Emerging phase change cold storage materials derived from sodium sulfate decahydrate
Emerging phase change cold storage materials derived from sodium sulfate decahydrate (SSD, Na2SO4·10H2O) were successfully prepared for the cold chain transportation (2–8 °C). Their phase transition temperatures were reduced by the addition of cooling agents (KCl and NH4Cl), meanwhile, their phase s...
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| Veröffentlicht in: | Energy (Oxford) 2022-04, Vol.245, p.123294, Article 123294 |
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| creator | Lin, Niangzhi Li, Chuanchang Zhang, Dongyao Li, Yaxi Chen, Jian |
| description | Emerging phase change cold storage materials derived from sodium sulfate decahydrate (SSD, Na2SO4·10H2O) were successfully prepared for the cold chain transportation (2–8 °C). Their phase transition temperatures were reduced by the addition of cooling agents (KCl and NH4Cl), meanwhile, their phase separation and supercooling were successfully inhibited by adding both carboxymethyl cellulose (CMC) and borax (B). The microstructure and chemical structure analyses of the composites showed that the resulting materials had good chemical compatibility. The preferred composite (SSD-BCKN3) with virtually no phase separation had a phase transition temperature at 6.8 °C, which had the latent heat of 97.05 J g−1 for melting, and its supercooling degree was 0.7 °C. The thermal conductivity of SSD-BCKN3 was 0.264 W m−1 k−1. Cooling experiments and fruit storage performance experiments showed that SSD-BCKN3 has good potential for energy storage in cold chain transportation applications.
•Multi-composite phase change cold storage materials were prepared.•The effect of the additives on the properties of the composites was studied.•Test proved the potential of composites for cold chain transport applications. |
| doi_str_mv | 10.1016/j.energy.2022.123294 |
| format | Article |
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•Multi-composite phase change cold storage materials were prepared.•The effect of the additives on the properties of the composites was studied.•Test proved the potential of composites for cold chain transport applications.</description><identifier>ISSN: 0360-5442</identifier><identifier>EISSN: 1873-6785</identifier><identifier>DOI: 10.1016/j.energy.2022.123294</identifier><language>eng</language><publisher>Oxford: Elsevier Ltd</publisher><subject>Ammonium chloride ; Borax ; Carboxymethyl cellulose ; Carboxymethylcellulose ; Cellulose ; Chemical compatibility ; Cold energy storage ; Cold storage ; Cooling ; Energy storage ; Fruit preservation test ; Latent heat ; Phase change ; Phase change materials ; Phase separation ; Phase transitions ; Potassium chloride ; Reagents ; Sodium sulfate ; Sodium sulfate decahydrate ; Sulfates ; Supercooling ; Thermal conductivity ; Transition temperature ; Transition temperatures ; Transportation applications</subject><ispartof>Energy (Oxford), 2022-04, Vol.245, p.123294, Article 123294</ispartof><rights>2022 Elsevier Ltd</rights><rights>Copyright Elsevier BV Apr 15, 2022</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c334t-e3f9f661ee02466dde369c0101a69fbf8c9c1f22f350d7b09c160b92342c41493</citedby><cites>FETCH-LOGICAL-c334t-e3f9f661ee02466dde369c0101a69fbf8c9c1f22f350d7b09c160b92342c41493</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.energy.2022.123294$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3548,27922,27923,45993</link.rule.ids></links><search><creatorcontrib>Lin, Niangzhi</creatorcontrib><creatorcontrib>Li, Chuanchang</creatorcontrib><creatorcontrib>Zhang, Dongyao</creatorcontrib><creatorcontrib>Li, Yaxi</creatorcontrib><creatorcontrib>Chen, Jian</creatorcontrib><title>Emerging phase change cold storage materials derived from sodium sulfate decahydrate</title><title>Energy (Oxford)</title><description>Emerging phase change cold storage materials derived from sodium sulfate decahydrate (SSD, Na2SO4·10H2O) were successfully prepared for the cold chain transportation (2–8 °C). Their phase transition temperatures were reduced by the addition of cooling agents (KCl and NH4Cl), meanwhile, their phase separation and supercooling were successfully inhibited by adding both carboxymethyl cellulose (CMC) and borax (B). The microstructure and chemical structure analyses of the composites showed that the resulting materials had good chemical compatibility. The preferred composite (SSD-BCKN3) with virtually no phase separation had a phase transition temperature at 6.8 °C, which had the latent heat of 97.05 J g−1 for melting, and its supercooling degree was 0.7 °C. The thermal conductivity of SSD-BCKN3 was 0.264 W m−1 k−1. Cooling experiments and fruit storage performance experiments showed that SSD-BCKN3 has good potential for energy storage in cold chain transportation applications.
•Multi-composite phase change cold storage materials were prepared.•The effect of the additives on the properties of the composites was studied.•Test proved the potential of composites for cold chain transport applications.</description><subject>Ammonium chloride</subject><subject>Borax</subject><subject>Carboxymethyl cellulose</subject><subject>Carboxymethylcellulose</subject><subject>Cellulose</subject><subject>Chemical compatibility</subject><subject>Cold energy storage</subject><subject>Cold storage</subject><subject>Cooling</subject><subject>Energy storage</subject><subject>Fruit preservation test</subject><subject>Latent heat</subject><subject>Phase change</subject><subject>Phase change materials</subject><subject>Phase separation</subject><subject>Phase transitions</subject><subject>Potassium chloride</subject><subject>Reagents</subject><subject>Sodium sulfate</subject><subject>Sodium sulfate decahydrate</subject><subject>Sulfates</subject><subject>Supercooling</subject><subject>Thermal conductivity</subject><subject>Transition temperature</subject><subject>Transition temperatures</subject><subject>Transportation applications</subject><issn>0360-5442</issn><issn>1873-6785</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp9UMtqwzAQFKWFpmn_oAdDz071smxdCiWkDwj0kp6FIq0SmdhKJTuQv6-Ce-5pdtmZWWYQeiR4QTARz-0Ceoi784JiSheEMir5FZqRpmalqJvqGs0wE7isOKe36C6lFmNcNVLO0GbVZaXvd8VxrxMUZq_7XYZwsEUaQtR56fQA0etDKmzGE9jCxdAVKVg_ZhgPLhPyzej92cY836Mbl-nw8Idz9P222iw_yvXX--fydV0axvhQAnPSCUEAMOVCWAtMSINzJC2k27rGSEMcpY5V2NZbnDeBt5IyTg0nXLI5epp8jzH8jJAG1YYx9vmlooI3AteE15nFJ5aJIaUITh2j73Q8K4LVpT_Vqqk_delPTf1l2cskg5zg5CGqZDz0BqyPYAZlg__f4Bex93sR</recordid><startdate>20220415</startdate><enddate>20220415</enddate><creator>Lin, Niangzhi</creator><creator>Li, Chuanchang</creator><creator>Zhang, Dongyao</creator><creator>Li, Yaxi</creator><creator>Chen, Jian</creator><general>Elsevier Ltd</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7ST</scope><scope>7TB</scope><scope>8FD</scope><scope>C1K</scope><scope>F28</scope><scope>FR3</scope><scope>KR7</scope><scope>L7M</scope><scope>SOI</scope></search><sort><creationdate>20220415</creationdate><title>Emerging phase change cold storage materials derived from sodium sulfate decahydrate</title><author>Lin, Niangzhi ; Li, Chuanchang ; Zhang, Dongyao ; Li, Yaxi ; Chen, Jian</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c334t-e3f9f661ee02466dde369c0101a69fbf8c9c1f22f350d7b09c160b92342c41493</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Ammonium chloride</topic><topic>Borax</topic><topic>Carboxymethyl cellulose</topic><topic>Carboxymethylcellulose</topic><topic>Cellulose</topic><topic>Chemical compatibility</topic><topic>Cold energy storage</topic><topic>Cold storage</topic><topic>Cooling</topic><topic>Energy storage</topic><topic>Fruit preservation test</topic><topic>Latent heat</topic><topic>Phase change</topic><topic>Phase change materials</topic><topic>Phase separation</topic><topic>Phase transitions</topic><topic>Potassium chloride</topic><topic>Reagents</topic><topic>Sodium sulfate</topic><topic>Sodium sulfate decahydrate</topic><topic>Sulfates</topic><topic>Supercooling</topic><topic>Thermal conductivity</topic><topic>Transition temperature</topic><topic>Transition temperatures</topic><topic>Transportation applications</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lin, Niangzhi</creatorcontrib><creatorcontrib>Li, Chuanchang</creatorcontrib><creatorcontrib>Zhang, Dongyao</creatorcontrib><creatorcontrib>Li, Yaxi</creatorcontrib><creatorcontrib>Chen, Jian</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Environment Abstracts</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Environment Abstracts</collection><jtitle>Energy (Oxford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lin, Niangzhi</au><au>Li, Chuanchang</au><au>Zhang, Dongyao</au><au>Li, Yaxi</au><au>Chen, Jian</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Emerging phase change cold storage materials derived from sodium sulfate decahydrate</atitle><jtitle>Energy (Oxford)</jtitle><date>2022-04-15</date><risdate>2022</risdate><volume>245</volume><spage>123294</spage><pages>123294-</pages><artnum>123294</artnum><issn>0360-5442</issn><eissn>1873-6785</eissn><abstract>Emerging phase change cold storage materials derived from sodium sulfate decahydrate (SSD, Na2SO4·10H2O) were successfully prepared for the cold chain transportation (2–8 °C). Their phase transition temperatures were reduced by the addition of cooling agents (KCl and NH4Cl), meanwhile, their phase separation and supercooling were successfully inhibited by adding both carboxymethyl cellulose (CMC) and borax (B). The microstructure and chemical structure analyses of the composites showed that the resulting materials had good chemical compatibility. The preferred composite (SSD-BCKN3) with virtually no phase separation had a phase transition temperature at 6.8 °C, which had the latent heat of 97.05 J g−1 for melting, and its supercooling degree was 0.7 °C. The thermal conductivity of SSD-BCKN3 was 0.264 W m−1 k−1. Cooling experiments and fruit storage performance experiments showed that SSD-BCKN3 has good potential for energy storage in cold chain transportation applications.
•Multi-composite phase change cold storage materials were prepared.•The effect of the additives on the properties of the composites was studied.•Test proved the potential of composites for cold chain transport applications.</abstract><cop>Oxford</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.energy.2022.123294</doi></addata></record> |
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| source | ScienceDirect Journals (5 years ago - present) |
| subjects | Ammonium chloride Borax Carboxymethyl cellulose Carboxymethylcellulose Cellulose Chemical compatibility Cold energy storage Cold storage Cooling Energy storage Fruit preservation test Latent heat Phase change Phase change materials Phase separation Phase transitions Potassium chloride Reagents Sodium sulfate Sodium sulfate decahydrate Sulfates Supercooling Thermal conductivity Transition temperature Transition temperatures Transportation applications |
| title | Emerging phase change cold storage materials derived from sodium sulfate decahydrate |
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