Synthesis and Crystal and Molecular Structures of 1,3-Di-p-tolyl-5-(5'-allyl 2'-ethoxybenzyl)-1,3,5-diazaphosphacyclohexane Complexes with Ni(II) and Pt(II) Salts

The reaction of heterocyclic phosphine ligand, 1,3-di- p -tolyl-5-(5'-allyl-2'-ethoxybenzyl)-1,3-diaza-5-diazaphosphacyclohexane (L), containing a functional substituent at phosphorus, with (1,5-cyclooctadiene)dichloroplatinum(II) and nickel(II) chloride gave complexes PtCl 2 L 2 ( I ) and...

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Veröffentlicht in:Russian journal of coordination chemistry 2022-04, Vol.48 (4), p.189-194
Hauptverfasser: Balueva, A. S., Musina, E. I., Baimukhametov, F. Z., Nikonov, G. N., Gubaidullin, A. T., Litvinov, I. A., Karasik, A. A.
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container_end_page 194
container_issue 4
container_start_page 189
container_title Russian journal of coordination chemistry
container_volume 48
creator Balueva, A. S.
Musina, E. I.
Baimukhametov, F. Z.
Nikonov, G. N.
Gubaidullin, A. T.
Litvinov, I. A.
Karasik, A. A.
description The reaction of heterocyclic phosphine ligand, 1,3-di- p -tolyl-5-(5'-allyl-2'-ethoxybenzyl)-1,3-diaza-5-diazaphosphacyclohexane (L), containing a functional substituent at phosphorus, with (1,5-cyclooctadiene)dichloroplatinum(II) and nickel(II) chloride gave complexes PtCl 2 L 2 ( I ) and NiCl 2 L 2 ( II ), respectively, with the cis- and trans -configurations of the central ion. The structure of the complexes was determined by X-ray diffraction (CIF files CCDC no. 2097704 ( I ), 2097705 ( II )).
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subjects Chemical synthesis
Chemistry
Chemistry and Materials Science
Crystal structure
Crystals
Inorganic Chemistry
Molecular structure
Phosphines
Physical Chemistry
title Synthesis and Crystal and Molecular Structures of 1,3-Di-p-tolyl-5-(5'-allyl 2'-ethoxybenzyl)-1,3,5-diazaphosphacyclohexane Complexes with Ni(II) and Pt(II) Salts
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