Isolation and structural characterization of stable carbamic–carbonic anhydrides: an experimental and computational study

Carbamic–carbonic anhydrides are elusive species that have been only indirectly detected under controlled conditions. This functional group is transiently formed during the reaction of secondary amines with anhydrides in the presence of nucleophilic catalysts such as 4-(dimethylamino)pyridine. In th...

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Veröffentlicht in:	Organic Chemistry Frontiers 2022-04, Vol.9 (8), p.2154-2163
Hauptverfasser:	Sampaio-Dias, Ivo E., Sousa, Carlos A. D., Silva-Reis, Sara C., Pinto da Sílva, Luís, García-Mera, Xerardo, Rodríguez-Borges, José E.
Format:	Artikel
Sprache:	eng
Schlagworte:	Amines Anhydrides Catalysts Computer applications Controlled conditions Decarboxylation Functional groups NMR Nuclear magnetic resonance Orbital stability Organic chemistry Structural analysis Thermal analysis
Online-Zugang:	Volltext
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