Synthesis of a cellulose dissolving liquid zwitterion from general and low-cost reagents
A carboxylate-type liquid zwitterion, OE 2 imC 3 C, has been recently reported as a unique solvent as a class of ionic liquids with distinctive properties and functions such as cellulose dissolution ability and low toxicity to fermentative microoganisms. Therefore, OE 2 imC 3 C first enabled success...
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| Veröffentlicht in: | Cellulose (London) 2022-03, Vol.29 (5), p.3017-3024 |
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| container_title | Cellulose (London) |
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| creator | Sharma, Gyanendra Kato, Yui Hachisu, Ayumi Ishibashi, Kojiro Ninomiya, Kazuaki Takahashi, Kenji Hirata, Eishu Kuroda, Kosuke |
| description | A carboxylate-type liquid zwitterion, OE
2
imC
3
C, has been recently reported as a unique solvent as a class of ionic liquids with distinctive properties and functions such as cellulose dissolution ability and low toxicity to fermentative microoganisms. Therefore, OE
2
imC
3
C first enabled successive conversion of biomass to bioethanol in the same reaction pot. However, the reagent, 1-bromo-2-(2-methoxyethoxy)ethane, used for OE
2
imC
3
C synthesis is expensive and sometimes out of production and thus prevents its industrialization. Here we synthesized OE
2
imC
3
C from general and low-cost reagents. We also confirmed that the present OE
2
imC
3
C maintained the distinctive properties and functions because previous literature indicates synthetic procedures affect the properties. The low toxicity and cellulose dissolution ability of the OE
2
imC
3
C synthesized in this study were equivalent to those of conventional OE
2
imC
3
C. In addition, OE
2
imC
3
C is known to have ability to cryopreserve mammalian cells and the OE
2
imC
3
C synthesized in this study exhibited the ability. |
| doi_str_mv | 10.1007/s10570-021-04185-y |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2644218847</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2644218847</sourcerecordid><originalsourceid>FETCH-LOGICAL-c385t-2313883ab00bada72b014c87e4cd65527e738da29f3f0471a1bdfebd9f54be5d3</originalsourceid><addsrcrecordid>eNp9kE1LAzEURYMoWKt_wFXAdTSfTWYpxS8ouFChu5CZJDUlnbTJjGX89Y5WcOfqwXvn3gcHgEuCrwnG8qYQLCRGmBKEOVECDUdgQoSkSCm6PAYTXM2q8cyqU3BWyhpjXElKJmD5MrTduyuhwOShgY2LsY-pOGhDKSl-hHYFY9j1wcLPfeg6l0Nqoc9pA1euddlEaFoLY9qjJpUOZmfGfVfOwYk3sbiL3zkFb_d3r_NHtHh-eJrfLlDDlOgQZYQpxUyNcW2skbTGhDdKOt7YmRBUOsmUNbTyzGMuiSG19a62lRe8dsKyKbg69G5z2vWudHqd-tyOLzWdcU6JUlyOFD1QTU6lZOf1NoeNyYMmWH8b1AeDejSofwzqYQyxQ6iMcLty-a_6n9QXG8N2Dw</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2644218847</pqid></control><display><type>article</type><title>Synthesis of a cellulose dissolving liquid zwitterion from general and low-cost reagents</title><source>SpringerLink Journals - AutoHoldings</source><creator>Sharma, Gyanendra ; Kato, Yui ; Hachisu, Ayumi ; Ishibashi, Kojiro ; Ninomiya, Kazuaki ; Takahashi, Kenji ; Hirata, Eishu ; Kuroda, Kosuke</creator><creatorcontrib>Sharma, Gyanendra ; Kato, Yui ; Hachisu, Ayumi ; Ishibashi, Kojiro ; Ninomiya, Kazuaki ; Takahashi, Kenji ; Hirata, Eishu ; Kuroda, Kosuke</creatorcontrib><description>A carboxylate-type liquid zwitterion, OE
2
imC
3
C, has been recently reported as a unique solvent as a class of ionic liquids with distinctive properties and functions such as cellulose dissolution ability and low toxicity to fermentative microoganisms. Therefore, OE
2
imC
3
C first enabled successive conversion of biomass to bioethanol in the same reaction pot. However, the reagent, 1-bromo-2-(2-methoxyethoxy)ethane, used for OE
2
imC
3
C synthesis is expensive and sometimes out of production and thus prevents its industrialization. Here we synthesized OE
2
imC
3
C from general and low-cost reagents. We also confirmed that the present OE
2
imC
3
C maintained the distinctive properties and functions because previous literature indicates synthetic procedures affect the properties. The low toxicity and cellulose dissolution ability of the OE
2
imC
3
C synthesized in this study were equivalent to those of conventional OE
2
imC
3
C. In addition, OE
2
imC
3
C is known to have ability to cryopreserve mammalian cells and the OE
2
imC
3
C synthesized in this study exhibited the ability.</description><identifier>ISSN: 0969-0239</identifier><identifier>EISSN: 1572-882X</identifier><identifier>DOI: 10.1007/s10570-021-04185-y</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Biofuels ; Bioorganic Chemistry ; Cellulose ; Ceramics ; Chemistry ; Chemistry and Materials Science ; Composites ; Dissolution ; Ethane ; Glass ; Ionic liquids ; Ions ; Low cost ; Natural Materials ; Organic Chemistry ; Physical Chemistry ; Polymer Sciences ; Reagents ; Sustainable Development ; Toxicity ; Zwitterions</subject><ispartof>Cellulose (London), 2022-03, Vol.29 (5), p.3017-3024</ispartof><rights>The Author(s), under exclusive licence to Springer Nature B.V. 2021</rights><rights>The Author(s), under exclusive licence to Springer Nature B.V. 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c385t-2313883ab00bada72b014c87e4cd65527e738da29f3f0471a1bdfebd9f54be5d3</citedby><cites>FETCH-LOGICAL-c385t-2313883ab00bada72b014c87e4cd65527e738da29f3f0471a1bdfebd9f54be5d3</cites><orcidid>0000-0003-3735-135X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10570-021-04185-y$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10570-021-04185-y$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51297</link.rule.ids></links><search><creatorcontrib>Sharma, Gyanendra</creatorcontrib><creatorcontrib>Kato, Yui</creatorcontrib><creatorcontrib>Hachisu, Ayumi</creatorcontrib><creatorcontrib>Ishibashi, Kojiro</creatorcontrib><creatorcontrib>Ninomiya, Kazuaki</creatorcontrib><creatorcontrib>Takahashi, Kenji</creatorcontrib><creatorcontrib>Hirata, Eishu</creatorcontrib><creatorcontrib>Kuroda, Kosuke</creatorcontrib><title>Synthesis of a cellulose dissolving liquid zwitterion from general and low-cost reagents</title><title>Cellulose (London)</title><addtitle>Cellulose</addtitle><description>A carboxylate-type liquid zwitterion, OE
2
imC
3
C, has been recently reported as a unique solvent as a class of ionic liquids with distinctive properties and functions such as cellulose dissolution ability and low toxicity to fermentative microoganisms. Therefore, OE
2
imC
3
C first enabled successive conversion of biomass to bioethanol in the same reaction pot. However, the reagent, 1-bromo-2-(2-methoxyethoxy)ethane, used for OE
2
imC
3
C synthesis is expensive and sometimes out of production and thus prevents its industrialization. Here we synthesized OE
2
imC
3
C from general and low-cost reagents. We also confirmed that the present OE
2
imC
3
C maintained the distinctive properties and functions because previous literature indicates synthetic procedures affect the properties. The low toxicity and cellulose dissolution ability of the OE
2
imC
3
C synthesized in this study were equivalent to those of conventional OE
2
imC
3
C. In addition, OE
2
imC
3
C is known to have ability to cryopreserve mammalian cells and the OE
2
imC
3
C synthesized in this study exhibited the ability.</description><subject>Biofuels</subject><subject>Bioorganic Chemistry</subject><subject>Cellulose</subject><subject>Ceramics</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Composites</subject><subject>Dissolution</subject><subject>Ethane</subject><subject>Glass</subject><subject>Ionic liquids</subject><subject>Ions</subject><subject>Low cost</subject><subject>Natural Materials</subject><subject>Organic Chemistry</subject><subject>Physical Chemistry</subject><subject>Polymer Sciences</subject><subject>Reagents</subject><subject>Sustainable Development</subject><subject>Toxicity</subject><subject>Zwitterions</subject><issn>0969-0239</issn><issn>1572-882X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp9kE1LAzEURYMoWKt_wFXAdTSfTWYpxS8ouFChu5CZJDUlnbTJjGX89Y5WcOfqwXvn3gcHgEuCrwnG8qYQLCRGmBKEOVECDUdgQoSkSCm6PAYTXM2q8cyqU3BWyhpjXElKJmD5MrTduyuhwOShgY2LsY-pOGhDKSl-hHYFY9j1wcLPfeg6l0Nqoc9pA1euddlEaFoLY9qjJpUOZmfGfVfOwYk3sbiL3zkFb_d3r_NHtHh-eJrfLlDDlOgQZYQpxUyNcW2skbTGhDdKOt7YmRBUOsmUNbTyzGMuiSG19a62lRe8dsKyKbg69G5z2vWudHqd-tyOLzWdcU6JUlyOFD1QTU6lZOf1NoeNyYMmWH8b1AeDejSofwzqYQyxQ6iMcLty-a_6n9QXG8N2Dw</recordid><startdate>20220301</startdate><enddate>20220301</enddate><creator>Sharma, Gyanendra</creator><creator>Kato, Yui</creator><creator>Hachisu, Ayumi</creator><creator>Ishibashi, Kojiro</creator><creator>Ninomiya, Kazuaki</creator><creator>Takahashi, Kenji</creator><creator>Hirata, Eishu</creator><creator>Kuroda, Kosuke</creator><general>Springer Netherlands</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><orcidid>https://orcid.org/0000-0003-3735-135X</orcidid></search><sort><creationdate>20220301</creationdate><title>Synthesis of a cellulose dissolving liquid zwitterion from general and low-cost reagents</title><author>Sharma, Gyanendra ; Kato, Yui ; Hachisu, Ayumi ; Ishibashi, Kojiro ; Ninomiya, Kazuaki ; Takahashi, Kenji ; Hirata, Eishu ; Kuroda, Kosuke</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c385t-2313883ab00bada72b014c87e4cd65527e738da29f3f0471a1bdfebd9f54be5d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Biofuels</topic><topic>Bioorganic Chemistry</topic><topic>Cellulose</topic><topic>Ceramics</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Composites</topic><topic>Dissolution</topic><topic>Ethane</topic><topic>Glass</topic><topic>Ionic liquids</topic><topic>Ions</topic><topic>Low cost</topic><topic>Natural Materials</topic><topic>Organic Chemistry</topic><topic>Physical Chemistry</topic><topic>Polymer Sciences</topic><topic>Reagents</topic><topic>Sustainable Development</topic><topic>Toxicity</topic><topic>Zwitterions</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sharma, Gyanendra</creatorcontrib><creatorcontrib>Kato, Yui</creatorcontrib><creatorcontrib>Hachisu, Ayumi</creatorcontrib><creatorcontrib>Ishibashi, Kojiro</creatorcontrib><creatorcontrib>Ninomiya, Kazuaki</creatorcontrib><creatorcontrib>Takahashi, Kenji</creatorcontrib><creatorcontrib>Hirata, Eishu</creatorcontrib><creatorcontrib>Kuroda, Kosuke</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Cellulose (London)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sharma, Gyanendra</au><au>Kato, Yui</au><au>Hachisu, Ayumi</au><au>Ishibashi, Kojiro</au><au>Ninomiya, Kazuaki</au><au>Takahashi, Kenji</au><au>Hirata, Eishu</au><au>Kuroda, Kosuke</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of a cellulose dissolving liquid zwitterion from general and low-cost reagents</atitle><jtitle>Cellulose (London)</jtitle><stitle>Cellulose</stitle><date>2022-03-01</date><risdate>2022</risdate><volume>29</volume><issue>5</issue><spage>3017</spage><epage>3024</epage><pages>3017-3024</pages><issn>0969-0239</issn><eissn>1572-882X</eissn><abstract>A carboxylate-type liquid zwitterion, OE
2
imC
3
C, has been recently reported as a unique solvent as a class of ionic liquids with distinctive properties and functions such as cellulose dissolution ability and low toxicity to fermentative microoganisms. Therefore, OE
2
imC
3
C first enabled successive conversion of biomass to bioethanol in the same reaction pot. However, the reagent, 1-bromo-2-(2-methoxyethoxy)ethane, used for OE
2
imC
3
C synthesis is expensive and sometimes out of production and thus prevents its industrialization. Here we synthesized OE
2
imC
3
C from general and low-cost reagents. We also confirmed that the present OE
2
imC
3
C maintained the distinctive properties and functions because previous literature indicates synthetic procedures affect the properties. The low toxicity and cellulose dissolution ability of the OE
2
imC
3
C synthesized in this study were equivalent to those of conventional OE
2
imC
3
C. In addition, OE
2
imC
3
C is known to have ability to cryopreserve mammalian cells and the OE
2
imC
3
C synthesized in this study exhibited the ability.</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s10570-021-04185-y</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0003-3735-135X</orcidid></addata></record> |
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| ispartof | Cellulose (London), 2022-03, Vol.29 (5), p.3017-3024 |
| issn | 0969-0239 1572-882X |
| language | eng |
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| source | SpringerLink Journals - AutoHoldings |
| subjects | Biofuels Bioorganic Chemistry Cellulose Ceramics Chemistry Chemistry and Materials Science Composites Dissolution Ethane Glass Ionic liquids Ions Low cost Natural Materials Organic Chemistry Physical Chemistry Polymer Sciences Reagents Sustainable Development Toxicity Zwitterions |
| title | Synthesis of a cellulose dissolving liquid zwitterion from general and low-cost reagents |
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