Gold nanoparticle-catalysed functionalization of carbon-hydrogen bonds by carbene transfer reactions

Gold nanoparticles stabilized by NHC ligands and supported onto reduced graphene oxide (rGO) catalyse the functionalization of cyclohexane and benzene C-H bonds upon insertion of carbene CHCO 2 Et (from N 2 &z.dbd;CHCO 2 Et) groups. This is the first example in which such C sp3 -H or C sp2 -H bo...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2022-03, Vol.51 (13), p.525-5256
Hauptverfasser:	Martínez-Laguna, Jonathan, Mollar-Cuni, Andrés, Ventura-Espinosa, David, Martín, Santiago, Caballero, Ana, Mata, Jose A, Pérez, Pedro J
Format:	Artikel
Sprache:	eng
Schlagworte:	Benzene Carbenes Cyclohexane Gold Graphene Hydrogen bonds Nanoparticles Recyclability
Online-Zugang:	Volltext
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