Sensitized and Self‐Sensitized Photocatalytic Carbon Dioxide Reduction Under Visible Light with Ruthenium Catalysts Shows Enhancements with More Conjugated Pincer Ligands

A new method to synthesize complexes of the type [(CNC)RuII(NN)L]n+ has been introduced, where CNC is a tridentate pincer composed of two (benz)imidazole derived NHC rings and a pyridyl ring, NN is a bidentate aromatic diimine ligand, L=bromide or acetonitrile, and n=1 or 2. Following this new metho...

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Veröffentlicht in:	European journal of inorganic chemistry 2022-03, Vol.2022 (8), p.n/a
Hauptverfasser:	Das, Sanjit, Nugegoda, Dinesh, Yao, Wenzhi, Qu, Fengrui, Figgins, Matthew T., Lamb, Robert W., Webster, Charles Edwin, Delcamp, Jared H., Papish, Elizabeth T.
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetonitrile Carbene ligands Carbon Dioxide Catalysts Chemical reduction Crystallography Diimide Electrochemical analysis Imidazole Inorganic chemistry Ligands Photocatalysis Pincer ligands Ruthenium Synthesis
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