fe2O4 nanoparticles by ruthenium doping</atitle><jtitle>Applied physics. A, Materials science & processing</jtitle><stitle>Appl. Phys. A</stitle><date>2022-05-01</date><risdate>2022</risdate><volume>128</volume><issue>5</issue><artnum>409</artnum><issn>0947-8396</issn><eissn>1432-0630</eissn><abstract>The characterization of Nanosized Ni
0.5
Zn
0.5
Ru
x
Fe
2−
x
O
4
(0.00 ≤
x
≤ 0.015), prepared by the wet chemical coprecipitation method, is reported in the current investigation. X-ray powder diffraction (XRD) analysis has confirmed the formation of a single phased spinel cubic structure. While transmission electron microscopy (TEM) studies have shown an increase in the particle size for high content of Ru
3+
doping. The elemental composition of all samples was investigated using energy dispersive x-ray (EDX) measurements. The results showed a reciprocal relation between the Fe
3+
and Ru
3+
contents, suggesting the successful substitution of Ru
3+
in Fe
3+
sites. UV–Vis spectroscopy studies, via Urbach energy analysis, proposed a perturbation in the band structure of Ni
0.5
Zn
0.5
Fe
2
O
4
induced by Ru
3+
substitution, affecting both the direct and indirect bandgap energies. Excitation wavelength-dependent photoluminescence (PL) studies, presented for the first time, have shown a strong dependence of the emission spectra on both the excitation wavelength and Ru
3+
doping. The PL analysis suggests the utilization of Ni
0.5
Zn
0.5
Ru
x
Fe
2−
x
O
4
as a candidate for photocatalytic applications. Furthermore, VSM studies, have shown a transition from superparamagnetic to soft ferromagnetic for Ru
3+
doped samples. The saturation magnetization, coercivity, and effective anisotropy were enhanced as a result of Ru
3+
doping. Finally, photocatalysis experiments have shown an enhancement of the degradation rate of nitrobenzene for the sample with
x
= 0.0125 with the ability of magnetic recycling, in agreement with the PL and VSM studies.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s00339-022-05552-7</doi><orcidid>https://orcid.org/0000-0002-0060-5259</orcidid></addata></record> |
| fulltext | fulltext |
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| ispartof | Applied physics. A, Materials science & processing, 2022-05, Vol.128 (5), Article 409 |
| issn | 0947-8396 1432-0630 |
| language | eng |
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| source | SpringerLink (Online service) |
| subjects | Anisotropy Applied physics Characterization and Evaluation of Materials Coercivity Condensed Matter Physics Doping Emission spectra Excitation Ferromagnetism Machines Magnetic properties Magnetic saturation Manufacturing Materials science Nanoparticles Nanotechnology Nitrobenzene Optical and Electronic Materials Optical properties Perturbation Photocatalysis Photoluminescence Physics Physics and Astronomy Processes Ruthenium Spectrum analysis Substitutes Surfaces and Interfaces Thin Films X ray powder diffraction |
| title | Enhancement of the magnetic and optical properties of Ni0.5Zn0.5Fe2O4 nanoparticles by ruthenium doping |
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