Sorption of 137Cs and 90Sr by Chemically Modified Humic Acids
The sorption characteristics of modified humic acid-based sorbents obtained from peat from the Gurovskoye deposit are studied. The functional and elemental composition of the sorbents is determined, and the molecular weight characteristics of the sorbent components are analyzed. The sorption of 137...
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| Veröffentlicht in: | Radiochemistry (New York, N.Y.) N.Y.), 2022, Vol.64 (1), p.88-95 |
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| container_title | Radiochemistry (New York, N.Y.) |
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| creator | Tokar, E. A. Fedorova, O. V. Egorina, A. M. Tananaev, I. G. |
| description | The sorption characteristics of modified humic acid-based sorbents obtained from peat from the Gurovskoye deposit are studied. The functional and elemental composition of the sorbents is determined, and the molecular weight characteristics of the sorbent components are analyzed. The sorption of
137
Cs and
90
Sr from liquid media depends on the pH value and the type and concentration of competing cations. The maximum adsorption capacity was calculated by fitting the obtained sorption isotherms to the Langmuir equation: the highest values are achieved on HA-2 (257 mg Cs/g) and HA-5 (310 mg Sr/g). The dependence of the sorption-selective characteristics of the sorption materials with respect to cesium and strontium was determined depending on the functional composition. The humic acid-based sorbents are recommended for the extraction of cesium and strontium radionuclides in a wide range of liquid media, including environmental objects, based on the results of this study. |
| doi_str_mv | 10.1134/S106636222201012X |
| format | Article |
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137
Cs and
90
Sr from liquid media depends on the pH value and the type and concentration of competing cations. The maximum adsorption capacity was calculated by fitting the obtained sorption isotherms to the Langmuir equation: the highest values are achieved on HA-2 (257 mg Cs/g) and HA-5 (310 mg Sr/g). The dependence of the sorption-selective characteristics of the sorption materials with respect to cesium and strontium was determined depending on the functional composition. The humic acid-based sorbents are recommended for the extraction of cesium and strontium radionuclides in a wide range of liquid media, including environmental objects, based on the results of this study.</description><identifier>ISSN: 1066-3622</identifier><identifier>EISSN: 1608-3288</identifier><identifier>DOI: 10.1134/S106636222201012X</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Cesium 137 ; Cesium isotopes ; Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Composition ; Humic acids ; Nuclear Chemistry ; Peat ; Radioisotopes ; Sorbents ; Sorption ; Strontium ; Strontium 90</subject><ispartof>Radiochemistry (New York, N.Y.), 2022, Vol.64 (1), p.88-95</ispartof><rights>Pleiades Publishing, Ltd. 2022</rights><rights>Pleiades Publishing, Ltd. 2022.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c161X-3dc818e6f058888666700b07f3dcc5fc3195385ee5f551e21434bddf5d885aab3</citedby><cites>FETCH-LOGICAL-c161X-3dc818e6f058888666700b07f3dcc5fc3195385ee5f551e21434bddf5d885aab3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S106636222201012X$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S106636222201012X$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Tokar, E. A.</creatorcontrib><creatorcontrib>Fedorova, O. V.</creatorcontrib><creatorcontrib>Egorina, A. M.</creatorcontrib><creatorcontrib>Tananaev, I. G.</creatorcontrib><title>Sorption of 137Cs and 90Sr by Chemically Modified Humic Acids</title><title>Radiochemistry (New York, N.Y.)</title><addtitle>Radiochemistry</addtitle><description>The sorption characteristics of modified humic acid-based sorbents obtained from peat from the Gurovskoye deposit are studied. The functional and elemental composition of the sorbents is determined, and the molecular weight characteristics of the sorbent components are analyzed. The sorption of
137
Cs and
90
Sr from liquid media depends on the pH value and the type and concentration of competing cations. The maximum adsorption capacity was calculated by fitting the obtained sorption isotherms to the Langmuir equation: the highest values are achieved on HA-2 (257 mg Cs/g) and HA-5 (310 mg Sr/g). The dependence of the sorption-selective characteristics of the sorption materials with respect to cesium and strontium was determined depending on the functional composition. The humic acid-based sorbents are recommended for the extraction of cesium and strontium radionuclides in a wide range of liquid media, including environmental objects, based on the results of this study.</description><subject>Cesium 137</subject><subject>Cesium isotopes</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Composition</subject><subject>Humic acids</subject><subject>Nuclear Chemistry</subject><subject>Peat</subject><subject>Radioisotopes</subject><subject>Sorbents</subject><subject>Sorption</subject><subject>Strontium</subject><subject>Strontium 90</subject><issn>1066-3622</issn><issn>1608-3288</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp1UE1Lw0AQXUTBWv0B3hY8R2ey2c324KEEtULFQxR6C8l-aEqbjbvNIf_eLRE8iO8yw7yPgUfINcItIsvuSgQhmEgjAAHTzQmZoQCZsFTK07hHOjny5-QihC0ASBRyRu5L5_tD6zrqLEWWF4HWnaYLKD1tRlp8mn2r6t1upC9Ot7Y1mq6GeKJL1epwSc5svQvm6mfOyfvjw1uxStavT8_Fcp0oFLhJmFYSpREWuIwQQuQADeQ2EopbxXDBmeTGcMs5mhQzljVaW66l5HXdsDm5mXJ7774GEw7V1g2-iy-rVHDI8gUwFlU4qZR3IXhjq963-9qPFUJ1bKn601L0pJMnRG33Yfxv8v-mb3hBZc0</recordid><startdate>2022</startdate><enddate>2022</enddate><creator>Tokar, E. A.</creator><creator>Fedorova, O. V.</creator><creator>Egorina, A. M.</creator><creator>Tananaev, I. G.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>2022</creationdate><title>Sorption of 137Cs and 90Sr by Chemically Modified Humic Acids</title><author>Tokar, E. A. ; Fedorova, O. V. ; Egorina, A. M. ; Tananaev, I. G.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c161X-3dc818e6f058888666700b07f3dcc5fc3195385ee5f551e21434bddf5d885aab3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Cesium 137</topic><topic>Cesium isotopes</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Composition</topic><topic>Humic acids</topic><topic>Nuclear Chemistry</topic><topic>Peat</topic><topic>Radioisotopes</topic><topic>Sorbents</topic><topic>Sorption</topic><topic>Strontium</topic><topic>Strontium 90</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Tokar, E. A.</creatorcontrib><creatorcontrib>Fedorova, O. V.</creatorcontrib><creatorcontrib>Egorina, A. M.</creatorcontrib><creatorcontrib>Tananaev, I. G.</creatorcontrib><collection>CrossRef</collection><jtitle>Radiochemistry (New York, N.Y.)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Tokar, E. A.</au><au>Fedorova, O. V.</au><au>Egorina, A. M.</au><au>Tananaev, I. G.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Sorption of 137Cs and 90Sr by Chemically Modified Humic Acids</atitle><jtitle>Radiochemistry (New York, N.Y.)</jtitle><stitle>Radiochemistry</stitle><date>2022</date><risdate>2022</risdate><volume>64</volume><issue>1</issue><spage>88</spage><epage>95</epage><pages>88-95</pages><issn>1066-3622</issn><eissn>1608-3288</eissn><abstract>The sorption characteristics of modified humic acid-based sorbents obtained from peat from the Gurovskoye deposit are studied. The functional and elemental composition of the sorbents is determined, and the molecular weight characteristics of the sorbent components are analyzed. The sorption of
137
Cs and
90
Sr from liquid media depends on the pH value and the type and concentration of competing cations. The maximum adsorption capacity was calculated by fitting the obtained sorption isotherms to the Langmuir equation: the highest values are achieved on HA-2 (257 mg Cs/g) and HA-5 (310 mg Sr/g). The dependence of the sorption-selective characteristics of the sorption materials with respect to cesium and strontium was determined depending on the functional composition. The humic acid-based sorbents are recommended for the extraction of cesium and strontium radionuclides in a wide range of liquid media, including environmental objects, based on the results of this study.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S106636222201012X</doi><tpages>8</tpages></addata></record> |
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| identifier | ISSN: 1066-3622 |
| ispartof | Radiochemistry (New York, N.Y.), 2022, Vol.64 (1), p.88-95 |
| issn | 1066-3622 1608-3288 |
| language | eng |
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| source | Springer Nature - Complete Springer Journals |
| subjects | Cesium 137 Cesium isotopes Chemistry Chemistry and Materials Science Chemistry/Food Science Composition Humic acids Nuclear Chemistry Peat Radioisotopes Sorbents Sorption Strontium Strontium 90 |
| title | Sorption of 137Cs and 90Sr by Chemically Modified Humic Acids |
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