Synthesis and Crystal and Molecular Structures of 1,3-Di-p-tolyl-5-(5'-allyl 2'-ethoxybenzyl)-1,3,5-diazaphosphacyclohexane Complexes with Ni(II) and Pt(II) Salts
The reaction of heterocyclic phosphine ligand, 1,3-di- p -tolyl-5-(5'-allyl-2'-ethoxybenzyl)-1,3-diaza-5-diazaphosphacyclohexane (L), containing a functional substituent at phosphorus, with (1,5-cyclooctadiene)dichloroplatinum(II) and nickel(II) chloride gave complexes PtCl 2 L 2 ( I ) and...
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Veröffentlicht in: | Russian journal of coordination chemistry 2022-04, Vol.48 (4), p.189-194 |
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container_title | Russian journal of coordination chemistry |
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creator | Balueva, A. S. Musina, E. I. Baimukhametov, F. Z. Nikonov, G. N. Gubaidullin, A. T. Litvinov, I. A. Karasik, A. A. |
description | The reaction of heterocyclic phosphine ligand, 1,3-di-
p
-tolyl-5-(5'-allyl-2'-ethoxybenzyl)-1,3-diaza-5-diazaphosphacyclohexane (L), containing a functional substituent at phosphorus, with (1,5-cyclooctadiene)dichloroplatinum(II) and nickel(II) chloride gave complexes PtCl
2
L
2
(
I
) and NiCl
2
L
2
(
II
), respectively, with the
cis-
and
trans
-configurations of the central ion. The structure of the complexes was determined by X-ray diffraction (CIF files CCDC no. 2097704 (
I
), 2097705 (
II
)). |
doi_str_mv | 10.1134/S1070328422030010 |
format | Article |
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p
-tolyl-5-(5'-allyl-2'-ethoxybenzyl)-1,3-diaza-5-diazaphosphacyclohexane (L), containing a functional substituent at phosphorus, with (1,5-cyclooctadiene)dichloroplatinum(II) and nickel(II) chloride gave complexes PtCl
2
L
2
(
I
) and NiCl
2
L
2
(
II
), respectively, with the
cis-
and
trans
-configurations of the central ion. The structure of the complexes was determined by X-ray diffraction (CIF files CCDC no. 2097704 (
I
), 2097705 (
II
)).</description><identifier>ISSN: 1070-3284</identifier><identifier>EISSN: 1608-3318</identifier><identifier>DOI: 10.1134/S1070328422030010</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Chemical synthesis ; Chemistry ; Chemistry and Materials Science ; Crystal structure ; Crystals ; Inorganic Chemistry ; Molecular structure ; Phosphines ; Physical Chemistry</subject><ispartof>Russian journal of coordination chemistry, 2022-04, Vol.48 (4), p.189-194</ispartof><rights>Pleiades Publishing, Ltd. 2022. ISSN 1070-3284, Russian Journal of Coordination Chemistry, 2022, Vol. 48, No. 4, pp. 189–194. © Pleiades Publishing, Ltd., 2022. Russian Text © The Author(s), 2022, published in Koordinatsionnaya Khimiya, 2022, Vol. 48, No. 4, pp. 195–199.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c268t-773ec3791da5cd76dd756f833dec90ae5de30db2ae79a89958523bc8af4408733</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1070328422030010$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1070328422030010$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Balueva, A. S.</creatorcontrib><creatorcontrib>Musina, E. I.</creatorcontrib><creatorcontrib>Baimukhametov, F. Z.</creatorcontrib><creatorcontrib>Nikonov, G. N.</creatorcontrib><creatorcontrib>Gubaidullin, A. T.</creatorcontrib><creatorcontrib>Litvinov, I. A.</creatorcontrib><creatorcontrib>Karasik, A. A.</creatorcontrib><title>Synthesis and Crystal and Molecular Structures of 1,3-Di-p-tolyl-5-(5'-allyl 2'-ethoxybenzyl)-1,3,5-diazaphosphacyclohexane Complexes with Ni(II) and Pt(II) Salts</title><title>Russian journal of coordination chemistry</title><addtitle>Russ J Coord Chem</addtitle><description>The reaction of heterocyclic phosphine ligand, 1,3-di-
p
-tolyl-5-(5'-allyl-2'-ethoxybenzyl)-1,3-diaza-5-diazaphosphacyclohexane (L), containing a functional substituent at phosphorus, with (1,5-cyclooctadiene)dichloroplatinum(II) and nickel(II) chloride gave complexes PtCl
2
L
2
(
I
) and NiCl
2
L
2
(
II
), respectively, with the
cis-
and
trans
-configurations of the central ion. The structure of the complexes was determined by X-ray diffraction (CIF files CCDC no. 2097704 (
I
), 2097705 (
II
)).</description><subject>Chemical synthesis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Crystal structure</subject><subject>Crystals</subject><subject>Inorganic Chemistry</subject><subject>Molecular structure</subject><subject>Phosphines</subject><subject>Physical Chemistry</subject><issn>1070-3284</issn><issn>1608-3318</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp1kUtr3DAUhU1JoZO0P6A7QxZJIEr1sCx5WSavgekDJlkbjXRdOyiWK8lknJ_TX1rNTCCLkNU9cL9zzuJk2VeCLwhhxbcVwQIzKgtKMcOY4A_ZjJRYIsaIPEg6vdH2_yk7DOFhS2BezbJ_q6mPLYQu5Ko3-dxPISq70z-cBT1a5fNV9KOOo4eQuyYn5wxddmhA0dnJIo5O-QlSNumcniCIrdtMa-ifJ3uGEnvOkenUsxpaF4ZW6Ulb18JG9ZDP3eNgYZNin7rY5j-708XibNf9O-7kStkYPmcfG2UDfHm5R9n99dXd_BYtf90s5t-XSNNSRiQEA81ERYzi2ojSGMHLRjJmQFdYATfAsFlTBaJSsqq45JSttVRNUWApGDvKjve5g3d_RwixfnCj71NlTcuiEnRrShTZU9q7EDw09eC7R-WnmuB6O0X9ZorkoXtPSGz_B_xr8vum_4KkiW4</recordid><startdate>20220401</startdate><enddate>20220401</enddate><creator>Balueva, A. S.</creator><creator>Musina, E. I.</creator><creator>Baimukhametov, F. Z.</creator><creator>Nikonov, G. N.</creator><creator>Gubaidullin, A. T.</creator><creator>Litvinov, I. A.</creator><creator>Karasik, A. A.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20220401</creationdate><title>Synthesis and Crystal and Molecular Structures of 1,3-Di-p-tolyl-5-(5'-allyl 2'-ethoxybenzyl)-1,3,5-diazaphosphacyclohexane Complexes with Ni(II) and Pt(II) Salts</title><author>Balueva, A. S. ; Musina, E. I. ; Baimukhametov, F. Z. ; Nikonov, G. N. ; Gubaidullin, A. T. ; Litvinov, I. A. ; Karasik, A. A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c268t-773ec3791da5cd76dd756f833dec90ae5de30db2ae79a89958523bc8af4408733</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Chemical synthesis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Crystal structure</topic><topic>Crystals</topic><topic>Inorganic Chemistry</topic><topic>Molecular structure</topic><topic>Phosphines</topic><topic>Physical Chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Balueva, A. S.</creatorcontrib><creatorcontrib>Musina, E. I.</creatorcontrib><creatorcontrib>Baimukhametov, F. Z.</creatorcontrib><creatorcontrib>Nikonov, G. N.</creatorcontrib><creatorcontrib>Gubaidullin, A. T.</creatorcontrib><creatorcontrib>Litvinov, I. A.</creatorcontrib><creatorcontrib>Karasik, A. A.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of coordination chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Balueva, A. S.</au><au>Musina, E. I.</au><au>Baimukhametov, F. Z.</au><au>Nikonov, G. N.</au><au>Gubaidullin, A. T.</au><au>Litvinov, I. A.</au><au>Karasik, A. A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and Crystal and Molecular Structures of 1,3-Di-p-tolyl-5-(5'-allyl 2'-ethoxybenzyl)-1,3,5-diazaphosphacyclohexane Complexes with Ni(II) and Pt(II) Salts</atitle><jtitle>Russian journal of coordination chemistry</jtitle><stitle>Russ J Coord Chem</stitle><date>2022-04-01</date><risdate>2022</risdate><volume>48</volume><issue>4</issue><spage>189</spage><epage>194</epage><pages>189-194</pages><issn>1070-3284</issn><eissn>1608-3318</eissn><abstract>The reaction of heterocyclic phosphine ligand, 1,3-di-
p
-tolyl-5-(5'-allyl-2'-ethoxybenzyl)-1,3-diaza-5-diazaphosphacyclohexane (L), containing a functional substituent at phosphorus, with (1,5-cyclooctadiene)dichloroplatinum(II) and nickel(II) chloride gave complexes PtCl
2
L
2
(
I
) and NiCl
2
L
2
(
II
), respectively, with the
cis-
and
trans
-configurations of the central ion. The structure of the complexes was determined by X-ray diffraction (CIF files CCDC no. 2097704 (
I
), 2097705 (
II
)).</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1070328422030010</doi><tpages>6</tpages></addata></record> |
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language | eng |
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subjects | Chemical synthesis Chemistry Chemistry and Materials Science Crystal structure Crystals Inorganic Chemistry Molecular structure Phosphines Physical Chemistry |
title | Synthesis and Crystal and Molecular Structures of 1,3-Di-p-tolyl-5-(5'-allyl 2'-ethoxybenzyl)-1,3,5-diazaphosphacyclohexane Complexes with Ni(II) and Pt(II) Salts |
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