Coordination Chemistry of Borane in Solution: Application to a STING Agonist

Equilibrium constants were determined for ligand exchange reactions of borane complexes with various oxygen, sulfur, nitrogen, and phosphorus nucleophiles in solution, and a binding affinity scale was built spanning a range of 12 orders of magnitude. While the Keq are minimally dependent on the solv...

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Veröffentlicht in:	European journal of organic chemistry 2022-04, Vol.2022 (13), p.n/a
Hauptverfasser:	Zhdanko, Alexander, Worp, Boris A., Lemaire, Sébastien
Format:	Artikel
Sprache:	eng
Schlagworte:	Affinity Binding Boranes Chemical equilibrium Kinetics Lewis bases Ligands Nucleophiles Nucleosides Phosphane ligands Protonation Substrates Thermodynamics
Online-Zugang:	Volltext
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