Aromatization as the driving force for single electron transfer towards C-C cross-coupling reactions

There is a strong current interest in C-H functionalization reactions under metal-free conditions. We report herein the deprotonated form of dihydrophenazine (DPh) as a potent initiator under photochemical conditions that can efficiently generate aryl radicals via single electron transfer (SET). The...

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Veröffentlicht in:	Catalysis science & technology 2022-03, Vol.12 (6), p.1934-194
Hauptverfasser:	Dey, Dhananjay, Kundu, Abhishek, Roy, Monojit, Pal, Subhankar, Adhikari, Debashis
Format:	Artikel
Sprache:	eng
Schlagworte:	Aromatic compounds Aromaticity Chemical reactions Cross coupling Electron transfer Electrons Initiators Interception Reaction intermediates Room temperature Single electrons Substrates
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