The new LED-Sensitive photoinitiators of Polymerization: Copper complexes in free radical and cationic photoinitiating systems and application in 3D printing

[Display omitted] •Copper complexes with good visible light absorption can be used as efficient photoinitiators.•Cationic and Radical polymerizations are possible as well as IPN synthesis.•A good spatial control is found for direct laser write experiments.•The chemical mechanisms are investigated in...

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Veröffentlicht in:	European polymer journal 2022-01, Vol.162, p.110885, Article 110885
Hauptverfasser:	Borjigin, Timur, Noirbent, Guillaume, Gigmes, Didier, Xiao, Pu, Dumur, Frédéric, Lalevée, Jacques
Format:	Artikel
Sprache:	eng
Schlagworte:	3D printing Acrylates Cationic polymerization Chemical reactions Coordination compounds Copper Copper complex Copper compounds Direct laser writing Electron paramagnetic resonance Electron spin Fourier transforms Free radical photopolymerization Free radical polymerization Free radicals Interpenetrating networks IPN photopolymerization LEDs Monomers Photochemistry Photoinitiator Photoinitiators Photolysis Polymerization Polymers Spectrum analysis Spin resonance Three dimensional printing
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