Regulating the proton conductivity of metal organic framework materials through solvent control

In order to study the influence of different solvent molecules on the proton conductivities of MOFs, {[Zn(pyeb) 2 ](DMF)(H 2 O)} n (1) (PyebH = 4-[2-(4-pyridyl)vinyl)]-benzoic acid, DMF denotes N , N ′-dimethylformamide) was selected and synthesized due to different solvent molecules in the crystal...

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Veröffentlicht in:New journal of chemistry 2022-04, Vol.46 (14), p.6657-6662
Hauptverfasser: Wang, Xinxin, Wang, Fengdong, Zhang, Chenxi, Wang, Qinglun
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Wang, Fengdong
Zhang, Chenxi
Wang, Qinglun
description In order to study the influence of different solvent molecules on the proton conductivities of MOFs, {[Zn(pyeb) 2 ](DMF)(H 2 O)} n (1) (PyebH = 4-[2-(4-pyridyl)vinyl)]-benzoic acid, DMF denotes N , N ′-dimethylformamide) was selected and synthesized due to different solvent molecules in the crystal structure. It possesses a 3D rhombic framework and exhibits outstanding thermal stabilities. In order to study the relationship between the different solvent molecules and proton conductivity properties, on the basis of MOF 1, three MOFs with different solvent molecules were obtained by introducing acetonitrile, acetone and DMF, denoted as {[Zn(pyeb) 2 ](MeCN)} n (2), {[Zn(pyeb) 2 ](Me 2 CO)} n (3), and {[Zn(pyeb) 2 ](DMF)} n (4). Through further research, it is found that the proton conductivities of the four MOFs are closely related to the solvent guest molecules in the pores, indicating that the change of solvent molecules can regulate the proton conductivity. This research work has certain significance in the detection of solvents by electrochemical probes.
doi_str_mv 10.1039/D2NJ00342B
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It possesses a 3D rhombic framework and exhibits outstanding thermal stabilities. In order to study the relationship between the different solvent molecules and proton conductivity properties, on the basis of MOF 1, three MOFs with different solvent molecules were obtained by introducing acetonitrile, acetone and DMF, denoted as {[Zn(pyeb) 2 ](MeCN)} n (2), {[Zn(pyeb) 2 ](Me 2 CO)} n (3), and {[Zn(pyeb) 2 ](DMF)} n (4). Through further research, it is found that the proton conductivities of the four MOFs are closely related to the solvent guest molecules in the pores, indicating that the change of solvent molecules can regulate the proton conductivity. 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It possesses a 3D rhombic framework and exhibits outstanding thermal stabilities. In order to study the relationship between the different solvent molecules and proton conductivity properties, on the basis of MOF 1, three MOFs with different solvent molecules were obtained by introducing acetonitrile, acetone and DMF, denoted as {[Zn(pyeb) 2 ](MeCN)} n (2), {[Zn(pyeb) 2 ](Me 2 CO)} n (3), and {[Zn(pyeb) 2 ](DMF)} n (4). Through further research, it is found that the proton conductivities of the four MOFs are closely related to the solvent guest molecules in the pores, indicating that the change of solvent molecules can regulate the proton conductivity. This research work has certain significance in the detection of solvents by electrochemical probes.</description><subject>Acetonitrile</subject><subject>Benzoic acid</subject><subject>Chemical synthesis</subject><subject>Conductivity</subject><subject>Crystal structure</subject><subject>Dimethylformamide</subject><subject>Electrons</subject><subject>Metal-organic frameworks</subject><subject>Molecular structure</subject><subject>Protons</subject><subject>Solvents</subject><issn>1144-0546</issn><issn>1369-9261</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNpFUMtOwzAQtBBIlMKFL7DEDSngR-zURyhvVSAhOFuOs05TkrjYTlH_nlRF4rQj7ezM7CB0TskVJVxd37HXF0J4zm4P0IRyqTLFJD0cMc3zjIhcHqOTGFeEUFpIOkH6HeqhNanpa5yWgNfBJ99j6_tqsKnZNGmLvcMdJNNiH2rTNxa7YDr48eELdyZBaEwbx-Pgh3qJo2830KedQgq-PUVHblzD2d-cos-H-4_5U7Z4e3ye3ywyy4RKmanA8hKMKEpwRMwsYWN46wyRspRMgC1lXinqShC8VNQSK4xwthCysAokn6KLve74wPcAMemVH0I_WmomczkrqCjEyLrcs2zwMQZweh2azoStpkTvCtT_BfJfQZBlkA</recordid><startdate>20220405</startdate><enddate>20220405</enddate><creator>Wang, Xinxin</creator><creator>Wang, Fengdong</creator><creator>Zhang, Chenxi</creator><creator>Wang, Qinglun</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>H9R</scope><scope>JG9</scope><scope>KA0</scope><orcidid>https://orcid.org/0000-0002-0983-6280</orcidid><orcidid>https://orcid.org/0000-0003-3383-9112</orcidid></search><sort><creationdate>20220405</creationdate><title>Regulating the proton conductivity of metal organic framework materials through solvent control</title><author>Wang, Xinxin ; Wang, Fengdong ; Zhang, Chenxi ; Wang, Qinglun</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c259t-adec3bea57bef058c02369cfa066b625ecb64d91fbe53b91c0c5a5fc7567c9e63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Acetonitrile</topic><topic>Benzoic acid</topic><topic>Chemical synthesis</topic><topic>Conductivity</topic><topic>Crystal structure</topic><topic>Dimethylformamide</topic><topic>Electrons</topic><topic>Metal-organic frameworks</topic><topic>Molecular structure</topic><topic>Protons</topic><topic>Solvents</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wang, Xinxin</creatorcontrib><creatorcontrib>Wang, Fengdong</creatorcontrib><creatorcontrib>Zhang, Chenxi</creatorcontrib><creatorcontrib>Wang, Qinglun</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Illustrata: Natural Sciences</collection><collection>Materials Research Database</collection><collection>ProQuest Illustrata: Technology Collection</collection><jtitle>New journal of chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wang, Xinxin</au><au>Wang, Fengdong</au><au>Zhang, Chenxi</au><au>Wang, Qinglun</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Regulating the proton conductivity of metal organic framework materials through solvent control</atitle><jtitle>New journal of chemistry</jtitle><date>2022-04-05</date><risdate>2022</risdate><volume>46</volume><issue>14</issue><spage>6657</spage><epage>6662</epage><pages>6657-6662</pages><issn>1144-0546</issn><eissn>1369-9261</eissn><abstract>In order to study the influence of different solvent molecules on the proton conductivities of MOFs, {[Zn(pyeb) 2 ](DMF)(H 2 O)} n (1) (PyebH = 4-[2-(4-pyridyl)vinyl)]-benzoic acid, DMF denotes N , N ′-dimethylformamide) was selected and synthesized due to different solvent molecules in the crystal structure. 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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Acetonitrile
Benzoic acid
Chemical synthesis
Conductivity
Crystal structure
Dimethylformamide
Electrons
Metal-organic frameworks
Molecular structure
Protons
Solvents
title Regulating the proton conductivity of metal organic framework materials through solvent control
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