High Performance of PVA Nanocomposite Reinforced by Janus-like Asymmetrically Oxidized Graphene: Synergetic Effect of H-bonding Interaction and Interfacial Crystallization
Macromolecule nanocrystal network and strong interfacial interaction are always beneficial to enhance the mechanical property of polymer-based nanocomposites. Poly(vinyl alcohol) (PVA), a typical biocompatible semicrystalline polymer, is an ideal candidate for preparing high performance polymer-base...
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Veröffentlicht in: | Chinese journal of polymer science 2022-04, Vol.40 (4), p.373-383 |
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creator | Zhang, Ning Zhang, Bin Pang, Yong Yang, Hong-Sheng Zong, Lu Duan, Yong-Xin Zhang, Jian-Ming |
description | Macromolecule nanocrystal network and strong interfacial interaction are always beneficial to enhance the mechanical property of polymer-based nanocomposites. Poly(vinyl alcohol) (PVA), a typical biocompatible semicrystalline polymer, is an ideal candidate for preparing high performance polymer-based nanocomposites. However, the rich hydrogen bonds between PVA matrix and graphene oxide (GO) can disrupt the formation of PVA nanocrystal network. Thus, it remains a great challenge to achieve both strong and tough PVA-GO nanocomposites. Herein, by introducing a novel Janus-like amphiphilic graphene oxide (JGO), both hydrogen bonding and interfacial crystallization have been constructed between JGO sheets and PVA matrix. Benefiting from amphiphilic interfacial interaction and the enhanced crystal network, both PVA-JGO dried films and their swollen hydrogel films show superior mechanical properties than those of traditional PVA-GO nanocomposites. PVA-JGO dried films exhibit a 264% improvement of toughness at a JGO loading of 1 wt%. Meanwhile, the corresponding PVA-JGO swollen hydrogel films display simultaneous improvement of nearly 8 times increase of tensile strength and 20 times increase of toughness compared to traditional PVA-GO nanocomposite. This work indicates multiple interfacial interactions and macromolecule crystal networks can be concurrent in PVA nanocomposites by innovative modification of nanofillers, providing a new strategy to construct PVA nanocomposites with high strength and high toughness. The integration of outstanding mechanical and swelling resistance properties on PVA-JGO nanocomposite films render their promising applications, such as packaging and toughening hydrogel materials. |
doi_str_mv | 10.1007/s10118-022-2664-x |
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Poly(vinyl alcohol) (PVA), a typical biocompatible semicrystalline polymer, is an ideal candidate for preparing high performance polymer-based nanocomposites. However, the rich hydrogen bonds between PVA matrix and graphene oxide (GO) can disrupt the formation of PVA nanocrystal network. Thus, it remains a great challenge to achieve both strong and tough PVA-GO nanocomposites. Herein, by introducing a novel Janus-like amphiphilic graphene oxide (JGO), both hydrogen bonding and interfacial crystallization have been constructed between JGO sheets and PVA matrix. Benefiting from amphiphilic interfacial interaction and the enhanced crystal network, both PVA-JGO dried films and their swollen hydrogel films show superior mechanical properties than those of traditional PVA-GO nanocomposites. PVA-JGO dried films exhibit a 264% improvement of toughness at a JGO loading of 1 wt%. Meanwhile, the corresponding PVA-JGO swollen hydrogel films display simultaneous improvement of nearly 8 times increase of tensile strength and 20 times increase of toughness compared to traditional PVA-GO nanocomposite. This work indicates multiple interfacial interactions and macromolecule crystal networks can be concurrent in PVA nanocomposites by innovative modification of nanofillers, providing a new strategy to construct PVA nanocomposites with high strength and high toughness. The integration of outstanding mechanical and swelling resistance properties on PVA-JGO nanocomposite films render their promising applications, such as packaging and toughening hydrogel materials.</description><identifier>ISSN: 0256-7679</identifier><identifier>EISSN: 1439-6203</identifier><identifier>DOI: 10.1007/s10118-022-2664-x</identifier><language>eng</language><publisher>Singapore: Springer Singapore</publisher><subject>Biocompatibility ; Bonding strength ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Condensed Matter Physics ; Crystallization ; Graphene ; Hydrogels ; Hydrogen bonding ; Hydrogen bonds ; Industrial Chemistry/Chemical Engineering ; Mechanical properties ; Nanocomposites ; Nanocrystals ; Polymer Sciences ; Polymers ; Polyvinyl alcohol ; Research Article ; Tensile strength ; Toughness</subject><ispartof>Chinese journal of polymer science, 2022-04, Vol.40 (4), p.373-383</ispartof><rights>Chinese Chemical Society Institute of Chemistry, Chinese Academy of Sciences 2022</rights><rights>Chinese Chemical Society Institute of Chemistry, Chinese Academy of Sciences 2022.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-7fd774b76db58fae925f9c98dfe8b9db174435669bfff6d8634f6dbf1c9f709e3</citedby><cites>FETCH-LOGICAL-c316t-7fd774b76db58fae925f9c98dfe8b9db174435669bfff6d8634f6dbf1c9f709e3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10118-022-2664-x$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10118-022-2664-x$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Zhang, Ning</creatorcontrib><creatorcontrib>Zhang, Bin</creatorcontrib><creatorcontrib>Pang, Yong</creatorcontrib><creatorcontrib>Yang, Hong-Sheng</creatorcontrib><creatorcontrib>Zong, Lu</creatorcontrib><creatorcontrib>Duan, Yong-Xin</creatorcontrib><creatorcontrib>Zhang, Jian-Ming</creatorcontrib><title>High Performance of PVA Nanocomposite Reinforced by Janus-like Asymmetrically Oxidized Graphene: Synergetic Effect of H-bonding Interaction and Interfacial Crystallization</title><title>Chinese journal of polymer science</title><addtitle>Chin J Polym Sci</addtitle><description>Macromolecule nanocrystal network and strong interfacial interaction are always beneficial to enhance the mechanical property of polymer-based nanocomposites. Poly(vinyl alcohol) (PVA), a typical biocompatible semicrystalline polymer, is an ideal candidate for preparing high performance polymer-based nanocomposites. However, the rich hydrogen bonds between PVA matrix and graphene oxide (GO) can disrupt the formation of PVA nanocrystal network. Thus, it remains a great challenge to achieve both strong and tough PVA-GO nanocomposites. Herein, by introducing a novel Janus-like amphiphilic graphene oxide (JGO), both hydrogen bonding and interfacial crystallization have been constructed between JGO sheets and PVA matrix. Benefiting from amphiphilic interfacial interaction and the enhanced crystal network, both PVA-JGO dried films and their swollen hydrogel films show superior mechanical properties than those of traditional PVA-GO nanocomposites. PVA-JGO dried films exhibit a 264% improvement of toughness at a JGO loading of 1 wt%. Meanwhile, the corresponding PVA-JGO swollen hydrogel films display simultaneous improvement of nearly 8 times increase of tensile strength and 20 times increase of toughness compared to traditional PVA-GO nanocomposite. This work indicates multiple interfacial interactions and macromolecule crystal networks can be concurrent in PVA nanocomposites by innovative modification of nanofillers, providing a new strategy to construct PVA nanocomposites with high strength and high toughness. The integration of outstanding mechanical and swelling resistance properties on PVA-JGO nanocomposite films render their promising applications, such as packaging and toughening hydrogel materials.</description><subject>Biocompatibility</subject><subject>Bonding strength</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Condensed Matter Physics</subject><subject>Crystallization</subject><subject>Graphene</subject><subject>Hydrogels</subject><subject>Hydrogen bonding</subject><subject>Hydrogen bonds</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Mechanical properties</subject><subject>Nanocomposites</subject><subject>Nanocrystals</subject><subject>Polymer Sciences</subject><subject>Polymers</subject><subject>Polyvinyl alcohol</subject><subject>Research Article</subject><subject>Tensile strength</subject><subject>Toughness</subject><issn>0256-7679</issn><issn>1439-6203</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp1kUFv1DAUhC1EJZbCD-BmibOpnTh2zG21Kt2iilZt4Wo5zvPWJbEX2ytt-pf4k2QVJE6cRk_vm5nDIPSB0U-MUnmRGWWsJbSqSCUEJ8dXaMV4rYioaP0arWjVCCKFVG_Q25yfKRVcNnKFfm_97gnfQXIxjSZYwNHhux9r_M2EaOO4j9kXwPfgw0xY6HE34a8mHDIZ_E_A6zyNI5TkrRmGCd8efe9fZuoqmf0TBPiMH6YAaQfFW3zpHNhyatiSLobehx2-DgWSscXHgE3ol9sZ682AN2nKZc71L-b0f4fOnBkyvP-r5-j7l8vHzZbc3F5db9Y3xNZMFCJdLyXvpOi7pnUGVNU4ZVXbO2g71XdMcl43QqjOOSf6VtR8ls4xq5ykCupz9HHJ3af46wC56Od4SGGu1JXgjDaUV_VMsYWyKeacwOl98qNJk2ZUnzbRyyZ63kSfNtHH2VMtnjyzYQfpX_L_TX8Ak26T1w</recordid><startdate>20220401</startdate><enddate>20220401</enddate><creator>Zhang, Ning</creator><creator>Zhang, Bin</creator><creator>Pang, Yong</creator><creator>Yang, Hong-Sheng</creator><creator>Zong, Lu</creator><creator>Duan, Yong-Xin</creator><creator>Zhang, Jian-Ming</creator><general>Springer Singapore</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20220401</creationdate><title>High Performance of PVA Nanocomposite Reinforced by Janus-like Asymmetrically Oxidized Graphene: Synergetic Effect of H-bonding Interaction and Interfacial Crystallization</title><author>Zhang, Ning ; Zhang, Bin ; Pang, Yong ; Yang, Hong-Sheng ; Zong, Lu ; Duan, Yong-Xin ; Zhang, Jian-Ming</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-7fd774b76db58fae925f9c98dfe8b9db174435669bfff6d8634f6dbf1c9f709e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Biocompatibility</topic><topic>Bonding strength</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Condensed Matter Physics</topic><topic>Crystallization</topic><topic>Graphene</topic><topic>Hydrogels</topic><topic>Hydrogen bonding</topic><topic>Hydrogen bonds</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Mechanical properties</topic><topic>Nanocomposites</topic><topic>Nanocrystals</topic><topic>Polymer Sciences</topic><topic>Polymers</topic><topic>Polyvinyl alcohol</topic><topic>Research Article</topic><topic>Tensile strength</topic><topic>Toughness</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhang, Ning</creatorcontrib><creatorcontrib>Zhang, Bin</creatorcontrib><creatorcontrib>Pang, Yong</creatorcontrib><creatorcontrib>Yang, Hong-Sheng</creatorcontrib><creatorcontrib>Zong, Lu</creatorcontrib><creatorcontrib>Duan, Yong-Xin</creatorcontrib><creatorcontrib>Zhang, Jian-Ming</creatorcontrib><collection>CrossRef</collection><jtitle>Chinese journal of polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, Ning</au><au>Zhang, Bin</au><au>Pang, Yong</au><au>Yang, Hong-Sheng</au><au>Zong, Lu</au><au>Duan, Yong-Xin</au><au>Zhang, Jian-Ming</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>High Performance of PVA Nanocomposite Reinforced by Janus-like Asymmetrically Oxidized Graphene: Synergetic Effect of H-bonding Interaction and Interfacial Crystallization</atitle><jtitle>Chinese journal of polymer science</jtitle><stitle>Chin J Polym Sci</stitle><date>2022-04-01</date><risdate>2022</risdate><volume>40</volume><issue>4</issue><spage>373</spage><epage>383</epage><pages>373-383</pages><issn>0256-7679</issn><eissn>1439-6203</eissn><abstract>Macromolecule nanocrystal network and strong interfacial interaction are always beneficial to enhance the mechanical property of polymer-based nanocomposites. Poly(vinyl alcohol) (PVA), a typical biocompatible semicrystalline polymer, is an ideal candidate for preparing high performance polymer-based nanocomposites. However, the rich hydrogen bonds between PVA matrix and graphene oxide (GO) can disrupt the formation of PVA nanocrystal network. Thus, it remains a great challenge to achieve both strong and tough PVA-GO nanocomposites. Herein, by introducing a novel Janus-like amphiphilic graphene oxide (JGO), both hydrogen bonding and interfacial crystallization have been constructed between JGO sheets and PVA matrix. Benefiting from amphiphilic interfacial interaction and the enhanced crystal network, both PVA-JGO dried films and their swollen hydrogel films show superior mechanical properties than those of traditional PVA-GO nanocomposites. PVA-JGO dried films exhibit a 264% improvement of toughness at a JGO loading of 1 wt%. Meanwhile, the corresponding PVA-JGO swollen hydrogel films display simultaneous improvement of nearly 8 times increase of tensile strength and 20 times increase of toughness compared to traditional PVA-GO nanocomposite. This work indicates multiple interfacial interactions and macromolecule crystal networks can be concurrent in PVA nanocomposites by innovative modification of nanofillers, providing a new strategy to construct PVA nanocomposites with high strength and high toughness. The integration of outstanding mechanical and swelling resistance properties on PVA-JGO nanocomposite films render their promising applications, such as packaging and toughening hydrogel materials.</abstract><cop>Singapore</cop><pub>Springer Singapore</pub><doi>10.1007/s10118-022-2664-x</doi><tpages>11</tpages></addata></record> |
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subjects | Biocompatibility Bonding strength Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Condensed Matter Physics Crystallization Graphene Hydrogels Hydrogen bonding Hydrogen bonds Industrial Chemistry/Chemical Engineering Mechanical properties Nanocomposites Nanocrystals Polymer Sciences Polymers Polyvinyl alcohol Research Article Tensile strength Toughness |
title | High Performance of PVA Nanocomposite Reinforced by Janus-like Asymmetrically Oxidized Graphene: Synergetic Effect of H-bonding Interaction and Interfacial Crystallization |
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