Activating room-temperature phosphorescence of 1,8-naphthalimide by doping into aromatic dicarboxylic acids
The room-temperature phosphorescence of 1,8-naphthalimide was activated by doping it into aromatic dicarboxylic acids. The doping system gives a bright yellow afterglow and 1,8-naphthalimide and isophthalic acid (0.02 mol% doping content) afford a phosphorescent lifetime of 403 ms and a quantum yiel...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2022-03, Vol.58 (22), p.3641-3644 |
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| container_title | Chemical communications (Cambridge, England) |
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| creator | Wang, Xiangming Wang, Zepeng Feng, Hua Lin, Chongyang Shi, Huifang An, Zhongfu Su, Zhong-Min Liang, Fu-Shun |
| description | The room-temperature phosphorescence of 1,8-naphthalimide was activated by doping it into aromatic dicarboxylic acids. The doping system gives a bright yellow afterglow and 1,8-naphthalimide and isophthalic acid (0.02 mol% doping content) afford a phosphorescent lifetime of 403 ms and a quantum yield of 4.2%. Both energy transfer from the host to the guest and the formation of an intermolecular hydrogen-bonding network are responsible for the observed efficient and long-lived phosphorescence.
The parent 1,8-naphthalimide, which is otherwise room-temperature phosphorescence inert, was activated by doping into aromatic dicarboxylic acids, leading to efficient and long-lived phosphorescent emission. |
| doi_str_mv | 10.1039/d2cc00474g |
| format | Article |
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The parent 1,8-naphthalimide, which is otherwise room-temperature phosphorescence inert, was activated by doping into aromatic dicarboxylic acids, leading to efficient and long-lived phosphorescent emission.</description><subject>Dicarboxylic Acids</subject><subject>Doping</subject><subject>Energy Transfer</subject><subject>Hydrogen bonding</subject><subject>Luminescence</subject><subject>Naphthalimides</subject><subject>Phosphorescence</subject><subject>Room temperature</subject><subject>Temperature</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNpdkctLxDAQxoMoPlYv3pWCFxGrSSZ9HZf1CYIXBW8lTzfaNjVpxf3vzbo-wIEwE_Kbj8l8CO0TfEYwVOeKSokxK9jzGtomkLM0Y-XT-rLOqrQAlm2hnRBecAySlZtoCzJKKADeRq9TOdh3PtjuOfHOtemg2157PoxeJ_3chXi8DlJ3UifOJOS0TDvez4c5b2xrlU7EIlGuX_bbbnAJ966NcjJRVnIv3MeiiRcurQq7aMPwJui97zxBj1eXD7Ob9O7--nY2vUslQDGkmcgrYQgzGccUlGQVUxXmVEnJc4ONwFyoEmsKRgpVCJ3nTAAvBJjcCM5ggo5Xur13b6MOQ93a-IOm4Z12Y6hpDlDmlACN6NE_9MWNvovTRYrhipUkrniCTlaU9C4Er03de9tyv6gJrpcW1Bd0Nvuy4DrCh9-So2i1-kV_dh6BgxXgg_x9_fMQPgFm5o0W</recordid><startdate>20220315</startdate><enddate>20220315</enddate><creator>Wang, Xiangming</creator><creator>Wang, Zepeng</creator><creator>Feng, Hua</creator><creator>Lin, Chongyang</creator><creator>Shi, Huifang</creator><creator>An, Zhongfu</creator><creator>Su, Zhong-Min</creator><creator>Liang, Fu-Shun</creator><general>Royal Society of Chemistry</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-9964-4441</orcidid><orcidid>https://orcid.org/0000-0003-4195-3863</orcidid><orcidid>https://orcid.org/0000-0002-6522-2654</orcidid></search><sort><creationdate>20220315</creationdate><title>Activating room-temperature phosphorescence of 1,8-naphthalimide by doping into aromatic dicarboxylic acids</title><author>Wang, Xiangming ; Wang, Zepeng ; Feng, Hua ; Lin, Chongyang ; Shi, Huifang ; An, Zhongfu ; Su, Zhong-Min ; Liang, Fu-Shun</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c337t-5b69bf14f5a023dc494d90a2dcca6f0fb0abd80e23fcbd7be664b3a7b3f6fba43</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Dicarboxylic Acids</topic><topic>Doping</topic><topic>Energy Transfer</topic><topic>Hydrogen bonding</topic><topic>Luminescence</topic><topic>Naphthalimides</topic><topic>Phosphorescence</topic><topic>Room temperature</topic><topic>Temperature</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wang, Xiangming</creatorcontrib><creatorcontrib>Wang, Zepeng</creatorcontrib><creatorcontrib>Feng, Hua</creatorcontrib><creatorcontrib>Lin, Chongyang</creatorcontrib><creatorcontrib>Shi, Huifang</creatorcontrib><creatorcontrib>An, Zhongfu</creatorcontrib><creatorcontrib>Su, Zhong-Min</creatorcontrib><creatorcontrib>Liang, Fu-Shun</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wang, Xiangming</au><au>Wang, Zepeng</au><au>Feng, Hua</au><au>Lin, Chongyang</au><au>Shi, Huifang</au><au>An, Zhongfu</au><au>Su, Zhong-Min</au><au>Liang, Fu-Shun</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Activating room-temperature phosphorescence of 1,8-naphthalimide by doping into aromatic dicarboxylic acids</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><addtitle>Chem Commun (Camb)</addtitle><date>2022-03-15</date><risdate>2022</risdate><volume>58</volume><issue>22</issue><spage>3641</spage><epage>3644</epage><pages>3641-3644</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>The room-temperature phosphorescence of 1,8-naphthalimide was activated by doping it into aromatic dicarboxylic acids. The doping system gives a bright yellow afterglow and 1,8-naphthalimide and isophthalic acid (0.02 mol% doping content) afford a phosphorescent lifetime of 403 ms and a quantum yield of 4.2%. Both energy transfer from the host to the guest and the formation of an intermolecular hydrogen-bonding network are responsible for the observed efficient and long-lived phosphorescence.
The parent 1,8-naphthalimide, which is otherwise room-temperature phosphorescence inert, was activated by doping into aromatic dicarboxylic acids, leading to efficient and long-lived phosphorescent emission.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>35212330</pmid><doi>10.1039/d2cc00474g</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0002-9964-4441</orcidid><orcidid>https://orcid.org/0000-0003-4195-3863</orcidid><orcidid>https://orcid.org/0000-0002-6522-2654</orcidid></addata></record> |
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| source | MEDLINE; Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Dicarboxylic Acids Doping Energy Transfer Hydrogen bonding Luminescence Naphthalimides Phosphorescence Room temperature Temperature |
| title | Activating room-temperature phosphorescence of 1,8-naphthalimide by doping into aromatic dicarboxylic acids |
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