SNS ligand-assisted catalyst activation in Zn-catalysed carbonyl hydroboration

Ligands that include Lewis acid/base functionality have extensive applications in bifunctional catalysis using first row metals. In this work, zinc bis(amido), bis(thiolate) and amido-thiolate SNS complexes were prepared and compared as precatalysts for carbonyl hydroboration using pinacolborane. Me...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2022-03, Vol.58 (23), p.3795-3798
Hauptverfasser:	Ataie, Saeed, Hogeterp, Seth, Ovens, Jeffrey S, Baker, R. Tom
Format:	Artikel
Sprache:	eng
Schlagworte:	Carbonyls Catalysis Catalysts Hydroboration Lewis acid Ligands Zinc
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creator	Ataie, Saeed Hogeterp, Seth Ovens, Jeffrey S Baker, R. Tom
description	Ligands that include Lewis acid/base functionality have extensive applications in bifunctional catalysis using first row metals. In this work, zinc bis(amido), bis(thiolate) and amido-thiolate SNS complexes were prepared and compared as precatalysts for carbonyl hydroboration using pinacolborane. Mechanistic studies revealed two different ligand-assisted precatalyst activation pathways, both leading to an active and robust zinc alkoxide catalyst. This work furthers our understanding of metal-ligand cooperation in first-row metal catalysis. Zinc amido and thiolate SNS complexes exhibit distinct ligand-assisted pre-catalyst activation pathways for carbonyl hydroboration using pinacolborane.
doi_str_mv	10.1039/d1cc06981k
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source	Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects	Carbonyls Catalysis Catalysts Hydroboration Lewis acid Ligands Zinc
title	SNS ligand-assisted catalyst activation in Zn-catalysed carbonyl hydroboration
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