Stereoselective cyclopropanation of enamides via C–C bond cleavage of cyclopropenes

This work describes a straightforward protocol for the stereoselective synthesis of vinylcyclopropylamides in high E / Z and syn / anti ratios by cyclopropanation of N -tosyl substituted enamides with cyclopropenes in the presence of a rhodium catalyst under very mild reaction conditions. The obtain...

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Veröffentlicht in:	Organic Chemistry Frontiers 2022-03, Vol.9 (7), p.1820-1825
Hauptverfasser:	Chen, Jie, Han, Jiabin, Wu, Tao, Zhang, Jian, Li, Meng, Xu, Ying, Zhang, Jinli, Jiao, Yongjuan, Yang, Yanhui, Jiang, Yaojia
Format:	Artikel
Sprache:	eng
Schlagworte:	Aldehydes Antibacterial activity Catalysts Covalent bonds Organic chemistry Organic compounds Rhodium Ring opening Stereoselectivity
Online-Zugang:	Volltext
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