Ignition of Boron-Containing High-Energy Materials Based on an Oxidizer and Polymer Binder
The use of aluminum borides is a promising direction in the development of modern propellant compositions and aerial vehicles. We present experimental data on the kinetics of oxidation of microscale powders of aluminum, amorphous boron, and the aluminum borides AlB 2 and AlB 12 in air upon heating a...
Gespeichert in:
| Veröffentlicht in: | Technical physics 2021-07, Vol.66 (7), p.895-901 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 901 |
|---|---|
| container_issue | 7 |
| container_start_page | 895 |
| container_title | Technical physics |
| container_volume | 66 |
| creator | Korotkikh, A. G. Sorokin, I. V. Slyusarskiy, K. V. Arkhipov, V. A. |
| description | The use of aluminum borides is a promising direction in the development of modern propellant compositions and aerial vehicles. We present experimental data on the kinetics of oxidation of microscale powders of aluminum, amorphous boron, and the aluminum borides AlB
2
and AlB
12
in air upon heating at a constant rate of 10°C/min and the results of laser-assisted ignition of high-energy materials that contain these metal powders and are based on ammonium perchlorate, ammonium nitrate, and an inert binder or an energetic combustible binder. We show that the use of the boron-containing powders enables us to lower the onset temperature of oxidation and the temperature of intense oxidation, while increasing their oxidation effectiveness, compared to pure aluminum. The dependences of ignition delay time on the heat flux show that the AlB
2
and AlB
12
powders are the most effective metal fuel components for solid propellants based on ammonium perchlorate, ammonium nitrate, and an energetic binder: they display the shortest ignition delay time and require the lowest heat input for ignition. |
| doi_str_mv | 10.1134/S1063784221060104 |
| format | Article |
| fullrecord | <record><control><sourceid>gale_proqu</sourceid><recordid>TN_cdi_proquest_journals_2641051653</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><galeid>A697623613</galeid><sourcerecordid>A697623613</sourcerecordid><originalsourceid>FETCH-LOGICAL-c313t-34d13afbe5db74d507a628348d7c4fb790680c9d2c8338e285e2a0681dede193</originalsourceid><addsrcrecordid>eNp1kVFLwzAQx4soOKcfwLeCz525pE3Tx21MN5hMcE--lKy51owtmUkHzk9vyoQhKnnIn8vvdxe4KLoFMgBg6f0LEM5ykVIaAgGSnkU9IAVJeEaz8y5zlnTvl9GV92tCAETGe9HrrDG61dbEto5H1lmTjK1ppTbaNPFUN2_JxKBrDvGTbNFpufHxSHpUcVCkiRcfWulPdCGr-NluDtuQR9oodNfRRR1wvPm--9HyYbIcT5P54nE2Hs6TigFrE5YqYLJeYaZWeaoykktOBUuFyqu0XuUF4YJUhaKVYEwgFRlSGWqgUCEUrB_dHdvunH3fo2_Ltd07EyaWlKdAMuAZO1GN3GCpTW1bJ6ut9lU55EXOKePQUYM_qHAUbnVlDdY61H8IcBQqZ713WJc7p7fSHUogZbeY8tdigkOPjg-sadCdPvy_9AV9a4x-</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2641051653</pqid></control><display><type>article</type><title>Ignition of Boron-Containing High-Energy Materials Based on an Oxidizer and Polymer Binder</title><source>SpringerNature Journals</source><creator>Korotkikh, A. G. ; Sorokin, I. V. ; Slyusarskiy, K. V. ; Arkhipov, V. A.</creator><creatorcontrib>Korotkikh, A. G. ; Sorokin, I. V. ; Slyusarskiy, K. V. ; Arkhipov, V. A.</creatorcontrib><description>The use of aluminum borides is a promising direction in the development of modern propellant compositions and aerial vehicles. We present experimental data on the kinetics of oxidation of microscale powders of aluminum, amorphous boron, and the aluminum borides AlB
2
and AlB
12
in air upon heating at a constant rate of 10°C/min and the results of laser-assisted ignition of high-energy materials that contain these metal powders and are based on ammonium perchlorate, ammonium nitrate, and an inert binder or an energetic combustible binder. We show that the use of the boron-containing powders enables us to lower the onset temperature of oxidation and the temperature of intense oxidation, while increasing their oxidation effectiveness, compared to pure aluminum. The dependences of ignition delay time on the heat flux show that the AlB
2
and AlB
12
powders are the most effective metal fuel components for solid propellants based on ammonium perchlorate, ammonium nitrate, and an energetic binder: they display the shortest ignition delay time and require the lowest heat input for ignition.</description><identifier>ISSN: 1063-7842</identifier><identifier>EISSN: 1090-6525</identifier><identifier>DOI: 10.1134/S1063784221060104</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Aluminum ; Ammonium compounds ; Ammonium nitrate ; Ammonium paratungstate ; Ammonium perchlorates ; Borides ; Boron ; Classical and Continuum Physics ; Delay time ; Flammability ; Heat flux ; Ignition ; Metal fuels ; Metal powder products ; Metal powders ; Oxidation ; Oxidizing agents ; Physics ; Physics and Astronomy ; Polymer industry ; Polymers ; Reaction kinetics ; Solid propellants</subject><ispartof>Technical physics, 2021-07, Vol.66 (7), p.895-901</ispartof><rights>Pleiades Publishing, Ltd. 2021. ISSN 1063-7842, Technical Physics, 2021, Vol. 66, No. 7, pp. 895–901. © Pleiades Publishing, Ltd., 2021. ISSN 1063-7842, Technical Physics, 2021. © Pleiades Publishing, Ltd., 2021. Russian Text © The Author(s), 2021, published in Zhurnal Tekhnicheskoi Fiziki, 2021, Vol. 91, No. 6, pp. 928–934.</rights><rights>COPYRIGHT 2021 Springer</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c313t-34d13afbe5db74d507a628348d7c4fb790680c9d2c8338e285e2a0681dede193</citedby><cites>FETCH-LOGICAL-c313t-34d13afbe5db74d507a628348d7c4fb790680c9d2c8338e285e2a0681dede193</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1063784221060104$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1063784221060104$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Korotkikh, A. G.</creatorcontrib><creatorcontrib>Sorokin, I. V.</creatorcontrib><creatorcontrib>Slyusarskiy, K. V.</creatorcontrib><creatorcontrib>Arkhipov, V. A.</creatorcontrib><title>Ignition of Boron-Containing High-Energy Materials Based on an Oxidizer and Polymer Binder</title><title>Technical physics</title><addtitle>Tech. Phys</addtitle><description>The use of aluminum borides is a promising direction in the development of modern propellant compositions and aerial vehicles. We present experimental data on the kinetics of oxidation of microscale powders of aluminum, amorphous boron, and the aluminum borides AlB
2
and AlB
12
in air upon heating at a constant rate of 10°C/min and the results of laser-assisted ignition of high-energy materials that contain these metal powders and are based on ammonium perchlorate, ammonium nitrate, and an inert binder or an energetic combustible binder. We show that the use of the boron-containing powders enables us to lower the onset temperature of oxidation and the temperature of intense oxidation, while increasing their oxidation effectiveness, compared to pure aluminum. The dependences of ignition delay time on the heat flux show that the AlB
2
and AlB
12
powders are the most effective metal fuel components for solid propellants based on ammonium perchlorate, ammonium nitrate, and an energetic binder: they display the shortest ignition delay time and require the lowest heat input for ignition.</description><subject>Aluminum</subject><subject>Ammonium compounds</subject><subject>Ammonium nitrate</subject><subject>Ammonium paratungstate</subject><subject>Ammonium perchlorates</subject><subject>Borides</subject><subject>Boron</subject><subject>Classical and Continuum Physics</subject><subject>Delay time</subject><subject>Flammability</subject><subject>Heat flux</subject><subject>Ignition</subject><subject>Metal fuels</subject><subject>Metal powder products</subject><subject>Metal powders</subject><subject>Oxidation</subject><subject>Oxidizing agents</subject><subject>Physics</subject><subject>Physics and Astronomy</subject><subject>Polymer industry</subject><subject>Polymers</subject><subject>Reaction kinetics</subject><subject>Solid propellants</subject><issn>1063-7842</issn><issn>1090-6525</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp1kVFLwzAQx4soOKcfwLeCz525pE3Tx21MN5hMcE--lKy51owtmUkHzk9vyoQhKnnIn8vvdxe4KLoFMgBg6f0LEM5ykVIaAgGSnkU9IAVJeEaz8y5zlnTvl9GV92tCAETGe9HrrDG61dbEto5H1lmTjK1ppTbaNPFUN2_JxKBrDvGTbNFpufHxSHpUcVCkiRcfWulPdCGr-NluDtuQR9oodNfRRR1wvPm--9HyYbIcT5P54nE2Hs6TigFrE5YqYLJeYaZWeaoykktOBUuFyqu0XuUF4YJUhaKVYEwgFRlSGWqgUCEUrB_dHdvunH3fo2_Ltd07EyaWlKdAMuAZO1GN3GCpTW1bJ6ut9lU55EXOKePQUYM_qHAUbnVlDdY61H8IcBQqZ713WJc7p7fSHUogZbeY8tdigkOPjg-sadCdPvy_9AV9a4x-</recordid><startdate>20210701</startdate><enddate>20210701</enddate><creator>Korotkikh, A. G.</creator><creator>Sorokin, I. V.</creator><creator>Slyusarskiy, K. V.</creator><creator>Arkhipov, V. A.</creator><general>Pleiades Publishing</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20210701</creationdate><title>Ignition of Boron-Containing High-Energy Materials Based on an Oxidizer and Polymer Binder</title><author>Korotkikh, A. G. ; Sorokin, I. V. ; Slyusarskiy, K. V. ; Arkhipov, V. A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c313t-34d13afbe5db74d507a628348d7c4fb790680c9d2c8338e285e2a0681dede193</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Aluminum</topic><topic>Ammonium compounds</topic><topic>Ammonium nitrate</topic><topic>Ammonium paratungstate</topic><topic>Ammonium perchlorates</topic><topic>Borides</topic><topic>Boron</topic><topic>Classical and Continuum Physics</topic><topic>Delay time</topic><topic>Flammability</topic><topic>Heat flux</topic><topic>Ignition</topic><topic>Metal fuels</topic><topic>Metal powder products</topic><topic>Metal powders</topic><topic>Oxidation</topic><topic>Oxidizing agents</topic><topic>Physics</topic><topic>Physics and Astronomy</topic><topic>Polymer industry</topic><topic>Polymers</topic><topic>Reaction kinetics</topic><topic>Solid propellants</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Korotkikh, A. G.</creatorcontrib><creatorcontrib>Sorokin, I. V.</creatorcontrib><creatorcontrib>Slyusarskiy, K. V.</creatorcontrib><creatorcontrib>Arkhipov, V. A.</creatorcontrib><collection>CrossRef</collection><jtitle>Technical physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Korotkikh, A. G.</au><au>Sorokin, I. V.</au><au>Slyusarskiy, K. V.</au><au>Arkhipov, V. A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ignition of Boron-Containing High-Energy Materials Based on an Oxidizer and Polymer Binder</atitle><jtitle>Technical physics</jtitle><stitle>Tech. Phys</stitle><date>2021-07-01</date><risdate>2021</risdate><volume>66</volume><issue>7</issue><spage>895</spage><epage>901</epage><pages>895-901</pages><issn>1063-7842</issn><eissn>1090-6525</eissn><abstract>The use of aluminum borides is a promising direction in the development of modern propellant compositions and aerial vehicles. We present experimental data on the kinetics of oxidation of microscale powders of aluminum, amorphous boron, and the aluminum borides AlB
2
and AlB
12
in air upon heating at a constant rate of 10°C/min and the results of laser-assisted ignition of high-energy materials that contain these metal powders and are based on ammonium perchlorate, ammonium nitrate, and an inert binder or an energetic combustible binder. We show that the use of the boron-containing powders enables us to lower the onset temperature of oxidation and the temperature of intense oxidation, while increasing their oxidation effectiveness, compared to pure aluminum. The dependences of ignition delay time on the heat flux show that the AlB
2
and AlB
12
powders are the most effective metal fuel components for solid propellants based on ammonium perchlorate, ammonium nitrate, and an energetic binder: they display the shortest ignition delay time and require the lowest heat input for ignition.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1063784221060104</doi><tpages>7</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1063-7842 |
| ispartof | Technical physics, 2021-07, Vol.66 (7), p.895-901 |
| issn | 1063-7842 1090-6525 |
| language | eng |
| recordid | cdi_proquest_journals_2641051653 |
| source | SpringerNature Journals |
| subjects | Aluminum Ammonium compounds Ammonium nitrate Ammonium paratungstate Ammonium perchlorates Borides Boron Classical and Continuum Physics Delay time Flammability Heat flux Ignition Metal fuels Metal powder products Metal powders Oxidation Oxidizing agents Physics Physics and Astronomy Polymer industry Polymers Reaction kinetics Solid propellants |
| title | Ignition of Boron-Containing High-Energy Materials Based on an Oxidizer and Polymer Binder |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-01T17%3A29%3A21IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-gale_proqu&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Ignition%20of%20Boron-Containing%20High-Energy%20Materials%20Based%20on%20an%20Oxidizer%20and%20Polymer%20Binder&rft.jtitle=Technical%20physics&rft.au=Korotkikh,%20A.%20G.&rft.date=2021-07-01&rft.volume=66&rft.issue=7&rft.spage=895&rft.epage=901&rft.pages=895-901&rft.issn=1063-7842&rft.eissn=1090-6525&rft_id=info:doi/10.1134/S1063784221060104&rft_dat=%3Cgale_proqu%3EA697623613%3C/gale_proqu%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2641051653&rft_id=info:pmid/&rft_galeid=A697623613&rfr_iscdi=true |