Functional modification, self-assembly and application of calix[4]resorcinarenes

As a special subset of calix[4]arene, calix[4]resorcinarene is an excellent molecular platform which could be modified by introducing functional groups to multiple sites at the upper and lower rims. There are mainly three ways to build functionalized calix[4]resorcinarene derivatives: (1) modificati...

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Veröffentlicht in:Journal of inclusion phenomena and macrocyclic chemistry 2022-04, Vol.102 (3-4), p.201-233
Hauptverfasser: Liu, Jing-Long, Sun, Meng, Shi, Yan-Hui, Zhou, Xin-Min, Zhang, Pei-Zhi, Jia, Ai-Quan, Zhang, Qian-Feng
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container_end_page 233
container_issue 3-4
container_start_page 201
container_title Journal of inclusion phenomena and macrocyclic chemistry
container_volume 102
creator Liu, Jing-Long
Sun, Meng
Shi, Yan-Hui
Zhou, Xin-Min
Zhang, Pei-Zhi
Jia, Ai-Quan
Zhang, Qian-Feng
description As a special subset of calix[4]arene, calix[4]resorcinarene is an excellent molecular platform which could be modified by introducing functional groups to multiple sites at the upper and lower rims. There are mainly three ways to build functionalized calix[4]resorcinarene derivatives: (1) modification on the C -2 sites of calix[4]resorcinarenes; (2) modification on the phenolic hydroxyl groups of calix[4]resorcinarenes; (3) modification on the bridging methylenes at lower rim of calix[4]resorcinarenes. Functionalized calix[4]resorcinarene derivatives play an important role in the development of self-assembly chemistry, among which hydrogen bonding and metal coordination are the two most common interactions to obtain multicomponent structures. Moreover, due to the excellent topological structures and various active substituents of functionalized calix[4]resorcinarene derivatives, their applications in various fields, such as nanoparticles, catalysts, fluorescent materials, and sensors, have been briefly presented in this paper.
doi_str_mv 10.1007/s10847-021-01119-w
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subjects Chemistry
Chemistry and Materials Science
Crystallography and Scattering Methods
Fluorescence
Food Science
Functional groups
Hydrogen bonding
Hydroxyl groups
Nanoparticles
Organic Chemistry
Review Article
Self-assembly
title Functional modification, self-assembly and application of calix[4]resorcinarenes
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